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The effect of a small addition of reactive elements (yttrium of zirconium) ...
Available to PurchasePublished: 01 January 1997
Fig. 5 The effect of a small addition of reactive elements (yttrium of zirconium) on scale adhesion and the 1100 °C (2010 °F) cyclic oxidation resistance of a model Ni-15Cr-13Al (wt%) coating alloy
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Image
The RCC process flow. (1) Wax pattern. (2) Shell is built on the wax patter...
Available to PurchasePublished: 01 January 2005
is filled with premixed ceramic grain. (5) For metal alloys containing highly reactive elements, the can may be sealed under vacuum. (6) Heated to hot pressing temperature, typically between 1030 and 1200 °C (1886 and 2192 °F), depending on the die alloy, and pressed for a few seconds. (7) Can is broken up
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Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003590
EISBN: 978-1-62708-182-5
... active elements so that only oxygen-inward transport occurs, leading to scale formation solely at the metal interface and reducing the growth stresses. Numerous mechanisms to explain the reactive- element effect were proposed ( Ref 10 ): A change in the transport properties of the oxide...
Abstract
This article examines the characteristics and behavior of scale produced by various types of oxidation. The basic models, concepts, processes, and open questions for high-temperature gaseous corrosion are presented. The article describes the development of geometrically induced growth stresses, transformation stresses, and thermal stresses in oxide scales. It discusses the ways in which stresses can be relieved. The article provides information on catastrophic oxidation, internal oxidation, sulfidation, alloy oxidation, selective oxidation, and concurrent oxidation. It illustrates the relationships between scale morphologies on binary alloys and concludes with a discussion on metal dusting and chlorine corrosion.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001081
EISBN: 978-1-62708-162-7
... and chemical properties, including chemical composition, corrosion resistance, and chemical reactivity. The article discusses the effects of alloying elements in titanium alloys, and describes the classes of titanium alloys, namely, alpha alloys, alpha-beta alloys, and beta alloys. It also describes...
Abstract
This article discusses the wrought product forms of titanium and titanium-base alloys, which include forgings and the typical mill products with tabulations for various specifications, and compares specifications for pure titanium, titanium alloys for mechanical, physical properties and chemical properties, including chemical composition, corrosion resistance, and chemical reactivity. The article discusses the effects of alloying elements in titanium alloys, and describes the classes of titanium alloys, namely, alpha alloys, alpha-beta alloys, and beta alloys. It also describes the typical applications of various titanium-base materials, and explains the crystal structure, effect of impurities, and microstructural constituents of titanium alloys. The article provides a brief description on the processing of wrought titanium alloys, including primary fabrication in which ingots are converted into general mill products and secondary fabrication (forging, extrusion, forming, machining, chemical milling and joining) of finished shapes from mill products and the heat treatment of titanium alloys.
Book: Machining
Series: ASM Handbook
Volume: 16
Publisher: ASM International
Published: 01 January 1989
DOI: 10.31399/asm.hb.v16.a0002189
EISBN: 978-1-62708-188-7
... Abstract This article focuses on the machining of reactive metals which refer collectively to the elements titanium, hafnium, and zirconium. It provides guidelines for machining titanium and titanium alloys and describes machining operations, such as turning, milling, drilling, tapping, reaming...
Abstract
This article focuses on the machining of reactive metals which refer collectively to the elements titanium, hafnium, and zirconium. It provides guidelines for machining titanium and titanium alloys and describes machining operations, such as turning, milling, drilling, tapping, reaming, grinding, and sawing, performed on titanium and its alloys. The article also provides information on electrochemical machining (ECM), chemical milling (CHM), and laser beam machining (LBM) for titanium and titanium alloys. Guidelines for machining zirconium alloys and hafnium are also provided. The article provides a short description of turning, milling, and drilling operations performed on zirconium alloys and hafnium. It also discusses health and safety considerations related to zirconium and hafnium.
