This article reviews some concepts considered important for an understanding of processes used for preparing cobalt-chromium alloy implants, the microstructures resulting from this processing, and the resulting material properties. The review includes the solidification of alloys, diffusionless (martensitic) phase transformation as occurs with face-centered cubic to hexagonal close-packed transformation in cobalt-chromium alloys, stacking faults and twins and their role in this transformation. It also includes strengthening mechanisms that are responsible for the mechanical properties of cast and wrought cobalt alloys. The article contains tables that list the commonly used cobalt alloys and their biomedical applications and chemical compositions. It discusses the mechanical and corrosion properties of cobalt alloys, and provides a description of the microstructure of cobalt alloys.

This article provides a detailed discussion on the most commonly employed tests and specific examples of the use of these tests in evaluating the corrosion resistance of powder metallurgy (P/M) stainless steels. It describes the influence of various processing parameters on the corrosion resistance of P/M stainless steels. The approaches used to improve the corrosion resistance of sintered stainless steels are discussed briefly. The article also presents a discussion on the manufacturing and corrosion characteristics of P/M superalloys.

Spray casting, also known as spray forming, is a niche casting process for the manufacture of preforms. This article lists commercial examples of alloys manufactured by spray casting and provides sequential steps of the spray casting process. Gas atomization is a chaotic, stochastic process that always produces a wide range of droplet diameters. The article schematically illustrates typical log-normal droplet diameter probability density distribution on a mass or volume basis obtained by gas atomization. It also illustrates the changes in solid fraction during the spray casting process as a function of axial distance from the point of droplet atomization. The article concludes with a section on occurrence of macrosegregation and coarsening in spray cast preforms.

Discontinuously reinforced aluminum (DRA) alloy metal-matrix composites (MMCs) represent an advanced aluminum materials concept whereby ceramic particles, or whiskers, are added to aluminum-base alloys through the use of either ingot-melting or casting and/or powder-metallurgy (P/M) techniques. This article begins with a summary of general observations on the forging of discontinuously reinforced composites. It provides information on some of the specific experimental results obtained on various DRA systems, including 2xxx DRA alloys and cast DRA alloys. The article reviews the efforts on the modeling of behavior of specific alloy systems, with a comparison of experimental results to the modeling attempts. It concludes with information on the properties of deformation-processed DRA alloys.

This article focuses on the significant fundamental powder characteristics, which include particle size, particle size distribution, particle shape, and powder purity, followed by an overview of general and individual powder production processes such as mechanical, chemical, electrochemical, atomizing, oxide reduction, and thermal decomposition processes. It also covers the consolidation of powders by pressing and sintering, as well as by high density methods. Further emphasis is provided on the distinguishing features of powders, their manufacturing processes, compacting processes, and consolidated part properties. In addition, a glossary of powder metallurgy terms is included.

Iron powders are the most widely used powder metallurgy (P/M) material for structural parts. This article reviews low to medium density iron and low-alloy steel parts produced by the pressing and sintering technology. It explains different powder production methods, including Hoeganaes process, Pyron process, atomization of liquid metal, thermal decomposition and the electrodeposition process for carbonyl and electrolytic iron powders. It describes the types of compaction and sintering, explaining their effects of processing with designations. Further, the article deals with the mechanical and physical properties of ferrous P/M materials, which may depend on certain factors, namely microstructure, porosity, density, infiltration, re-pressing, chemical composition, and heat treatment.

This article discusses the production of low-alloy steel parts by powder forging, focusing on the material considerations, such as hardenability and inclusion assessment; and process considerations, including sintering and reheating, metal flow, and secondary operations. It presents the mechanical property data for copper and graphite powders mixed with an iron powder base to produce materials that generally contain 2″ Cu, including tensile, impact, and fatigue properties. Heat treatment procedures used in developing the properties of the prealloyed powder forged materials are also covered. Finally, the article describes the process steps and cost considerations in metal injection molding (MIM) and tabulates the composition, and mechanical properties of MIM low-alloy steels.

