All refractory metals, except osmium and iridium, have the highest melting temperatures and lowest vapor pressures of all metals. This article discusses the commercial applications, and production procedures of refractory metals and alloys. These procedures include fabrication, machining, forming, cleaning, joining, and coatings. The article also presents information on, and specifications for, the following metals and their alloys: niobium, tantalum, molybdenum, tungsten, rhenium, and refractory metal fiber-reinforced composites. It discusses the processes involved in their production, their mechanical properties, physical properties, thermal properties, electrical properties, chemical properties, applications, and corrosion resistance.

Metal-matrix composites (MMCs) are a class of materials with potential for a wide variety of structural and thermal management applications. They are nonflammable, do not outgas in a vacuum, and suffer minimal attack by organic fluids, such as fuels and solvents. This article presents an overview of the status of MMCs, and provides information on physical and mechanical properties, processing methods, distinctive features, and various types of continuously and discontinuously reinforced aluminum, magnesium, titanium, copper, superalloy, and intermetallic-matrix composites. It further discusses the property prediction and processing methods for MMCs.

Metal-matrix composites (MMCs) are a class of materials with potential for a wide variety of structural and thermal applications. This article discusses the mechanical properties of MMCs, namely aluminum-matrix composites, titanium-matrix composites, magnesium-matrix composites, copper-matrix composites, superalloy-matrix composites, and intermetallic-matrix composites. It describes the processing methods of discontinuous aluminum MMCs which include casting processes, liquid-metal infiltration, spray deposition and powder metallurgy. The article provides useful information on aluminum MMC designation system and also describes the types of continuous fiber aluminum MMCs, including aluminum/boron MMC, aluminum/silicon carbide MMC, aluminum/graphite MMC, and aluminum/alumina MMC.

This article discusses the mechanisms for enhancing the reliability of three types of ceramic-matrix composites: discontinuously reinforced ceramic-matrix composites, continuous fiber ceramic composites, and carbon-carbon composites. It also presents examples of their mechanical and physical properties. Examples that illustrate the properties of commercially available materials are also provided.

The applications of discontinuously reinforced ceramic-matrix composites (CMCs) fall into four major categories, namely, cutting tool inserts; wear-resistant parts; aerospace and military applications; and other industrial applications, including engines and energy-related applications. This article provides examples for these four categories, with an emphasis on those applications/materials that have achieved commercial viability. The applications for continuous fiber ceramic composites are also summarized.

This article describes the manufacture, post-processing, fabrication, and properties of carbon-carbon composites (CCCs). Manufacturing techniques with respect to the processibility of different geometries of two-directional and multiaxial carbon fibers are listed in a table. The article discusses matrix precursor impregnants, liquid impregnation, and chemical vapor infiltration (CVI) for densification of CCCs. It presents various coating approaches for protecting CCCs, including pack cementation, chemical vapor deposition, and slurry coating. Practical limitations of coatings are also discussed. The article concludes with information on the mechanical properties of CCCs.

Ceramic-matrix composites (CMCs) are being developed for a number of high-temperature and high-performance applications in industrial, aerospace, and energy conservation sectors. This article focuses on processing, fabrication, testing, and characterization methods of CMCs, namely, discontinuously reinforced composites and continuous-fiber-reinforced composites. Processing methods include cold pressing, sintering, hot pressing, reaction bonding, melt infiltration, directed metal oxidation, sol-gel and polymer pyrolysis, self-propagating high-temperature synthesis and joining. A table summarizes the properties of various ceramic reinforcements and industrial applications of these composites.

Metal-matrix composites (MMCs) are a class of materials with a wide variety of structural, wear, and thermal management applications. This article discusses the primary processing methods used to manufacture discontinuous aluminum MMCs, namely, high-pressure die casting, pressure infiltration casting, liquid metal infiltration, spray deposition, and powder metallurgy methods. It describes the processing of continuous fiber-reinforced aluminum, discontinuously, reinforced titanium, and continuous fiber-reinforced titanium. The article concludes with information on work done to develop magnesium, copper, and superalloy MMCs.

Carbon-carbon is a unique composite material in which a nonstructural carbonaceous matrix is reinforced by carbon fibers to create a heat-resistant structural material that finds application in the aerospace and defense industries. This article provides a detailed account of the fundamentals of protecting carbon-carbon composites and explains the various coating deposition techniques, namely, pack cementation, chemical vapor deposition, and slurry coatings. It includes information on the practical limitations of coatings for the carbon-carbon composites.

Carbon-carbon composites (CCCs) are introduced in fields that require their high specific strength and stiffness, in combination with their thermoshock resistance, chemical resistance, and fracture toughness, especially at high temperatures. The use of CCCs has expanded as the price of carbon fibers has dropped and their mechanical properties have increased. This article begins with an overview of the carbon conversion processes, fiber properties and microstructures, and interfacial bonding and environmental interaction of carbon fibers, followed by a detailed discussion on the various techniques available for processing CCCs for specific applications, including preform fabrication (fiber weaving), densification, application of protective coatings, and joining. The article closes with a description of the mechanical and physical properties and applications of CCCs. The main applications of CCCs, in terms of money and mass, are in the military, space, and aircraft industries.