Book Chapter
Introduction to Powder Metallurgy Stainless Steels
Available to PurchaseBook: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006066
EISBN: 978-1-62708-175-7
..., is a reactive element, and it has strong affinity for oxygen, carbon, and nitrogen. Because of this, greater care is necessary in the processing of PM stainless steels in order to avoid formation of undesirable phases and metallurgical defects. In wrought stainless steel metallurgy, oxygen, carbon, and nitrogen...
Abstract
Stainless steels are highly alloyed materials in comparison to most other popular powder metallurgy (PM) materials, such as low-alloy steels, copper alloys, and aluminum alloys. This article provides an overview of the history of PM stainless steels.
Book Chapter
Continuous Fiber Reinforcements for Metal-Matrix Composites
Available to PurchaseBook: Composites
Series: ASM Handbook Archive
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003359
EISBN: 978-1-62708-195-5
... applications, but the difficulties encountered relate to both the poor bond strength and high wetting angle between carbon and copper, necessitating the use of coatings or reactive elements to increase the bond strength. Generally, the low bond strength between carbon fibers and any of the common metals...
Abstract
For the reinforcement of metal-matrix composites, four general classes of materials are commercially available: oxide fibers based primarily on alumina and alumina silica systems, nonoxide systems based on silicon carbide, boron fibers, and carbon fibers. This article discusses the key aspects of aluminum oxide fibers, silicon carbide fibers, boron fibers, and carbon fibers. The commercial fibers for reinforcement of metal-matrix composites are presented in a table. A tabulation of the coating schemes for silicon carbide monofilament fibers is also provided.
Book Chapter
Design for Oxidation Resistance
Available to PurchaseSeries: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002473
EISBN: 978-1-62708-194-8
... and are occasionally present in engineering alloys or coatings. The phenomenon is especially important for single-crystal superalloys, which have the potential of being very oxidation resistant, but are not easily manufactured with yttrium. Fig. 5 The effect of a small addition of reactive elements (yttrium...
Abstract
Alloys intended for use in high-temperature environments rely on the formation of a continuous, compact, slow-growing oxide layer for oxidation, and hot corrosion resistance. This article focuses on the issues related to high-temperature oxidation of superalloys used in gas turbine engine applications. It discusses the general methodologies used to evaluate oxidation resistance of materials. The article describes the performance characteristics of superalloys, single-crystal superalloys, and other high-temperature materials such as refractory metals and ceramics. It discusses hot corrosion of superalloys and airfoil degradation due to deposits resulting from ingested particles or sand. The article concludes with a discussion on the limitations of testing techniques and life prediction.
Book Chapter
Vacuum Induction Melting
Available to PurchaseBook: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005200
EISBN: 978-1-62708-187-0
.... Commercial vacuum induction melting (VIM) was developed in the early 1950s, having been stimulated by the need to produce superalloys containing reactive elements within an evacuated atmosphere. The process is relatively flexible, featuring the independent control of time, temperature, pressure, and mass...
Abstract
Vacuum induction melting (VIM) is often done as a primary melting operation followed by secondary melting (remelting) operations. This article presents the process description of VIM and illustrates potential processing routes for products, which are cast from VIM ingots or electrodes. It describes the VIM refinement process, which includes the removal of trace elements, nitrogen and hydrogen degassing, and deoxidation. The article concludes with information on the production of nonferrous materials by VIM.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005204
EISBN: 978-1-62708-187-0
... (for example, for refractory metals), vacuum arc melting and remelting (for reactive metals and superalloys), and electroslag melting and vacuum induction melting (for superalloys, specialty steels, and nonferrous metals). Some advantages and limitations of the competing vacuum processes are given in Table 1...
Abstract
Electron beam melting includes melting, refining, and conversion processes for metals and alloys. This article describes the electron beam melting process, as well as the principles, equipment, and process considerations of drip melting and cold hearth melting process.
