This article examines the understanding of persistent material changes produced in stainless alloys during light water reactor (LWR) irradiation based on the fundamentals of radiation damage and existing experimental measurements. It summarizes the overall trends and correlations for irradiation-assisted stress-corrosion cracking. The article addresses the effects of various radiation factors on corrosion. These include radiation-induced segregation at grain boundaries, radiation hardening, mode of deformation, radiation creep relaxation, and radiolysis. The article discusses a variety of approaches for mitigating stress-corrosion cracking in LWRs, in categories of water chemistry, operating guidelines, new alloys, design issues, and stress mitigation. It concludes with a discussion on the irradiation effects of irradiation on corrosion of zirconium alloys in LWR environments.

Copper and copper alloys are used extensively in structural applications in which they are subject to moderately elevated temperatures. At relatively low operating temperatures, these alloys can undergo thermal softening or stress relaxation, which can lead to service failures. This article is a collection of curves and tables that present data on thermal softening and stress-relaxation in copper and copper alloys. Thermal softening occurs over extended periods at temperatures lower than those inducing recrystallization in commercial heat treatments. Stress relaxation occurs because of the transformation of elastic strain in the material to plastic, or permanent strain.

This article reviews the basic equipment and methods for creep and creep rupture testing. It begins with a discussion on the creep properties, including stress and temperature dependence, as well as of the extrapolation techniques that permit estimation of the long-term creep and rupture strengths of materials. The article describes the different types of equipment for determination of creep characteristics, including test stands, furnaces, and extensometers. It also discusses the different testing methods for creep rupture: constant-load testing and constant-stress testing. The article presents other testing considerations and concludes with information on stress relaxation testing.

This article reviews the basic mechanisms of elevated-temperature behavior and associated design considerations, with an emphasis on metals. It discusses the key concepts of elevated-temperature design. These include plastic instability at elevated temperatures; deformation mechanisms and strain components associated with creep processes; stress and temperature dependence; fracture at elevated temperatures; and environmental effects. The article describes the basic presentation and analysis methods for creep rupture. It provides information on the application of these methods to materials selection and the setting of basic design rules. The article examines the limitations of high-temperature components as well as the alternative design approaches and tests for most high-temperature components.

The article commences with an overview of short-term and long-term mechanical properties of polymeric materials. It discusses plasticization, solvation, and swelling in rubber products. The article further describes environmental stress cracking and degradation of polymers. It illustrates how surface degradation of a plain strain tension specimen alters the ductile brittle transition in polyethylene creep rupture. The article concludes with information on the effects of temperature on polymer performance.

The lifetime assessment of polymeric products is complicated, and if the methodology utilized leads to inaccurate predictions, the mistakes could lead to financial loss as well as potential loss of life, depending on the service application of the product. This article provides information on the common aging mechanisms of polymeric materials and the common accelerated testing methods used to obtain relevant data that are used with the prediction models that enable service life assessment. Beginning with a discussion of what constitutes a product failure, this article then reviews four of the eight major aging mechanisms, namely environmental stress cracking, chemical degradation, creep, and fatigue, as well as the methods used in product service lifetime assessment for them. Later, several methods of service lifetime prediction that have gained industry-wide acceptance, namely the hydrostatic design basis approach, Miner's rule, the Arrhenius model, and the Paris Law for fatigue crack propagation, are discussed.

This article describes the phenomena of crack initiation and early growth. It examines specimen design and preparation as well as the apparatus used in crack initiation testing. The article provides descriptions of the various commercially available fatigue testing machines: axial fatigue testing machines and bending fatigue machines. Load cells, grips and alignment devices, extensometry and strain measuring devices, environmental chambers, graphic recorders, furnaces, and heating systems of ancillary equipment are discussed. The article presents technologies available to accomplish closed loop control of materials testing systems in performing standard materials tests and for the development of custom testing applications. It explores the advanced software tools for materials testing. The article includes a description of baseline isothermal fatigue testing, creep-fatigue interaction, and thermomechanical fatigue. The effects of various variables on fatigue resistance and guidelines for fatigue testing are also presented.

