Paints and protective coatings are the most common means of protecting materials from deterioration. This article focuses on coating degradation that results from the environmental interaction with the coatings. The major environmental influences of the degradation include energy (solar radiation, heat and temperature variation, and nuclear radiation), permeation (moisture, solvent retention, chemical, and oxygen), stress (drying and curing, vibration, and impact and abrasion), and biological influences (microbiological and macrobiological).

This article discusses the environmental influences on protective coating films that can result in deterioration. These environmental factors can be classified into four groups: (1) energy: solar, heat; (2) permeation: moisture, solvent, chemical, and gas; (3) stress: drying and curing-internal stress, and vibration-external stress; and (4) biological influences such as microbiological, mildew, and marine fouling.

This article provides background information on the chemistry, coating properties, resin types, applications techniques, and performance characteristics of fluoroethylene vinyl ether (FEVE) resins. It describes the formulation methods of FEVE resins, namely, solvent-based coating formulations, water-based coating formulations, and powder coating formulations. The basic concerns to be addressed when formulating and using FEVE coatings are also discussed. The article concludes with a section on health and related safety regulations.

Painting is a generic term for the application of a thin organic coating to the surface of a material for decorative, protective, or functional purposes. This article provides a detailed account of the types and selection factors of paints and the various application methods, including conventional air atomized, airless, and electrostatic spray; roller coating; dip coating; flow coating; curtain coating; tumble coating; electrocoating; and powder coating. Surface preparation methods and prepaint treatments for coating systems are also discussed. The article includes information on quality control procedures, causes of paint film defects, cost calculation, and safety and environmental precautions. The composition and characteristics of organic coatings, coating system selection factors, the types of paints for structural steel, and the applications of paint on structural steel are also reviewed.

This article provides a discussion on polyester coating applications such as powder coatings, can coatings, and automotive paints. It includes an overview, structure, properties, and benefits of vinyl ester resins. The article discusses the additives for both unsaturated polyester and vinyl ester coatings, namely, curing systems, thixotropic agents and fillers. It exemplifies polyester and vinyl ester coating, lining and flooring systems that are used for top-to-bottom protection of industrial plants and equipment. The article also highlights the concerns to be addressed when using polyesters and vinyl esters.

Powder coatings are widely used by manufacturers as a finish of choice to enhance the appearance and performance of their products. This article begins with a discussion on advantages and disadvantages of powder coatings. It describes the selection of coating-types and uses of powder coatings in appliance industries, furniture industries, computer industries, fixture industries, architectural industries, automotive industries, agriculture and construction equipment industries, recreational equipment industries, and general industries. Powder coating formulations consist of binder systems, pigments, extenders, and additives. The basic process flow for the manufacture of powder coatings consists of premix, extrusion, grinding, and packing. The article also provides information on application of powder coatings, including pretreatment, deposition, and curing as well as on troubleshooting, trends and challenges for the powder coatings.

This article provides a detailed discussion on the principal classes and curatives of epoxy resins used in the coatings industry. The principal classes are bisphenol A epoxy, bisphenol F epoxy, epoxy phenol novolac, cycloaliphatic epoxies, epoxy acrylate, brominated bisphenol-A-based epoxy, phosphorus-containing epoxy, fluorinated epoxies, epoxy esters, epoxy phosphate esters, and waterborne epoxy. The principal curatives are amines, amine adducts, cyanoethylated amines, ketimines, polyoxyalkylene amines, cycloaliphatic amines, aromatic amines, polyamides, amido amines, and dicyandiamides. Other curatives include polyester co-polymers, phenolic co-polymers, melamine and urea formaldehyde co-polymer resins, phosphate flame retardants, ultraviolet and electron beam curing of epoxy resins, Mannich bases, Mannich-based adducts, and anhydrides. The article concludes by discussing the concerns regarding the use of epoxy coatings.

This article provides an overview of the environmental performance of the most commonly used nonmetallic materials, including elastomers, plastics, thermosetting resins, resin-matrix composites, organic coatings, concrete, refractories, and ceramics. It also discusses the applications and uses of these materials.

Functional fusion-bonded epoxy (FBE) coatings are used as external pipe coatings, base layer for three-layer pipe-coating systems, internal pipe linings, and corrosion coatings for concrete reinforcing steel (rebar). This article provides information on the chemistries of FBE, and discusses the application procedures for internal and external FBE pipe coating. The procedures involve pipe inspection, surface preparation, heating, powder application, curing, cooling, coating inspection, and repairing. It describes the problems and solutions for FBE external pipe coatings, girth weld FBE application, FBE custom coatings, internal FBE pipe linings, and FBE rebar coatings.

This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.