Book Chapter
Solidification of Eutectic Alloys: Cast Iron
Available to PurchaseBook: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005213
EISBN: 978-1-62708-187-0
... boundary illustrates that the (1010) faces grow by nucleation of planes at the step. Source: Ref 37 When weak, reactive impurities such as sulfur are present in the melt, a contaminated environment occurs. These elements change the edge energy of steps, resulting in a relative position change...
Abstract
Cast iron exhibits a considerable amount of eutectic in the solid state. This article discusses the structure of liquid iron-carbon alloys to understand the mechanism of the solidification of cast iron. It illustrates the nucleation of the austenite-flake graphite eutectic, austenite-spheroidal graphite eutectic, and austenite-iron carbide eutectic. The article provides a discussion on primary austenite and primary graphite. It also describes the growth of eutectic in cast iron in terms of isothermal solidification, directional solidification, and multidirectional solidification.
Book Chapter
High-Temperature Corrosion-Related Failures
Available to PurchaseSeries: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006787
EISBN: 978-1-62708-295-2
.... Once sulfur has reacted with the alloy, sulfur tends to react preferentially with chromium or aluminum to form sulfides; this can cause redistribution of the scale-forming elements or interfere with the formation of protective oxide scales. Nickel-chromium alloys have been successfully used at service...
Abstract
High-temperature corrosion can occur in numerous environments and is affected by various parameters such as temperature, alloy and protective coating compositions, stress, time, and gas composition. This article discusses the primary mechanisms of high-temperature corrosion, namely oxidation, carburization, metal dusting, nitridation, carbonitridation, sulfidation, and chloridation. Several other potential degradation processes, namely hot corrosion, hydrogen interactions, molten salts, aging, molten sand, erosion-corrosion, and environmental cracking, are discussed under boiler tube failures, molten salts for energy storage, and degradation and failures in gas turbines. The article describes the effects of environment on aero gas turbine engines and provides an overview of aging, diffusion, and interdiffusion phenomena. It also discusses the processes involved in high-temperature coatings that improve performance of superalloy.
Image
Schematic of the change in the growth rate of graphite due to the absorptio...
Available to PurchasePublished: 01 December 2008
Fig. 25 Schematic of the change in the growth rate of graphite due to the absorption of foreign atoms in spheroidal graphite eutectic. Three variations of an Fe-C-Si cast iron are as follows. (a) With nodularizer added as reactive impurity environment. (b) Pure environment. (c) Contaminated
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Book Chapter
Vacuum Deposition, Reactive Evaporation, and Gas Evaporation
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001287
EISBN: 978-1-62708-170-2
... Abstract This article discusses the fundamentals of thermal vaporization and condensation and provides information on the various vaporization sources and methods of vacuum deposition. It offers an overview of reactive evaporation and its deposition techniques. The article also explains...
Abstract
This article discusses the fundamentals of thermal vaporization and condensation and provides information on the various vaporization sources and methods of vacuum deposition. It offers an overview of reactive evaporation and its deposition techniques. The article also explains the advantages, limitations, and applications of vacuum deposition processes. Finally, it provides information on the gas evaporation process, its processing chamber, and related systems.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005338
EISBN: 978-1-62708-187-0
... and chemical properties of zirconium castings. Zirconium Reactivity Considerations Zirconium has a melting point of 1852 °C (3365 °F). It reacts vigorously with interstitial elements (e.g., hydrogen, nitrogen, oxygen, and carbon) at elevated temperatures. This reaction begins to occur at temperatures...
Abstract
This article describes typical foundry practices used to commercially produce zirconium castings. The foundry practices are divided into two sections, namely, melting and casting. The article discusses various melting processes, such as vacuum arc skull melting, induction skull melting, and vacuum induction melting. Various casting processes, such as rammed graphite casting, static and centrifugal casting, and investment casting are reviewed. The article also provides information on the mechanical and chemical properties of zirconium castings.