While there are many fracture mechanisms that can lead to the failure of a plastic component, environmental stress cracking (ESC) is recognized as one of the leading causes of plastic failure. This article focuses on unpacking the basic concepts of ESC to provide the engineer with a better understanding of how to evaluate and prevent it. It then presents factors that affect and contribute to the susceptibility of plastic to ESC: material factors, chemical factors, stress, and environmental factors. The article includes the collection of background information to understand the circumstances surrounding the failure, a fractographic evaluation to assess the cracking, and analytical testing to evaluate the material, design, manufacturing, and environmental factors.

This article examines residual stresses in quenched and surface-hardened steels by focusing on its theoretical background, formation mechanisms of residual stress, effects of tempering and cryogenic cooling on residual stress, effects of residual stress on the service performance of components, and measurement, computation, and relaxation of residual stress.

Understanding the mechanical properties of aluminum alloys is useful for the designer for choosing the best alloy and establishing appropriate allowable stress values, and for the aluminum producer to control the fabrication processes. This article discusses the nature and significance of mechanical property data and of stress-strain curves detailing the effects of mechanical properties on the design and selection of aluminum alloys. The properties include tensile, compressive, shear, bearing, creep and creep-rupture, fatigue, and fracture resistance properties.

Stress-relief heat treating of steel is the uniform heating of a structure to a suitable temperature below the transformation range, holding at this temperature for a predetermined period of time, followed by uniform cooling. This article provides information on the sources of residual stress, briefly describes the factors influencing the relief of residual stresses, and discusses the various thermal stress-relief methods. It contains tables that provide a summary of compressive and tensile residual stresses at the surface of parts fabricated by common manufacturing processes. The article presents the temperature range of alloy steels for stress-relief heat treating and describes the importance of stress relief of springs.

Thermomechanical analysis (TMA) is a thermal analysis technique in which the length of a specimen is precisely measured versus temperature and time as the specimen is subjected to controlled heating and cooling. This article discusses the various factors and processes involved in TMA. The discussion covers the general principles, equipment used, specimen preparation process, calibration conditions, data analysis steps, and examples of the applications and interpretation of TMA.

With any polymeric material, chemical exposure may have one or more different effects. Some chemicals act as plasticizers, changing the polymer from one that is hard, stiff, and brittle to one which is softer, more flexible, and sometimes tougher. Often these chemicals can dissolve the polymer if they are present in large enough quantity and if the polymer is not crosslinked. Other chemicals can induce environmental stress cracking (ESC), an effect in which brittle fracture of a polymer will occur at a level of stress well below that required to cause failure in the absence of the ESC reagent. Finally, there are some chemicals that cause actual degradation of the polymer, breaking the macromolecular chains, reducing molecular weight, and diminishing polymer properties as a result. This article examines each of these effects. The discussion also covers the effects of surface embrittlement and temperature on polymer performance.

This article is a compilation of terms related to mechanical testing and evaluation of metals, plastics, ceramics, and composites.

Accelerated life testing and aging methodologies are increasingly being used to generate engineering data for determining material property degradation and service life (or fitness for purpose) of plastic materials for hostile service conditions. This article presents an overview of accelerated life testing and aging of unreinforced and fiber-reinforced plastic materials for assessing long-term material properties and life expectancy in hostile service environments. It considers various environmental factors, such as temperature, humidity, pressure, weathering, liquid chemicals (i.e., alkalis and acids), ionizing radiation, and biological degradation, along with the combined effects of mechanical stress, temperature, and moisture (including environmental stress corrosion). The article also includes information on the use of accelerated testing for predicting material property degradation and long-term performance.

A unidirectional fiber composite (UDC) consists of aligned continuous fibers that are embedded in a matrix. This article describes a variety of analytical methods that are used to determine the various physical properties of the UDC. These properties include elasticity, thermal expansion coefficients, moisture swelling coefficients, static and dynamic viscoelastic properties, conductivity, and moisture diffusivity.

Modeling will help reduce machining problems and thereby enable more rapid introduction of high-performance materials and components. This article discusses the technical needs of aircraft engine and airframe structural components and modeling of heat-treat-induced residual stress by finite-element residual-stress analysis. It describes the two-dimensional (2-D) and three-dimensional (3-D) procedures involved in finite-element residual-stress analysis. The article deals with the 2-D and 3-D machining distortion validation on engine-disk-type components. It describes methods for obtaining machining-induced residual stresses, including detailed finite-element analysis of the cutting process, the simple fast-acting mechanistic model, and the semi-empirical linear stress model. The article concludes with information on the modeling benefits and implementation of modeling in a production environment.