Ductile cast irons are heat treated primarily to create matrix microstructures and associated mechanical properties not readily obtained in the as-cast condition. This article discusses the most important heat treatments of ductile irons and their purposes. International standards of ductile iron provided by ASTM International, the International Organization for Standardization (ISO), and SAE International are presented in a table. The article explains basic structural differences between the ferritic, pearlitic, martensitic, and ausferritic classes. It presents recommended practices for annealing ductile iron castings for different alloy contents and for castings with and without eutectic carbides. The article discusses the induction surface hardening and remelt hardening of ductile iron. It concludes with information on the effect of heat treatment on fatigue strength of ductile iron.

Structural steels with very high strength levels are often referred to as ultrahigh-strength steels. This article describes the commercial structural steels capable of a minimum yield strength of 1380 MPa (200 ksi). The ultrahigh-strength class of constructional steels includes several distinctly different families of steels. The article focuses on medium-carbon low-alloy steels, medium-alloy air-hardening steels, and high fracture toughness steels. The medium-carbon low-alloy family of ultrahigh-strength steels includes AISI/SAE 4130, the higher-strength 4140, and the deeper hardening, higher-strength 4340. Also from this family are descriptions for the 300M, D-6a and D-6ac, 6150, and 8640 steels. The medium-alloy air-hardening family of ultrahigh-strength steels includes H11 modified and H13 steels. The high fracture toughness family of ultrahigh-strength steels includes HP-9-4-30 steel and AF1410 steel. The article explains the mechanical properties and the heat treatments of the medium-carbon low-alloy steels, medium-alloy air-hardening steels, and high fracture toughness steels.

Ductile cast irons are heat treated to create matrix microstructures and associated mechanical properties not readily obtained in the as-cast condition. This article provides a detailed account of the general characteristics of ductile irons. It discusses the most important heat treatments of ductile irons, namely, stress relieving, austenitizing, annealing, normalizing, quenching, martempering, austempering, and surface hardening. The article elucidates the effects of these heat treatments on the mechanical properties of the ductile irons.

Rolling-element bearings, whether ball bearings or roller bearings with spherical, straight, or tapered rollers, are fabricated from a wide variety of steels. This article discusses the production process, characteristics, nominal compositions, and types of bearing steels. These include standard bearing steels, such as high-carbon bearing steels and carburizing bearing steels; and special-purpose bearing steels, such as high-temperature service bearing steels and corrosion-resistant bearing steels.

Ultrahigh-strength steels are designed to be used in structural applications where very high loads are applied and often high strength-to-weight ratios are required. This article discusses the composition, mechanical properties, processing, product forms, and applications of commercial structural steels capable of a minimum yield strength of 1380 MPa (200 ksi). These include medium-carbon low-alloy steels, such as 4340, 300M, D-6a and D-6ac steels; medium-alloy air-hardening steels, such as HI1 modified steel and H13 steel; high fracture toughness steels, such as HP-9-4-30, AF1410, and AerMet 100 steels; and maraging steels.

Air hardening steel is a type of steel that has deep hardenability and can be hardened in large sections by air cooling. This article discusses the principles of heat treatment of air-hardening steel, and describes the recommended heat treating practices for air-hardening high-strength structural steels, namely, H11 Mod, H13 steel, 300M steel, D-6A and D-6AC, and AF1410 steel. It also provides information on recommended heat treating practices for air-hardening martensitic stainless steels.

Bearing steels, which include high-carbon and low-carbon types, can be divided into service-based classes, such as normal service, high-temperature service, and service under corrosive conditions. This article discusses the importance of matching the hardenability and quenching of a bearing steel. It also discusses the typical microstructure of a high-carbon through-hardened bearing, and shows typical case and core microstructures in carburized bearing materials. Apart from a satisfactory microstructure, which is obtained through the proper combination of steel grade and heat treatment, the single most important factor in achieving high levels of rolling-contact fatigue life in bearings is the cleanliness, or freedom from harmful nonmetallic inclusions, of the steel. Alloy conservation and a more consistent heat-treating response are benefits of using specially designed bearing steels. The selection of a carburizing steel for a specific bearing section is based on the heat-treating practice of the producer, either direct quenching from carburizing or reheating for quenching, and on the characteristics of the quenching equipment.

