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Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006076
EISBN: 978-1-62708-175-7
... Abstract The two most important classes of materials that are manufactured via infiltration methods are copper- and silver-infiltrated refractory metals and refractory carbides, and copper-infiltrated steels. This article focuses on copper-infiltrated steels and discusses the basic requirements...
Abstract
The two most important classes of materials that are manufactured via infiltration methods are copper- and silver-infiltrated refractory metals and refractory carbides, and copper-infiltrated steels. This article focuses on copper-infiltrated steels and discusses the basic requirements for infiltration, which is a technique that is only applicable to material systems that meet certain requirements. It addresses these requirements and describes the conventional (partial) infiltration process of powder metallurgy (PM) steel. The materials used in the process, such as matrix and infiltrant, are discussed. The article also details several criteria used to evaluate the performance of an infiltration process. It concludes with information on alloy steels and fully infiltrated steels.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006052
EISBN: 978-1-62708-175-7
... Abstract This article discusses the methods and procedures used to extract, purify, and synthesize tungsten carbide powder, metal, and other refractory carbide/nitride powders used in hard metal production. Selection of powders, additives, equipment, and processes for making ready-to-press hard...
Abstract
This article discusses the methods and procedures used to extract, purify, and synthesize tungsten carbide powder, metal, and other refractory carbide/nitride powders used in hard metal production. Selection of powders, additives, equipment, and processes for making ready-to-press hard metal powders is also discussed. The article also provides information on the emerging technologies for tungsten carbide synthesis and binders in hard metal production, such as cobalt, iron, and nickel.
Book Chapter
Book: Machining
Series: ASM Handbook
Volume: 16
Publisher: ASM International
Published: 01 January 1989
DOI: 10.31399/asm.hb.v16.a0002123
EISBN: 978-1-62708-188-7
... of cobalt-rich solid solution that is strengthened by chromium and tungsten and is dispersion strengthened by complex, hard, refractory carbides of tungsten and chromium ( Ref 2 , 3 ). Nominal compositions for two commercially available grades are as follows: Element Alloy Tantung G, % Tantung...
Abstract
Cast cobalt alloys were developed to bridge the gap between high-speed steels and carbides. Although comparable in room-temperature hardness to high-speed steel tools, cast cobalt alloy tools retain their hardness to a much higher temperature and can be used at higher cutting speeds than high-speed steel tools. This article provides an overview of the processing, properties, and applications of these alloys.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001318
EISBN: 978-1-62708-170-2
... was an important contribution of this work. The investigation by Chown and coworkers of refractory carbides for protecting graphite ( Ref 22 ) was an important early contribution to coating technology. Their results showed that chemical vapor deposition (CVD) of SiC could provide reliable protection for long...
Abstract
Carbon-carbon is a unique composite material in which a nonstructural carbonaceous matrix is reinforced by carbon fibers to create a heat-resistant structural material that finds application in the aerospace and defense industries. This article provides a detailed account of the fundamentals of protecting carbon-carbon composites and explains the various coating deposition techniques, namely, pack cementation, chemical vapor deposition, and slurry coatings. It includes information on the practical limitations of coatings for the carbon-carbon composites.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001104
EISBN: 978-1-62708-162-7
... Abstract Cemented carbides belong to a class of hard, wear-resistant, refractory materials in which the hard carbide particles are bound together, or cemented, by a soft and ductile metal binder. The performance of cemented carbide as a cutting tool lies between that of tool steel and cermets...
