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pyrrhotite
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Published: 01 January 2003
Fig. 5 Flotation of pyrrhotite as a function of contact time with glass, mild steel (MS) and austenitic stainless steel in air-exposed distilled water at natural pH unless indicated otherwise. Comparison of MS in bubbled environment given. Source: Ref 14
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Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003629
EISBN: 978-1-62708-182-5
... Abstract This article describes the methods of wear measurements and a model of corrosive wear in mill atmospheres. It explains the polarization curves of pyrrhotite and high-carbon low-alloy steel in a quartzite slurry with examples. The surfaces of pyrrhotite in contact with mild steel...
Abstract
This article describes the methods of wear measurements and a model of corrosive wear in mill atmospheres. It explains the polarization curves of pyrrhotite and high-carbon low-alloy steel in a quartzite slurry with examples. The surfaces of pyrrhotite in contact with mild steel or stainless steel affected by galvanic interaction are discussed. The article contains a table that lists the results of laboratory marked ball wear tests for three types of steel balls in wet grinding of magnetic taconite. It also provides information on the mechanism of electrochemical interaction and relative significance of corrosion and abrasion in wear. Galvanic interactions in multielectrode systems are reviewed. The article presents a case history on the material selection for grinding balls to minimize corrosion loss and the adverse effect on flotation.
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Published: 01 January 2003
Fig. 6 Combination potentials and galvanic currents of a short-circuited pyrite-pyrrhotite-mild steel (MS) electrode under abrasion in a quartzite slurry in a 0.05 M sodium sulfate solution at neutral pH under oxygen atmosphere. Pyrrhotite, Po. Pyrite, Py. Source: Ref 20
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Published: 01 January 2003
Fig. 4 Polarization curves. Estimation of corrosion current ( i corr ) for the pyrrhotite (Po)-high-carbon low-alloy (HCLA) steel electrodes under abrasion in a quartzite slurry by adjusting to the surface area ratio of ground pyrrhotite and HCLA steel balls. SCE, saturated calomel electrode
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Published: 01 January 2003
Fig. 3 Wear of mild steel (MS), high-carbon low-alloy steel (HCLA), and austenitic stainless steel (SS-A) balls as a function of pyrrhotite addition under different aeration conditions. Source: Ref 10
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Published: 01 January 2003
Fig. 10 The effect of chromium contents on the wear of ball materials in wet grinding of quartzite (Qz), quartzite with either 5% pyrrhotite (Po) or 5% chalcopyrite (Cp) slurries in the presence and absence of oxygen. Source: Ref 24
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Published: 01 January 2003
Fig. 11 Batch flotation results using potassium ethyl xanthate (KEX) on a quartzite with 5% pyrrhotite mixture ground with various cast iron ball materials under (a) nitrogen or (b) oxygen atmosphere. Source: Ref 24
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Published: 01 January 2003
Fig. 7 Polarization curves. Estimation of corrosion currents ( i corr ) for pyrite (Py)-mild steel (MS), pyrrhotite (Po)-MS, and Py-Po-MS systems under abrasion in a quartzite slurry by adjusting to the surface area ratios of ground minerals and steel balls. Numbered points are discussed
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Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006415
EISBN: 978-1-62708-192-4
... currents of pyrite, pyrrhotite, and mild-steel electrodes were determined in short-circuit connections under abrasive and nonabrasive conditions ( Ref 63 , 64 , 65 ). Figure 16 shows a device developed for tests performed under abrasive conditions, consisting of a porcelain ball rotating against three...
Abstract
Tribocorrosion is the subject dealing with complex, synergistic effects of chemical and mechanical conditions that cause wear. This article begins with a discussion on oxidative wear and corrosive wear, as well as quantitative measurements of corrosion, mechanical wear, and wear-corrosion effects. It illustrates the mechanism of corrosive-abrasive wear and discusses the factors affecting two-body wear. These factors include particle shape, size, density, and hardness; slurry velocity; slurry particle angle of attack; solids concentration in the slurry; hydrodynamic factors; corrosion products and the mass transfer of oxygen. The article describes slurry particle impingement tests and grinding tribocorrosion tests, as well as the factors to be considered for mitigating corrosive wear, such as materials selection, surface treatments, and environment modifications.
Book Chapter
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003567
EISBN: 978-1-62708-180-1
.... , and Newman R.C. , The Corrosive Wear of Cast Iron Under Potentiostatically-Controlled Conditions in Sulfuric Acid Solutions , Corros. Sci. , Vol 30 , 1990 , p 813 – 830 4. Pozzo R.L. and Iwasaki I. , Pyrite-Pyrrhotite Grinding Media Interactions and Their Effects on Media Wear...
Abstract
This article focuses on the corrosion-wear synergism in aqueous slurry and grinding environments. It describes the effects of environmental factors on corrosive wear and provides information on the impact and three-body abrasive-corrosive wear. The article also discusses the various means for combating corrosive wear, namely, materials selection, surface treatments, and handling-environment modifications.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004142
EISBN: 978-1-62708-184-9
... chloride … FeCl 3 Green Phosphates Iron phosphate octahydrate Vivianite Fe 3 (PO 4 ) 2 ·8H 2 O Dark blue (or white) Iron phosphate dihydrate Strengite FePO 4 ·2H 2 O Pink Sulfides Iron sulfide Pyrrhotite Fe 1− x S ( x =0–0.2) Yellow-brown Iron sulfide Mackinawite...
Abstract
The corrosion processes of metals during burial are affected by environmental pollutants, other archaeological material, geography, microorganisms in the soil, vegetation, land use, soil chemistry, soil physical properties, and the presence or absence of water and air. This article discusses the key environmental variables that affect the corrosion of buried metal artifacts. These include water (including dissolved salts and gases), sulfate-reducing bacteria, pH (acidity), and potential (oxidizing or reducing capacity). The article contains tables that list some corrosion products identified on archaeological tin and pewter, lead, iron alloys, silver alloys, and copper alloys. It also discusses the corrosion problems after excavation and the techniques followed by archaeological department for conserving metal artifacts.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004210
EISBN: 978-1-62708-184-9
... be sustained beneath thick but porous iron sulfide deposits (primarily pyrrhotite, FeS 1.15 ) because the FeS surface is an effective cathode. The anodic reaction beneath the FeS deposit is dependent on the presence of a thin layer of concentrated iron chloride (FeCl 2 ) at the Fe/FeS interface...
Abstract
This article discusses the particular corrosion problems encountered and the corrosion control methods used in petroleum production (i.e., upstream) and the storage and transportation of oil and gas (i.e., midstream) up to the refinery (i.e., downstream). These control methods include proper material selection, protective coatings, cathodic protection systems, use of inhibitors, use of nonmetallic materials, and control of the environment. The article reviews the aspects of corrosion that tend to be unique to corrosion as encountered in applications involving oil and gas exploration and production. It discusses corrosion problems that are specific to the various types of environments or equipment used in secondary recovery, including producing wells, producing flow lines, and injection wells. Corrosion mitigation methods and guidelines are also discussed for each type of environment.