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radiolysis
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in Effect of Irradiation on Stress-Corrosion Cracking and Corrosion in Light Water Reactors
> Corrosion: Environments and Industries
Published: 01 January 2006
Fig. 7 (a) The relationship between the H 2 concentration in the feedwater and the H 2 injection flow (straight line, round data points). The descending curve (square data points) is H 2 generated by radiolysis, which decreases as H 2 is injected due to suppression of radiolysis. The curve
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Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004147
EISBN: 978-1-62708-184-9
... for irradiation-assisted stress-corrosion cracking. The article addresses the effects of various radiation factors on corrosion. These include radiation-induced segregation at grain boundaries, radiation hardening, mode of deformation, radiation creep relaxation, and radiolysis. The article discusses a variety...
Abstract
This article examines the understanding of persistent material changes produced in stainless alloys during light water reactor (LWR) irradiation based on the fundamentals of radiation damage and existing experimental measurements. It summarizes the overall trends and correlations for irradiation-assisted stress-corrosion cracking. The article addresses the effects of various radiation factors on corrosion. These include radiation-induced segregation at grain boundaries, radiation hardening, mode of deformation, radiation creep relaxation, and radiolysis. The article discusses a variety of approaches for mitigating stress-corrosion cracking in LWRs, in categories of water chemistry, operating guidelines, new alloys, design issues, and stress mitigation. It concludes with a discussion on the irradiation effects of irradiation on corrosion of zirconium alloys in LWR environments.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004148
EISBN: 978-1-62708-184-9
...,” this phenomenon only occurs under irradiation and cannot be duplicated without neutron or gamma flux ( Ref 16 ). Local irradiation enhanced radiolysis has been suggested to explain the phenomenon ( Ref 17 ), but local electrochemical conditions under irradiation are now considered as the critical parameter...
Abstract
The components used in light water reactors (LWR) often remain in contact with the primary coolant, whose typical temperatures and pressures are highly aggressive, therefore, initiating corrosion in most of the alloys. This article describes the corrosion behavior of zirconium alloys in water and heat flow conditions that causes irradiation on the zirconium alloy assemblies. It discusses the effect of irradiation on the microstructure and morphology of cladded linings. The article describes the impact of metallurgical parameters on the oxidation resistance of zirconium alloys. It concludes with a discussion on LWR coolant chemistry and corrosion of fuel rods in reactors.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004149
EISBN: 978-1-62708-184-9
.... It has been suggested that radiation may produce changes in the external environment, for example by controlling microbial activity or radiolysis of ground water. Currently, the United States plans to accept the most active waste for disposal (5 years out of reactor). This waste will produce maximum dose...
Abstract
This article addresses the long-term corrosion behavior of high-level waste (HLW) container materials, more specifically of the outer shell of the containers. It discusses time, environmental, and materials considerations for the emplacement of HLW in geological repositories. Environmental corrosion resistance of materials planned for reducing repositories is also discussed. The article reviews the design and characterization of nuclear waste repository with an oxidizing environment surrounding the waste package.
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005676
EISBN: 978-1-62708-198-6
... Thermooxidative Solvolysis Hydrolysis Alcoholysis Aminolysis, etc. Photolysis Visible Ultraviolet Radiolysis Gamma rays X-rays Electrobeam Fracture-induced radical reactions Source: Ref 7 Design When developing new products, engineers must consider...
Abstract
Polymers offer a wide range of choices for medical applications because of their versatility in properties and processing. This article provides an overview of polymeric materials and the characteristics that make them a unique class of materials. It describes the ways to classify polymers, including the polymerization method, how the material deforms, or molecular origin or stability. The article contains tables that list common medical polymers used in medical devices. It explains the medical polymer selection criteria and regulatory aspects of materials selection failure analysis and prevention. Failure analysis and prevention processes to determine the root cause of failures that arise at different stages of the product life cycle are reviewed. The article describes the mechanisms of plastic product failure analysis. It discusses the trends in the use of medical polymers, such as high-performance polymers for implants, tissue engineering, and bioresorbable polymers.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004146
EISBN: 978-1-62708-184-9
... redox potential, as determined by the hydrogen partial pressure and the solution pH ( Fig. 2 ) ( Ref 1 ). By contrast, in direct cycle BWR systems, significant concentrations of oxygen and hydrogen peroxide are present as the end products of water radiolysis (which may be reduced by hydrogen additions...
Abstract
This article discusses the main materials and water chemistry characteristics of the primary and secondary water circuits of a pressurized water reactor (PWR). It reviews the corrosion issues of PWR materials and the influence of corrosion and fouling on primary and secondary circuit radiation fields. The article explains the primary side intergranular stress corrosion cracking (IGSCC) in different materials, namely, nickel-base alloys, high-strength nickel-base alloys, low-strength austenitic stainless steels, and high-strength stainless steels. The secondary side corrosion in steam generator including denting, pitting, intergranular attack and IGSCC is also discussed. The article examines laboratory studies that have resulted in models and computer codes for evaluating and predicting intergranular corrosion, and considers the remedial actions for preventing or arresting intergranular corrosion. It concludes with information on the external bolting corrosion in nuclear power reactors.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006677
EISBN: 978-1-62708-213-6
Abstract
This article is intended to provide the reader with a good understanding of the underlying science, technology, and the most common applications of focused ion beam (FIB) instruments. It begins with a survey of the various types of FIB instruments and their configurations, discusses the essential components, and explains their function only to the extent that it helps the operator obtain the desired results. An explanation of how the components of ion optical column shape and steer the ion beam to the desired target locations is then provided. The article also reviews the many diverse accessories and options that enable the instrument to realize its full potential across all of the varied applications. This is followed by a detailed analysis of the physical processes associated with the ion beam interacting with the sample. Finally, a complete survey of the most prominent FIB applications is presented.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006811
EISBN: 978-1-62708-329-4
Abstract
Bearing in mind the three-legged stool approach of device design/manufacturing, patient factors, and surgical technique, this article aims to inform the failure analyst of the metallurgical and materials engineering aspects of a medical device failure investigation. It focuses on the device "failures" that include fracture, wear, and corrosion. The article first discusses failure modes of long-term orthopedic and cardiovascular implants. The article then focuses on short-term implants, typically bone screws and plates. Lastly, failure modes of surgical tools are discussed. The conclusion of this article presents several case studies illustrating the various failure modes discussed throughout.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004145
EISBN: 978-1-62708-184-9
... for nonsensitized stainless steels in simulated boiling water reactor water at 288 °C (550 °F) as a function of yield stress. Source: Ref 56 Environmental Factors The recirculating water coolant in a BWR undergoes radiolysis in the reactor core. The majority of the hydrogen produced in this process...
Abstract
This article focuses on the environmentally assisted cracking (EAC) of structural materials in boiling water reactors (BWRs), reactor pressure vessels, core internals, and ancillary piping. It discusses the effects of water chemistry on materials degradation, mitigation approaches, and their impact on aging management programs. The article reviews the effects of materials, environment, and stress factors on the cracking susceptibility of ferritic and austenitic structural alloys in BWRs. It describes the methods, such as data-based life-prediction approaches and mechanisms-informed life-prediction approaches, for predicting cracking kinetics in BWRs. The article provides information on several EAC mitigation techniques for BWR components, namely material solutions, stress solutions, and environmental solutions.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.9781627083294
EISBN: 978-1-62708-329-4
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.9781627082136
EISBN: 978-1-62708-213-6