Abstract
Cemented carbides belong to a class of hard, wear-resistant, refractory materials in which the hard carbide particles are bound together, or cemented, by a soft and ductile metal binder. The performance of cemented carbide as a cutting tool lies between that of tool steel and cermets. Almost 50% of the total production of cemented carbides is used for nonmetal cutting applications. Their properties also make them appropriate materials for structural components, including plungers, boring bars, powder compacting dies and punches, high-pressure dies and punches, and pulverizing hammers. This article discusses the manufacture, microstructure, composition, classifications, and physical and mechanical properties of cemented carbides, as well as their machining and nonmachining applications. It examines the relationship between the workpiece material, cutting tool and operational parameters, and provides suggestions to simplify the choice of cutting tool for a given machining application. It also examines new tool geometries, tailored substrates, and the application of thin, hard coatings to cemented carbides by chemical vapor deposition and physical vapor deposition. It discusses the tool wear mechanisms and the methods available for holding the carbide tool. The article is limited to tungsten carbide cobalt-base materials.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003152
EISBN: 978-1-62708-199-3
... Abstract Cemented carbides belong to a class of hard, wear-resistant, refractory materials in which the hard carbide particles are bound together, or cemented, by a ductile metal binder. Cermet refers to a composite of a ceramic material with a metallic binder. This article discusses...
Abstract
Cemented carbides belong to a class of hard, wear-resistant, refractory materials in which the hard carbide particles are bound together, or cemented, by a ductile metal binder. Cermet refers to a composite of a ceramic material with a metallic binder. This article discusses the manufacture, composition, classifications, and physical and mechanical properties of cemented carbides. It describes the application of hard coatings to cemented carbides by physical or chemical vapor deposition (PVD or CVD). Tungsten carbide-cobalt alloys, submicron tungsten carbide-cobalt alloys, and alloys containing tungsten carbide, titanium carbide, and cobalt are used for machining applications. The article also provides an overview of cermets used in machining applications.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006091
EISBN: 978-1-62708-175-7
..., properties, and performance of electrical contacts based on PM or hybrid composite technologies with refractory metals and compounds. These metals and compounds include tungsten, molybdenum, carbide-based composites, and silver-base composites. The article explains composite manufacturing methods, namely, PM...
Abstract
Electrical contacts are made of elemental metals, composites, or alloys that are made by the melt-cast method or manufactured by powder metallurgy (PM) processes. PM facilitates combinations of metals that ordinarily cannot be achieved by alloying. This article describes the processing, properties, and performance of electrical contacts based on PM or hybrid composite technologies with refractory metals and compounds. These metals and compounds include tungsten, molybdenum, carbide-based composites, and silver-base composites. The article explains composite manufacturing methods, namely, PM methods, internal oxidation, and hybrid consolidation. The availability of the refractory metals and compounds in various product forms are also reviewed.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003551
EISBN: 978-1-62708-180-1
... those chemical and physical properties that make them applicable for structures, or as components of systems, that are exposed to environments above 538 °C (1000 °F).” Nowadays, refractories are made of not only oxides and nonoxide compounds (carbides, nitrides, and carbons), but also of metallic...
Abstract
This article provides a discussion on the structural ceramics used in gas turbine components, the automotive and aerospace industries, or as heat exchangers in various segments of the chemical and power generation industries. It covers the fundamental aspects of chemical corrosion and describes the corrosion resistance characteristics of specific classes of refractories and structural ceramics. The article also examines the prevention strategies that minimize corrosion failures of both classes of materials.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 31 January 2025
DOI: 10.31399/asm.hb.v13b.a0007042
EISBN: 978-1-62708-183-2
... applicable for structures, or as components of systems, that are exposed to environments above 538 °C (1000 °F).” Refractories are made of not only oxides and nonoxide compounds (carbides, nitrides, and carbons) but also of metallic additions. The new generations of “black refractories,” which contain 7...
Abstract
This article provides a discussion on the corrosion of industrial refractory materials and technical ceramics. These materials, which are used to minimize heat losses and provide a barrier between the vessel and its contents, are utilized in the metallurgical, chemical process, power generation, automotive, and aerospace industries. The article covers the fundamental principles of chemical corrosion of refractories and ceramics, and the use of thermodynamic calculations and kinetic models to evaluate the probability of the occurrence of corrosion-causing chemical reactions. It describes the corrosion resistance characteristics of specific classes of refractories and structural ceramics. The article also examines the prevention strategies that minimize corrosion failures of both classes of materials.
