Reinforcing fibers are a key component of polymer-matrix composites (PMCs), ceramic-matrix composites (CMCs), and metal-matrix composites (MMCs). This article discusses the mechanical and nonmechanical properties of these composites. It presents an overview of PMC, CMC, and MMC reinforcing fibers. The article describes cost-considered value-in-use of the ultimate-use temperature of selected fibers in three fiber categories: metal fibers or wires, oxide ceramic fibers, and non-oxide ceramic fibers.

This article addresses the types, properties, forms, and applications of fibers that are available for use in fiber-reinforced polymeric matrix composites, including glass, graphite, carbon, aramid, boron, silicon carbide, ceramic, continuous oxide and discontinuous oxide fibers. It describes the functions, types, and chemical composition of fiber sizing agents. The article discusses the styles, properties, applications, and weaving methods of unidirectional, two-directional and multidirectionally reinforced fabrics. The article also reviews the use of prepreg resins in aerospace and lower performance applications.

Fiber-matrix adhesion is a variable to be optimized in order to get the best properties and performance in composite materials. This article schematically illustrates fiber matrix interphase for composite materials. It discusses thermodynamics of interphase in terms of surface energy, contact angle, work of adhesion, solid surface energy, and wetting and wicking. The article describes the change in interphase depending on the reinforcing fiber such as glass fiber, polymeric fiber, and carbon fiber. It emphasizes fiber-matrix adhesion measurements by direct methods, indirect methods, and composite laminate tests. The effects of interphase and fiber-matrix adhesion on composite mechanical properties, such as composite on-axis properties, composite off-axis properties, and composite fracture properties, are also discussed.

This article provides a summary of the concepts discussed in the articles under the Section “Constituent Materials” in ASM Handbook, Volume 21: Composites. The Section describes the major matrix resins and reinforcing fibers used in composite materials, as well as some of the intermediate material forms available for composite fabrication.

This article describes the most significant tests to characterize the properties of constituent materials. It discusses the chemical, physical, and mechanical tests for determining the properties of reinforcement fibers and fabrics. The article provides information on some of the basic materials used for thermoset and thermoplastic resin matrices. It reviews the identification of the individual characteristics of thermoset and thermoplastic resin along with the test methods normally used for their determination. The article contains a table that lists properties and tests for uncured and cured thermoset-matrix resins and prepregs.

Rehabilitation is the process of repairing or modifying reinforced concrete structures to a desired useful condition. This article describes the operational steps for the structural assessment of reinforced concrete structures. It discusses the classification of composite materials reinforcing systems for strengthening reinforced concrete structures, such as shop-manufactured and field-manufactured structures. The article reviews the materials property requirements for designing reinforcing systems to strengthen the reinforced concrete structures. It discusses the fiber-reinforced polymer (FRP)-reinforced concrete behavior that depends on flexural, shear, or axial failures. Surface preparation procedures for rehabilitation techniques of reinforced concrete structures using bonded FRP materials are also discussed. The article provides information on the applications of rehabilitation of concrete structures. It explains data recording and acceptance criteria for rehabilitation of concrete structures with composite materials.

This article begins with a review of the purposes of mechanical characterization tests and the general considerations related to the mechanical properties of anisotropic systems, specimen fabrication, equipment and fixturing, environmental conditioning, and analysis of test results. It provides information on the specimen preparation, instrumentation, and procedures for various mechanical test methods of fiber-reinforced composites. These include the compression test, flexure test, shear test, open hole tension test, and compression after impact test. The article describes three distinct fracture modes, namely, crack opening mode, shearing mode, and tearing mode. It presents an overview of fatigue testing and fatigue damage mechanisms of composite materials and reviews the types of mechanical measurements that can be made during the course of testing to assess fatigue damage. The article concludes with a discussion on the split-Hopkinson pressure bar test.

This article describes how composite specimens are sectioned, documented, and labeled during sample preparation. The mounting procedures for the specimen are summarized. The article explains sample clamping, which involves not mounting the specimens using an adhesive or casting resin and corresponds to clamped samples used in automated polishing heads. It details that cavity molds involve mounting the composite specimens using a casting resin in a preset mold. The article also discusses the mounting of composite materials for hand polishing.

Microstructural analysis of the composite matrix is necessary to understand the performance of the part and its long-term durability. This article focuses on the microstructural analysis of engineering thermoplastic-matrix composites and the influence of cooling rate and nucleation on the formation of spherulites in high-temperature thermoplastic-matrix carbon-fiber-reinforced composites. It also describes the microstructural analysis of a bio-based thermosetting-matrix natural fiber composite system.

For the reinforcement of metal-matrix composites, four general classes of materials are commercially available: oxide fibers based primarily on alumina and alumina silica systems, nonoxide systems based on silicon carbide, boron fibers, and carbon fibers. This article discusses the key aspects of aluminum oxide fibers, silicon carbide fibers, boron fibers, and carbon fibers. The commercial fibers for reinforcement of metal-matrix composites are presented in a table. A tabulation of the coating schemes for silicon carbide monofilament fibers is also provided.

Compression molding is the single largest primary manufacturing process used for automotive composite applications. This article provides an overview of the compression molding process. It describes the basic design, materials, and processing equipment of three main groups of composite materials, namely, glass-fiber-mat-reinforced thermoplastics, long-fiber-reinforced thermoplastics, and sheet molding compounds. The article also presents information on the application examples and market volume of compression molding.

Rough grinding and polishing of specimens are required to prepare fiber-reinforced composite samples for optical analysis. This article discusses the consumables, process variables, and the equipment that influence the sample preparation procedure. It describes the hand and automated grinding methods. The article summarizes the rough and final polishing steps for both hand and automated techniques. Common artifacts that may be created during grinding and polishing steps of composite samples are reviewed. These include scratches, fiber pull-out, matrix smears, streaks, erosion of different phases, and fiber and sample edge rounding and relief.