Search Results for reducing conditions

This article is a comprehensive collection of engineering property data in tabulated form for ceramics and glasses. Data are provided for physical and mechanical properties of ceramic materials and color of ceramics fired under oxidizing and reducing conditions. The article also lists the materials characterization techniques for ceramics and glasses.

The article provides an introduction on the importance of alloying elements on corrosion behavior of nickel alloys and describes the applications of heat-resistant alloys to resist corrosion. It focuses on the metallurgical effects, mainly the effect of internal factors, including chemical composition and microstructure of the alloy, and the external factors, including electrolyte composition, temperature, and electrode potential, on the corrosion behavior of corrosion-resistant alloys. The article also discusses the implication of changing the alloy microstructure by second-phase precipitation, cold working, and cast and wrought forms on the corrosion behavior of high-nickel alloys.

This article provides a discussion on the process descriptions, processing conditions, and processing variables of the most common chemical methods for metal powder production. These methods include oxide reduction, precipitation from solution, and thermal decomposition. Methods such as precipitation from salt solution and gas, chemical embrittlement, hydride decomposition, and thermite reactions are also discussed. The article also discusses the methods used to produce powders electrolytically and the types of metal powders produced. The physical and chemical characteristics of these powders are also reviewed.

This article discusses corrosion resistance of titanium and titanium alloys to different types of corrosion, including galvanic corrosion, crevice corrosion, stress-corrosion cracking (SCC), erosion-corrosion, cavitation, hot salt corrosion, accelerated crack propagation, and solid and liquid metal embrittlement. A short section discusses the addition of alloys that can improve the corrosion resistance of titanium.

The presence of certain impurities in coal and oil is responsible for the majority of fireside corrosion experienced in utility boilers. In coal, the primary impurities are sulfur, alkali metals, and chlorine. The most detrimental impurities in fuel oil are vanadium, sodium, sulfur, and chlorine. This article describes the two categories of fireside corrosion based on location in the furnace: waterwall corrosion in the lower furnace and fuel ash corrosion of superheaters and reheaters in the upper furnace. It discusses prevention methods, including changes to operating parameters and application of protective cladding or coatings.

This article discusses the procedures used for pickling nickel and nickel alloys. Nickel alloys can be divided into four groups: high-nickel alloys, nickel-copper alloys, nickel-chromium alloys, and nickel-iron-chromium alloys. Alloys within each composition group that has similar surface conditions are pickled in the same solutions using the same procedures. The article discusses three different surface conditions for pickling these nickel alloys: bright annealed white surface requiring removal of tarnish by flash pickling; bright annealed oxidized surface requiring removal of a layer of reduced oxide, sometimes followed by a flash pickle to brighten; and black or dark-colored surface requiring removal of adherent oxide film or scale. The article also reviews specialized pickling operations of nickel alloys and various cleaning and finishing operations, including grinding, polishing, buffing, brushing, and blasting.

Fretting is the small-amplitude oscillatory movement that can occur between contacting surfaces, which are nominally at rest. This article discusses fretting wear in mechanical components and the mechanisms of fretting wear. It describes the role of fretting conditions, such as fretting duration, slip amplitude, normal load, fretting frequency, contact geometry, type of vibration, and surface finish, as well as the role of environmental conditions. The article reviews the influence of an aqueous environment on the mechanism of fretting. The steps that can be taken to reduce or eliminate damage due to fretting are extremely diverse. The article presents some general indications of how to address the fretting wear problem.

When metal is exposed to an oxidizing gas at elevated temperature, corrosion can occur by direct reaction with the gas, without the need for the presence of a liquid electrolyte. This type of corrosion is referred to as high-temperature gaseous corrosion. This article describes the various forms of high-temperature gaseous corrosion, namely, high-temperature oxidation, sulfidation, carburization, corrosion by hydrogen, and hot corrosion.

This article reviews the corrosion behavior in various environments for seven important nickel alloy families: commercially pure nickel, Ni-Cu, Ni-Mo, Ni-Cr, Ni-Cr-Mo, Ni-Cr-Fe, and Ni-Fe-Cr. It examines the behavior of nickel alloys in corrosive media found in industrial settings. The corrosive media include: hydrochloric acid, sulfuric acid, phosphoric acid, hydrofluoric acid, hydrobromic acid, nitric acid, organic acids, salts, seawater, and alkalis. The modes of high-temperature corrosion include oxidation, carburization, metal dusting, sulfidation, nitridation, corrosion by halogens, and corrosion by molten salts. Applications where the corrosion properties of nickel alloys are important factors in materials selection include the petroleum, chemical, and electrical power industries. Most nickel alloys are much more resistant than the stainless steels to reducing acids, such as hydrochloric, and some are extremely resistant to the chloride-induced phenomena of pitting, crevice attack, and stress-corrosion cracking (to which the stainless steels are susceptible). Nickel alloys are also among the few metallic materials able to cope with hot hydrofluoric acid. The conditions where nickel alloys suffer environmentally assisted cracking are highly specific and therefore avoidable by proper design of the industrial components.