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005629
EISBN: 978-1-62708-174-0
... for friction stir welding (FSW) pin tools, various tool geometries that have been used, designs for specific applications, predicting and measuring tool performance, and other considerations in FSW pin tool design. The tool materials include tool steels, superalloys, refractory metals, carbides and ceramics...
Abstract
A key differentiator between friction stir welding (FSW) and other friction welding processes is the presence of a nonconsumable tool in FSW, often referred to as a pin tool to differentiate it from other tooling associated with the process. This article discusses materials for friction stir welding (FSW) pin tools, various tool geometries that have been used, designs for specific applications, predicting and measuring tool performance, and other considerations in FSW pin tool design. The tool materials include tool steels, superalloys, refractory metals, carbides and ceramics, and superabrasives.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001105
EISBN: 978-1-62708-162-7
... oxide cermets, carbide and carbonitride cermets, boride cermets, and other refractory types. It describes the powder metallurgy process by which cermets are produced, examining each step from powder preparation to post treatment. It discusses forming and compacting, injection molding, extrusion, rolling...
Abstract
Ceramic-metal composites, or cermets, combine the heat and wear resistance of ceramics with the formability of metals, filling an application niche that includes cutting tools, brake pads, heat shields, and turbine components. This article examines a wide range of cermets, including oxide cermets, carbide and carbonitride cermets, boride cermets, and other refractory types. It describes the powder metallurgy process by which cermets are produced, examining each step from powder preparation to post treatment. It discusses forming and compacting, injection molding, extrusion, rolling, pressing, slip casting, and sintering. It also discusses fundamental concepts such as chemical bonding, chemical composition, microstructure, and the development of physical and mechanical properties.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006133
EISBN: 978-1-62708-175-7
... for common metal cutting operations; thus equipment must be more rigid and have greater torque to ensure optimal results. Carbide and, on occasion, cast cobalt tools give acceptable tool life and cutting properties. Tool sharpness is critical to cut refractory metals cleanly. Worn tools can tear the material...
Abstract
Refractory metals are typically processed from powders into ingots that are subsequently swaged into round bars or rolled into plates. Secondary operations are required to fabricate more complex refractory metal components. This article discusses two such secondary operations, namely, machining and joining processes for tungsten, tungsten heavy alloys, molybdenum, tantalum, niobium, and rhenium components. It describes the various types of metal joining processes, including mechanical fastening, brazing, and welding.
Book
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.9781627081832
EISBN: 978-1-62708-183-2
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003151
EISBN: 978-1-62708-199-3
... carbide cutting tools, and in a variety of tungsten-base chemicals. In terms of refractory metal consumption, tungsten ranks second to molybdenum. Cutting tools account for 59% of the total tungsten consumed; mill products, 26%; alloying, 9%; and chemicals and miscellaneous applications, 6%. Processing...
Abstract
The refractory metals include niobium, tantalum, molybdenum, tungsten, and rhenium. They are readily degraded by oxidizing environments at moderately low temperatures. Protective coating systems have been developed, mostly for niobium alloys, to permit their use in high-temperature oxidizing aerospace applications. This article discusses the properties, processing, applications, and classes of refractory metals and its alloys, namely molybdenum, tungsten, niobium, tantalum and rhenium. It also provides an outline of the coating processes used to improve their oxidation resistance.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001280
EISBN: 978-1-62708-170-2
... for wear plus impact service. Tungsten carbides wear well to about 590 °C (1000 °F) in air. At higher temperatures, chromium carbide and certain nickel-chromium alloys are used because of self-lubricating qualities. Coatings based on aluminum oxide, refractory carbides, and an oxidation-resistant metallic...