This article focuses on technologies in the protective coatings field, namely, polysiloxane hybrids and related materials. Industrial maintenance topcoats, including silicone alkyds, silicone epoxies, and polysiloxanes are reviewed. The article discusses two major application areas of protective coatings, namely, architectural coatings and automotive clear coats.

A coating can be defined as a substance spread over a surface to provide protection or to serve decorative purposes. This article discusses two industrial coating components, namely, nonvolatile components such as the resin or binder, pigments, and any additives that may be incorporated into the formulation; and volatile components such as solvents, or water in emulsions and their composition. It provides general information on volatile organic compounds. The article describes the film-forming mechanisms of various coating types, namely, lacquers, chemically converting coatings, latex coatings, alkyds and other resins, which cure by oxidation, moisture-curing polyurethanes and inorganic zinc primers, and powder coatings. The article concludes with a discussion on the functions of the primer, intermediate coat, and topcoat in coating systems.

Surface coatings are essential in all facilities that process nuclear materials or use nuclear fission for power generation. This article describes the coatings used in two basic types of Generation 3 nuclear reactor designs in the United States and their containment size. These reactors are the boiling water reactor (BWR) and pressurized water reactor (PWR). The article provides information on the loss-of-coolant accident (LOCA) identified as the design basis accident (DBA), which can rapidly de-water the core of an operating nuclear reactor. To avoid LOCA, both the BWR and the PWR include emergency core cooling systems. The article describes a DBA test and other coating performance parameters necessary for safety-related coating systems. It provides a detailed account of the selection criteria of coating types in a nuclear plant. The article concludes by highlighting protective coating strategies in Generation 3 Plants.

This article provides an overview of common analytical tools used as part of the process of providing practical information regarding the causes of a coating problem or failure. The common analytical tools include Fourier transform infrared spectroscopy, differential scanning calorimetry, scanning electron microscopy-energy dispersive X-ray spectroscopy, chromatography, and electrochemical impedance spectroscopy. Test cabinets and standard test environments for laboratory analysis are reviewed. The article describes non-standard simulation testing and case studies of simulated environments for coating failure analysis.

This article discusses the three basic elements of an epoxy resin formulation that must be understood when selecting a thermoset system. These include base resins, epoxy resin curatives, and modifiers. The article provides examples of epoxy resin formulations that illustrate how raw materials are combined to tailor a formulation to a specific application. It concludes with a discussion on general guidelines for the safe handling of epoxy resins and their associated products.

Cyanate ester resins are a family of high-temperature thermosetting resins that bridge the gap in thermal performance between engineering epoxy and high-temperature polyimides. This article discusses the chemistry, properties and characteristics of the cyanate ester resins. It describes the processing procedures for the cyanate ester resins and provides information on properties for selected applications, such as space applications, radomes, and printed circuit boards.

This article is an informative primer on sealants and the role they play in engineered assemblies. It discusses the physical, thermal, chemical, and electrical properties of sealant materials and the various forms in which they are applied, including liquids, pastes, and extruded tapes. It also describes classifications and types, comparing and contrasting sealants made from oil-based caulks, asphalts, coal tar resins, latex acrylic sealants, polyvinyl acetate caulks, solvent acrylics, butyl sealants, polysulfides, polyurethanes, modified silicones, anaerobics, vinyl plastisols, and polypropylenes. In addition, the article provides practical design insight, addressing application requirements, seal configurations, and joint stresses. It concludes with a brief discussion on the use of sealants in aerospace, automotive, electrical, and construction applications.

Although aluminum alloys are inherently corrosion resistant, there are many operating environments where they require additional protection. This article describes the conditions under which aluminum is prone to corrode and explains how to prevent it through the addition of conversion coatings and paints. It addresses some of the more common corrosion mechanisms, including corrosion driven by pH extremes, pitting corrosion, crevice corrosion, galvanic corrosion, and filiform corrosion. The article also describes in-plant as well as field application procedures for cleaning and coating, and discusses the advantages and limitations of the various materials and chemicals used.

This article provides a detailed discussion on the functions, applications, types, and selection criteria of exterior and interior rail coatings. It includes a discussion on the corrosivity, inspection/maintenance, and qualification of applicators/inspectors/facilities.

Open molding is the method used in the polymer-matrix composites industry to make thermoset composite products. This article discusses the advantages, disadvantages, and applications of the open molding. It describes the various process of the open molding, such as hand lay-up process and spray-up process. Workmanship for hand lay-up and spray-up processes is reviewed. The article provides information on the matrix-resin materials used for open molding, including unsaturated polyester resins, epoxy vinyl ester resins, and reinforcements. It explains the component design and short- and long-term properties of a fiber reinforced composite laminate depending on material selection and workmanship. The article also presents the basic design guidelines for open molding.