Laser-beam welding (LBW) uses a moving high-density coherent optical energy source, called laser, as the source of heat. This article discusses the advantages and limitations of LBW and tabulates energy consumption and efficiency of LBW relative to other selected welding processes. It provides information on the applications of microwelding with pulsed solid-state lasers. The article describes the modes of laser welding such as conduction-mode welding and deep-penetration-mode welding, as well as major independent process variables for laser welding, such as laser-beam power, laser-beam diameter, absorptivity, and traverse speed. It concludes with information on various hazards associated with LBW, including electrical hazards, eye hazards, and chemical hazards.

Microjoining methods are commonly used to fabricate medical components and devices. This article describes key challenges involved during microjoining of medical device components. The primary mechanisms used in microjoining for medical device applications include microresistance spot welding (MRSW) and laser welding. The article illustrates the fundamental principles involved in MRSW and laser welding. The article presents examples of various microjoining methods used in medical device applications, including pacemaker and nitinol microscopic forceps.

The study of the physical properties of ductile solids subjected to shock wave loading is undertaken to understand how the thermodynamic conditions and strain rate affect material response. This article presents a description of a range of possible experimental techniques to quantify the structure/property effects of planar shock waves on ductile materials (metals and alloys) due to the wave propagation through the material. The techniques include explosive-driven shock-loading methods, shock-loading methods using exploding foil and laser-driven impactors, gas/powder launcher-driven shock loading methods, and radiation-driven shock-loading methods. Design parameters for shock recovery fixtures, spallation fixtures, and the flyer-plate experiment, are also discussed.

Laser has found its applications in cutting, drilling, and shock-peening operations of manufacturing industry because of its accurate, safe, and rapid cutting property. This article provides an account on the fundamental principles of laser cutting (thermal), drilling, and shock-peening processes of which emphasis is placed on thermal laser cutting. It details the principal set-up parameters, such as the laser beam output, nozzle design, focusing optic position and characteristics, assist gases, surface conditions, and cutting speed. A discussion on the types of gas, supply system, purity level, and flow rates of lasing and assist gases is also provided. The article also describes the metallurgies and other key material considerations that impact laser-cutting performances and includes examples of laser cutting of nonmetal materials.

Lasers evolved as a versatile materials processing tool due to their advantages such as rapid, reproducible processing, chemical cleanliness, ability to handle variety of materials, and suitability for automation. This article focuses on state-of-the-art laser applications to improve tribological performance of structural materials in lubricated and nonlubricated environments. It discusses the fundamentals of various laser materials interactions and reviews laser-based surface-modification strategies, including laser surface heating and melting, laser-synthesized coatings, and laser-based design approaches such as laser patterning and dimpling. Laser-surface modification of novel materials, such as high-entropy alloys and metallic glasses, is explored. The article provides an overview of hybrid techniques involving laser as a secondary tool, as well as a discussion on the improved capabilities of laser surface engineering for tribological applications by means of integrated computational process modeling.

Conventional high-strength aluminum alloys produced via powder metallurgy (P/M) technologies, namely, rapid solidification (RS) and mechanical alloying (mechanical attrition) have high strength at room temperature and elevated temperature. This article focuses on the metallurgy and weldability of dispersion-strengthened aluminum alloys based on the aluminum-iron system that are produced using various RS-P/M processing techniques. It describes weldability issues related to weld solidification behavior, the formation of hydrogen-induced porosity in the weld zone, and the high-temperature deformation behavior of these alloys, which affect the selection and application of fusion and solid-state welding processes. The article provides specific examples of material responses to welding conditions and highlights the microstructural development in the weld zone.

Fusion-based additive manufacturing (AM) processes rely on the formation of a metallurgical bond between a substrate and a feedstock material. Energy sources employed in the fusion AM process include conventional arcs, lasers, and electron beams. Each of these sources is discussed, with an emphasis on their principles of operation, key processing variables, and the influence of each source on the transfer of heat and material. Common energy sources used for metals AM processes, particularly powder-bed fusion and directed-energy deposition, are also discussed. Brief sections at the end of the article discuss the factors dictating the choice of each of these energy sources and provide information on alternative sources of AM.

This article is a detailed account of optical emission spectroscopy (OES) for elemental analysis. It begins with a discussion on the historical background of OES and development trends in OES methods. This is followed by a description of the general principles and optical systems of OES, along with various types of emission sources commonly used for OES. Some of the processes involved in calibration and quantification of OES for direct solids analysis by the ratio method are then described. The article ends with a discussion on the applications of each type of emission sources.

This article presents a general description of pulsed-laser deposition. It describes the components of pulsed-laser deposition equipment. The article also discusses the effects of angular distribution of materials. Finally, the article reviews the characteristics of high-temperature superconductors and ferroelectric materials.

This article provides a history of electron and laser beam welding, discusses the properties of electrons and photons used for welding, and contrasts electron and laser beam welding. It presents a comparison of the electron and laser beam welding processes. The article also illustrates constant power density boundaries, showing the relationship between the focused beam diameter and the absorbed beam power for approximate regions of keyhole-mode welding, conduction-mode welding, cutting, and drilling.