Lasers evolved as a versatile materials processing tool due to their advantages such as rapid, reproducible processing, chemical cleanliness, ability to handle variety of materials, and suitability for automation. This article focuses on state-of-the-art laser applications to improve tribological performance of structural materials in lubricated and nonlubricated environments. It discusses the fundamentals of various laser materials interactions and reviews laser-based surface-modification strategies, including laser surface heating and melting, laser-synthesized coatings, and laser-based design approaches such as laser patterning and dimpling. Laser-surface modification of novel materials, such as high-entropy alloys and metallic glasses, is explored. The article provides an overview of hybrid techniques involving laser as a secondary tool, as well as a discussion on the improved capabilities of laser surface engineering for tribological applications by means of integrated computational process modeling.

Cr-Mo steels are preferred in the construction of high-temperature components because they possess excellent strength, toughness, and corrosion resistance relative to carbon steels and most low-alloy steels. This article discusses the composition and metallurgy of the heat-resistant Cr-Mo steels. It details the Charpy V-notch (CVN) toughness properties of Cr-Mo steels relevant to fatigue and fracture resistance. The fracture mechanics of Cr-Mo steels are reviewed. The article analyzes the characterization of low-cycle fatigue based on fatigue damage calculations. It concludes with information on fatigue crack growth and fatigue behavior of weldments.

Maraging steels comprise a special class of high-strength steels that differ from conventional steels in that they are hardened by a metallurgical reaction that does not involve carbon. Instead, these steels are strengthened by the precipitation of intermetallic compounds at temperatures of about 480 deg C. Commercial maraging steels are designed to provide specific levels of yield strength in the range of 1030 to 2420 MPa. However, some experimental maraging steels have yield strengths as high as 3450 MPa. These steels typically have very high nickel, cobalt, and molybdenum contents and very low carbon contents. This article outlines the processing of maraging steels: melting, hot working, cold working, machining, heat treating, surface treatment, and welding. It also covers mechanical and physical properties as well as tooling and aerospace applications, where maraging steels are extensively used.

Maraging steels are highly alloyed low-carbon iron-nickel martensite steels that possess an excellent combination of strength and toughness superior to that of most carbon-hardened steels. This article provides a detailed account of the formation of martensite in maraging steels. It discusses the heat treatment of these steels, namely, aging, solution annealing, age hardening, and nitriding. Their hardening during aging has been attributed to two different mechanisms: short-range ordering and precipitation. The article concludes with a discussion on the grain refinement using thermal cycling and transformation-induced plasticity maraging methods.

Surface hardening improves the wear resistance of steel parts. This article focuses exclusively on the methods that involve surface and subsurface modification without any intentional buildup or increase in part dimensions. These include diffusion methods, such as carburizing, nitriding, carbonitriding, and austenitic and ferritic nitrocarburizing, as well as selective-hardening methods, such as laser transformation hardening, electron beam hardening, ion implantation, selective carburizing, and surface hardening with arc lamps. The article also discusses the factors affecting the choice of these surface-hardening methods.

This article describes the systems for designating the aluminum and aluminum alloys that incorporate the product forms (wrought, casting or foundry ingots) and its respective temper for strain-hardened alloys, heat-treatable alloys and annealed alloys. All these systems are covered by American National Standards Institute (ANSI) standard H35.1. Furthermore, the article provides a short note on the designation of unregistered tempers.

This article discusses the various heat treating processes, namely, solid-solution hardening, solution treating, solution aging and dispersion hardening, for low-melting-point alloys such as lead alloys, tin-rich alloys, and zinc alloys. Heat treating of tin-rich alloys has been practiced for bearing alloys, pewterware, and organ pipe alloys. The article reviews the principles underlying these applications.