This article discusses the types, properties, and uses of continuous-fiber-reinforced composites, including glass, carbon, aramid, boron, continuous silicon carbide, and aluminum oxide fiber composites. While polyester and vinyl ester resins are the most used matrix materials for commercial applications, epoxy resins, bismaleimide resins, polyimide resins, and thermoplastic resins are used for aerospace applications. The article addresses design considerations as well as product forms and fabrication processes.

This article provides a discussion on various types of glasses: traditional glasses, specialty glasses, and glass ceramics. It provides information on glazes and enamels and reviews the broad classes of ceramic materials. These include whitewares, structural clay products, technical ceramics, refractories, structural ceramics, engineering ceramics, and electronic and magnetic ceramics. General processing variables that can affect structure and compositional homogeneity are discussed. Traditional ceramics that include both oxide and nonoxide ceramics are also reviewed. The article concludes with several examples of engineering ceramics.

Traditional ceramics, one of two general classes, are commonly used in high-volume manufacturing to make building materials, household products, and various industrial goods. Although there is a tendency to equate traditional ceramics with low technology, sophisticated processes and advanced manufacturing techniques are often used where these materials are employed. This article examines several traditional ceramics, including structural clay, whiteware, glazes, enamels, portland cements, and concrete. It also provides a detailed account of fabrication methods, properties, and applications. As an example, common applications for structural clay include facing materials, load-bearing units, pavers, and ceramic tiles.

Metal matrix composites (MMCs) can be synthesized by vapor phase, liquid phase, or solid phase processes. This article emphasizes the liquid phase processing where solid reinforcements are incorporated in the molten metal or alloy melt that is allowed to solidify to form a composite. It illustrates the three broad categories of MMCs depending on the aspect ratio of the reinforcing phase. The categories include continuous fiber-reinforced composites, discontinuous or short fiber-reinforced composites, and particle-reinforced composites. The article discusses the two main classes of solidification processing of composites, namely, stir casting and melt infiltration. It describes the effects of reinforcement present in the liquid alloy on solidification. The article examines the automotive, space, and electronic packaging applications of MMCs. It concludes with information on the development of select cast MMCs.

Metal-matrix composites (MMCs) are used in structural applications, and in applications requiring wear resistance, thermal management, and weight savings. This article summarizes the mechanical and thermal properties of discontinuously reinforced aluminum MMCs, laminated metallic composites, and continuously aligned fiber reinforced MMCs.

In general, metal-matrix composites (MMCs) are classified into three broad categories: continuous fiber-reinforced composites, discontinuous or short fiber-reinforced composites, and particle-reinforced composites. This article focuses on stir casting and melt infiltration as the two main methods of MMC solidification processing. It describes the MCC casting methods, such as sand and permanent mold casting, centrifugal casting, compocasting, and high-pressure die casting. The article discusses the MMC infiltration processes in terms of pressure infiltration casting and liquid metal infiltration. It reviews the powder metallurgy processing of aluminum MMCs and deformation processing of discontinuously reinforced aluminum composites. The article concludes with a discussion on the processing of fiber-reinforced aluminum.

Ceramic-matrix composites (CMCs) have ability to withstand high temperatures and have superior damage tolerance over monolithic ceramics. This article describes important processing techniques for CMCs: cold pressing, sintering, hot pressing, reaction-bonding, directed oxidation, in situ chemical reaction techniques, sol-gel techniques, pyrolysis, polymer infiltration, self-propagating high-temperature synthesis, and electrophoretic deposition. The advantages and disadvantages of each technique are highlighted to provide a comprehensive understanding of the achievements and challenges that remain in this area.

The selection of engineered materials is an integrated process that requires an understanding of the interaction between materials properties, manufacturing characteristics, design considerations, and the total life cycle of the product. This article classifies various engineered materials, including ferrous alloys, nonferrous alloys, ceramics, cermets and cemented carbides, engineering plastics, polymer-matrix composites, metal-matrix composites, ceramic-matrix and carbon-carbon composites, and reviews their general property characteristics and applications. It describes the synergy between the elements of the materials selection process and presents a general comparison of material properties. Finally, the article provides a short note on computer aided materials selection systems, which help in proper archiving of materials selection decisions for future reference.

This article begins with a discussion on fiber-reinforced composite materials and describes the generic behavior and structure/property relationships of composites. The article summarizes lamina properties and presents equations that help in the calculation of lamina properties. Composite laminates are constructed from lamina with uniaxial fiber orientation and frequently from textile fabrics as well. The article explains the characteristics of symmetric in-plane and through-thickness laminates; asymmetric in-plane and symmetric through-thickness laminates; asymmetric laminates; and curved laminates. It provides information on controlled thermal expansion composites, metal-matrix composites, and ceramic-matrix composites. The article illustrates the types of bonded joints and concludes with a discussion on design for manufacturing.