This article focuses on a variety of laser beam machining (LBM) operations of aluminum and its alloys, namely, laser cutting, laser drilling, laser milling, laser turning, laser grooving, laser scribing, laser marking, and laser micromachining. It presents different approaches for carrying out machining operations, laser processing parameters, efficiency and accuracy of the process, and the effect of laser processing parameters on the quality of the machined surface. The article provides an overview of the various conventional (chip forming) and nonconventional machining techniques employed for aluminum-based materials. A comparison of the various aspects of LBM with other non-conventional techniques is also presented. The article also describes the features of LBM techniques employed for aluminum and its alloys for different types of machining.

Cutting with lasers is accomplished with carbon dioxide (CO 2 ) and neodymium: yttrium-aluminum-garnet (Nd:YAG) lasers. This article provides a description of the process variables and principles of laser cutting. It discusses the three basic types of CO 2 gas lasers, namely, slow axial flow, transverse flow, and fast axial flow and reviews the applications of Nd:YAG laser. The article describes the basic parameters in the laser-cutting process: beam quality, power, travel speed, nozzles design, and focal-point position. Several material conditions that affect the quality of the laser cut are also discussed. The article provides information on the basic laser-cutting system and its optional equipment. A general description of how well each metal group can be cut is also provided.

Hybrid laser arc welding (HLAW) is a metal joining process that combines laser beam welding (LBW) and arc welding in the same weld pool. This article provides a discussion on the major process variables for two modes of operation of HLAW, namely, stabilization mode and penetration mode. The major process variables for either mode of operation include three sets of welding parameters: the variables for the independent LBW and gas metal arc welding processes and welding variables that are specific to the HLAW process. The article discusses the advantages, limitations, and applications of the HLAW and describes the major components and consumables used for HLAW. The components include the laser source, gas metal arc welding source, hybrid welding head, and motion system. The article also describes the typical sources of defects and safety concerns of HLAW.

Microjoining with high energy density beams is a new subject in the sense that the progress of miniaturization in industry has made the desire to make microjoints rapidly and reliably a current and exciting topic. This article summarizes the current state of microjoining with both electron and laser beams. It considers the elementary physical processes such as heat and fluid flow to introduce the reader to the phenomena that affect melting, coalescence, and solidification needed for a successful microweld. The various forces driving (and resisting) fluid flow are analyzed. The article discusses the equipment suitable for microjoining and the metallurgical consequences and postweld metrology of the process. It also provides examples of developmental welds employing laser and electron beam microwelding techniques.

Most welding lasers fall into the category of fiber, disc, or direct diode, all of which can be delivered by fiber optic. This article provides a comparison of the energy consumptions and efficiencies of laser beam welding (LBW) with other major welding processes. It discusses the two modes of laser welding: conduction-mode welding and deep-penetration mode welding. The article reviews the factors of process selection and procedure development for laser welding. The factors include power density, interaction time, laser beam power, laser beam diameter, laser beam spatial distribution, absorptivity, traverse speed, laser welding efficiency, and plasma suppression and shielding gas. The article concludes with a discussion on laser cutting, laser roll welding, and hybrid laser welding.

This article provides an introduction to the molecular fluorescence spectroscopy, and discusses the theory of fluorescence and its application to chemical analysis. It provides information on fluorescence that occurs in organic compounds and inorganic atoms and molecules. The article describes the instruments used in the spectroscopy, namely, radiation sources, sample holders, wavelength selectors, detectors, computers, and ratiometric instruments. The practical considerations include solvent effects, corrected spectra, wavelength calibration, temperature, and scattered light. The article also discusses the uses of some special techniques used in molecular fluorescence spectroscopy.

This article endeavors to familiarize the reader with a selection of different ionization designs and instrument components to provide knowledge for sorting the various analytical strategies in the field of solid analysis by mass spectrometry (MS). It begins with a description of the general principles of MS. This is followed by sections providing a basic understanding of instrumentation and discussing the operating requirements as well as practical considerations related to solid sample analysis by MS. Instrumentation discussed include the triple quadrupole mass spectrometer and the time-of-flight mass spectrometer. Inductively coupled plasma and thermal ionization MS provide atomic information, and direct analysis in real-time and matrix-assisted laser-desorption ionization MS are used to analyze molecular compositions. The article describes various factors pertinent to ionization methods, namely glow discharge mass spectrometry and secondary ion mass spectrometry. It concludes with a section on various examples of applications and interpretation of MS for various materials.

The effective integration of aluminum metal-matrix composites (Al-MMCs) into useful structures and devices often requires an understanding of the weldability of Al-MMCs that includes a thorough knowledge on the effects of various interactions between matrix and reinforcement. This article provides a detailed discussion on weldability and the effect of viscosity, chemical reactions, and solidification on weldability. It discusses different welding processes, namely, gas-tungsten arc welding, gas-metal arc welding, laser-beam welding, electron-beam welding, resistance welding, friction welding, transient liquid phase bonding, and capacitor discharge welding.

The measurement of thermophysical properties of metal alloys, especially at high temperatures, is difficult because of the reactivity of some alloys. This article reviews the methods available for measurement of thermal and other physical properties for liquid, semi-solid, and solid commercial alloys, including adiabatic calorimetry, modulated calorimetry, Calvet calorimetry, single-pan calorimetry, and drop calorimetry. It describes differential scanning calorimetry and differential temperature analysis for measuring transition temperatures such as phase transformation or glass transition temperatures. The article schematically illustrates the laser flash apparatus for measuring the thermal diffusivity of solids and oscillation viscometer for measurements of the viscosity of metals. A summary of the measurement methods is presented in tables.