High-temperature exposure of materials occurs in many applications such as power plants (coal, oil, natural gas, and nuclear), land-based gas turbine and diesel engines, gas turbine engines for aircraft, marine gas turbine engines for shipboard use, waste incineration, high-temperature fuel cells, and missile components. This article discusses high-temperature corrosion in boilers, diesel engines, gas turbines, and waste incinerators. Boilers are affected by stress rupture failures, waterside corrosion failures, fireside corrosion failures, and environmental cracking failures. Contamination of combustion fuel in diesel engines can cause high-temperature corrosion. Gas turbine engines are affected by hot corrosion. Refractory-lined incinerators and alloy-lined incinerators are discussed. The article provides case studies for each component failure.

Two high-strength low-alloy (HSLA) families, acicular-ferrite steels and pearlite-reduced steels, contain microalloying additions of vanadium and niobium. Vanadium, niobium, and titanium combine preferentially with carbon and/or nitrogen to form a fine dispersion of precipitated particles in the steel matrix. This article summarizes the metallurgical effects of vanadium, niobium, molybdenum, and titanium. The metallurgical fundamentals were first applied to forgings in the early 1970s. The ultimate strength of first- and second-generation microalloy steels is adequate for many engineering applications, but these steels do not achieve the toughness of conventional quenched and tempered alloys under normal hot-forging conditions. Third-generation microalloy steels differ from their predecessors in that they are direct quenched from the forging temperature to produce microstructures of lath martensite with uniformly distributed temper carbides. Without subsequent heat treatment, these materials achieve properties, including toughness, similar to those of standard quenched and tempered steels.

Powder metallurgy (PM) stainless steels, as with conventional PM steels, are often used in the as-sintered condition. In addition to cost considerations, minimization of postsinter handling and secondary operations is also preferred because it reduces the potential for contamination of the parts with particulates and residues, which can result in the appearance of surface rust. This article provides information on various secondary operations, including tumbling, re-pressing, resin impregnation, annealing or heat treating, brazing, machining, and welding. It describes those aspects relating to welding of PM stainless steels, specifically, the effects of density, residual porosity, and sintered chemistry on weldability. Further, the article investigates the influence the sintering atmosphere has on machinability, as well as differences created by the presence of residual porosity.

Refractory metals are extracted from ore concentrates or scrap, processed into intermediate chemicals, and then reduced to metal, usually in powder form. This article discusses the raw materials needed and the processing steps for producing pure and alloyed refractory metal powders. The effects of processing conditions on the physical and chemical properties of tungsten, molybdenum, tantalum, niobium, and rhenium powders are reviewed.

This article explains how an engineer might go about assessing the risk of microbiologically influenced corrosion (MIC) in an industrial situation. It describes the systems that are susceptible to the effects of MIC by sulfate-reducing bacteria (SRB). The article discusses the effects of microorganisms other than SRB on metals. SRB-related problems, which are the most common MIC issue, are also explored. The article describes the test procedures used to enumerate microbiological populations. It concludes with a discussion on risk assessment based on operating conditions.

This article is a pictorial guide to forms of corrosion that draws attention to common pitfalls or situations that have caused premature corrosion, sometimes with expensive consequences. The examples used are not exhaustive; they highlight the necessity to fully examine materials, conditions, and specific circumstances that together can reduce the anticipated service life of a component or plant. The color images in this article are categorized according to the type of corrosion following the general order that is adopted in Volume 13A of ASM Handbook. The first table of the article provides a categorization of the forms of corrosion. It also provides a reference to articles or sections of articles in Volume 13A that detail the particular corrosion form or mechanism. The second table is a guide listing the figures in this article by material and by the corrosion form or mechanism illustrated.

The components used in light water reactors (LWR) often remain in contact with the primary coolant, whose typical temperatures and pressures are highly aggressive, therefore, initiating corrosion in most of the alloys. This article describes the corrosion behavior of zirconium alloys in water and heat flow conditions that causes irradiation on the zirconium alloy assemblies. It discusses the effect of irradiation on the microstructure and morphology of cladded linings. The article describes the impact of metallurgical parameters on the oxidation resistance of zirconium alloys. It concludes with a discussion on LWR coolant chemistry and corrosion of fuel rods in reactors.

Both hot and cold forgings are batch-type processes in which steady-state conditions are never fully achieved and the initial lubricant supply must perform adequately for the duration of the operation. This article discusses methods to measure lubricant effectiveness and wear. It describes the mixed-film lubrication and solid film lubrication in cold forging, as well as solid film lubrication and thick film lubrication in hot forging. The article reviews the factors affecting abrasive wear: die hardness, workpiece temperature, and lubrication and die temperature. It concludes with information on ways to improve resistance to abrasive wear.

This article addresses the long-term corrosion behavior of high-level waste (HLW) container materials, more specifically of the outer shell of the containers. It discusses time, environmental, and materials considerations for the emplacement of HLW in geological repositories. Environmental corrosion resistance of materials planned for reducing repositories is also discussed. The article reviews the design and characterization of nuclear waste repository with an oxidizing environment surrounding the waste package.