Book Chapter
Electroslag Remelting
Available to PurchaseBook: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005201
EISBN: 978-1-62708-187-0
... current must travel. An additional consideration is the degree of chemical reactivity of the slag with elemental components of the electrode. Figure 6 is a nominal plot of process parameters for the remelting of a nickel-base alloy. Figure 7 shows voltage swings and the major control parameters...
Abstract
Electroslag remelting (ESR) is commonly used to produce the highest levels of quality in plate steels, particularly in thick plates. This article provides an overview of the ESR and discusses the major components and operations of the ESR furnaces. It describes the principles of ingot solidification and the various defects of remelted ingot such as tree ring patterns, freckles, and white spots. The article explains several variations of ESR such as pressure electroslag remelting, remelting under reduced pressure, and electroslag rapid remelting. It also examines the features of steel ESR and superalloy ESR.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001441
EISBN: 978-1-62708-173-3
... titanium and austenitic stainless steels. Zirconium has a low coefficient of thermal expansion, which contributes to low distortion during welding. Because of the reactivity of zirconium with oxygen, nitrogen, and hydrogen, the metal must be shielded during welding with high-purity inert gas or a good...
Abstract
Zirconium and its alloys are available in two general categories: commercial grade and reactor grade. This article discusses the welding processes that can be used for welding any of the zirconium alloys. These include gas-tungsten arc welding (GTAW), gas-metal arc welding (GMAW), plasma arc welding (PAW), electron-beam welding (EBW), laser-beam welding (LBW), friction welding (FRW), resistance welding (RW), resistance spot welding (RSW), and resistance seam welding (RSEW). The article reviews the selection of shielding gases and filler metals for welding zirconium alloys. It concludes with a discussion on process procedures for welding zirconium alloys.
Book Chapter
Introduction to Corrosion of Nonferrous Metals and Specialty Products
Available to PurchaseBook: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003814
EISBN: 978-1-62708-183-2
... easily be categorized by elemental base. aluminum copper corrosion resistance nickel nonferrous metals titanium NONFERROUS METALS AND ALLOYS are widely used to resist corrosion. At one end of the spectrum, they are used for water piping and food preparation. At the other end...
Abstract
Nonferrous metals and alloys are widely used to resist corrosion. This article describes the corrosion behavior of the most widely used nonferrous metals, such as aluminum, copper, nickel, and titanium. It also provides information on several specialty nonferrous products that cannot easily be categorized by elemental base.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001774
EISBN: 978-1-62708-178-8
... Al + signal in a dirty vacuum or in the presence of an intentional oxygen leak than in a nonreactive UHV environment. Therefore, most modern approaches to SIMS analysis—at least when quantitative elemental analysis is of interest—use reactive primary ion beams rather than inert ion beams; an oxygen...
Abstract
In secondary ion mass spectroscopy (SIMS), an energetic beam of focused ions is directed at the sample surface in a high or ultrahigh vacuum (UHV) environment. The transfer of momentum from the impinging primary ions to the sample surface causes sputtering of surface atoms and molecules. This article focuses on the principles and applications of high sputter rate dynamic SIMS for depth profiling and bulk impurity analysis. It provides information on broad-beam instruments, ion microprobes, and ion microscopes, detailing their system components with illustrations. The article graphically illustrates the SIMS spectra and depth profiles of various materials. The quantitative analysis of ion-implantation profiles, instrumental features required for secondary ion imaging, the analysis of nonmetallic samples, detection sensitivity, and the applications of SIMS are also discussed.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005203
EISBN: 978-1-62708-187-0
... in a vacuum/inert gas chamber. The chamber and vacuum or inert gas backfill is essential to avoid excessive oxidation of the reactive alloy elements, particularly titanium. Directly below the furnace is a centrifuge table that the molds are mounted on so that the molds can be centrifuged during filling...
Abstract
Skull melting refers to the use of furnaces with water-cooled crucibles that freeze a solid “skull” of material on the crucible wall. This article describes the basic components, operating pressure, advantages, and applications of vacuum arc and induction skull melting furnaces.
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