Abstract
Ceramic coatings are applied to metals to protect them against oxidation and corrosion at room temperature and at elevated temperatures. This article provides a detailed account of the factors to be considered when selecting a ceramic coating and describes the characteristics of various coating materials, namely, silicate glasses, oxides, carbides, silicides, and cermets. It reviews ceramic coating methods: brushing, spraying, dipping, flow coating, combustion flame spraying, plasma-arc flame spraying, detonation gun spraying, pack cementation, fluidized-bed deposition, vapor streaming, troweling, and electrophoresis. The article also includes information on the evaluation of the quality of ceramic coatings.
Book Chapter
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006123
EISBN: 978-1-62708-175-7
... for hexagonal close-packed (hcp) rhenium are quite different from those of the other metals, which are body-centered cubic (bcc). Unlike the others, rhenium does not form a carbide. Figures 1 and 2 compare the temperature-dependent ultimate tensile strengths and elastic moduli of the refractory metals...
Abstract
This article focuses on the selection, properties, and applications of powder metallurgy refractory metals and their alloys, including tungsten, molybdenum, tantalum, niobium, and rhenium.
Book: Machining
Series: ASM Handbook
Volume: 16
Publisher: ASM International
Published: 01 January 1989
DOI: 10.31399/asm.hb.v16.a0002190
EISBN: 978-1-62708-188-7
...-speed steel or carbide tools. The machining and grinding characteristics of tantalum vary from those of soft copper to those of annealed stainless steel. Fully recrystallized unalloyed tantalum has the machinability of soft copper. Tungsten Among the refractory metals, turning is a problem only...
Abstract
This article describes various machining techniques of refractory metals, namely, niobium, molybdenum, tantalum, and tungsten. These include turning, boring, trepanning, reaming, milling, tapping, drilling, and sawing. Parameters for the machining of the refractory metals are also tabulated. In addition, the article provides information on cutting fluids and tools that are used in machining of the refractory metals as well as on the safety precautions to be followed in the machining process.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003840
EISBN: 978-1-62708-183-2
... are zirconia, thoria, silicon nitride, boron nitride, and silicon carbide. Refractories are used as lining materials for heat and mass containment in high-temperature processing equipment such as furnaces and kilns. Some typical examples are silica, alumina, chromium oxide, calcium oxide, silicon nitride...
Abstract
This article provides an overview of the environmental performance of the most commonly used nonmetallic materials, including elastomers, plastics, thermosetting resins, resin-matrix composites, organic coatings, concrete, refractories, and ceramics. It also discusses the applications and uses of these materials.
Book Chapter
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003422
EISBN: 978-1-62708-195-5
... thermal mismatch stresses and low oxide-scale growth kinetics. In the higher temperature range, 1700 to 2200 °C (3090 to 3990 °F), refractory carbides and borides have been used for short time periods. Coating deposition techniques that have been used include pack cementation, CVD, and slurry processes...
Abstract
This article describes the manufacture, post-processing, fabrication, and properties of carbon-carbon composites (CCCs). Manufacturing techniques with respect to the processibility of different geometries of two-directional and multiaxial carbon fibers are listed in a table. The article discusses matrix precursor impregnants, liquid impregnation, and chemical vapor infiltration (CVI) for densification of CCCs. It presents various coating approaches for protecting CCCs, including pack cementation, chemical vapor deposition, and slurry coating. Practical limitations of coatings are also discussed. The article concludes with information on the mechanical properties of CCCs.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006099
EISBN: 978-1-62708-175-7
...) are tungsten-copper, tungsten-silver, molybdenum-copper, and molybdenum-silver systems, where the solubility of refractory metals in molten metal is minimal to practically nil, but wettability is excellent. These conditions are ideal for infiltration of refractory materials and tungsten carbide. Fixed-Cutter...
Abstract
This article provides information on the infiltration mechanism of carbide structures. It reviews the basic techniques used for metal infiltration, including dip infiltration, contact filtration, gravity feed infiltration, and external-pressure infiltration. The article highlights various applications of contact infiltration in oil, gas, and blast-hole drilling such as fixed-cutter drill bits and diamond-impregnated coring bits. It also discusses the applications of infiltrated carbide material in erosion-resistant cladding.
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