This article discusses the characteristics, properties, and production methods of copper powders and copper alloy powders. Bulk of the discussion is devoted to production and applications of powder metallurgy (P/M) parts, including pure copper P/M parts, bronze P/M parts, brass and nickel silver P/M parts, copper-nickel P/M parts, copper-lead P/M parts, copper-base P/M friction materials, copper-base P/M electrical contact materials, copper-base P/M brush materials, infiltrated parts, and oxide-dispersion-strengthened copper P/M materials.

Stainless steel powder metallurgy (P/M) parts represent an important and growing segment of the P/M industry. This article describes the processing, properties, and composition of medium-density and high-density P/M stainless steels. Medium-density materials are processed by pressing and sintering prealloyed stainless powders. High-density materials are produced by hot isostatic pressing, cold isostatic pressing followed by extrusion, or metal injection molding. The comparison of mechanical properties of these P/M stainless steels is represented graphically. The article contains a table that lists the effect of iron, carbon, nitrogen, oxygen, and density on the corrosion resistance of the sintered austenitic stainless steels.

This article provides an overview of the composition and properties of powder metallurgy (P/M) aluminum powders for pressed and sintered parts. It includes the steps involved in the processing of high-performance P/M alloys. The article describes the classes of high-performance P/M alloys, including corrosion-resistant alloys (stress-corrosion cracking), elevated-temperature alloys, and low density/high-stiffness alloys.

Specialty steels encompass a broad range of ferrous alloys noted for their special processing characteristics (powder metallurgy alloys), corrosion resistance (stainless steels), wear resistance and toughness (tool steels), high strength (maraging steels), or magnetic properties (electrical steels). This article provides a detailed discussion on the various surface treatments, including cleaning, nitriding, carburizing, coating, and plating, performed on specialty steels.

The potential for introducing defects during processing becomes greater as the relative density of pressed and sintered powder metallurgy (PM) parts increases and more multilevel parts with complex geometric shapes are produced. This article discusses the potential defects in pressed and sintered PM parts: density variations, compaction and ejection cracks, microlaminations, poor degree of sintering, and voids from prior lubricant agglomerates. It describes the various methods applicable to green compacts: direct-current resistivity testing, radiographic techniques, computed tomography, and gamma-ray density determination. The article also discusses the methods for automated nondestructive testing of pressed and sintered PM parts: acoustic methods-resonance testing, eddy current testing, magnetic bridge comparator testing, ultrasonic techniques, radiographic techniques, gamma-ray density determination, and visual inspection.

Powder forging is an extension of the conventional press and sinter powder metallurgy process, which is recognized as an effective technology for producing a variety of parts to net or near-net shape. This article focuses on the material considerations, such as powder characteristics, alloy development, and inclusion assessment; and process considerations, such as process stages, tool design, and secondary operations; of ferrous alloy powder forging. The mechanical properties of powder forged materials are also reviewed. The article discusses the quality assurance tests for powder forged materials: the part dimensions and surface finish measurement, magnetic particle inspection, metallographic analysis, and nondestructive testing. It concludes with a discussion on the applications of powder forged parts with examples.

Titanium and its alloys have been used extensively in a wide variety of implant applications, such as artificial heart pumps, pacemaker cases, heart valve parts, and load-bearing bone or hip joint replacements or bone splints. This article discusses the properties of titanium and its alloys and presents titanium-base biomaterials in a table. Titanium components are produced in wrought, cast, and powder metallurgy (PM) form. The article describes forging, casting, and heat treating of titanium alloys for producing titanium components. Typical mechanical properties of titanium biomedical implant alloys are listed in a tabular form. The article presents an overview of surface-modification methods for titanium and its alloys implants. It concludes with a section on biocompatibility and in vivo corrosion of titanium alloys.

Aluminum and its alloys are used in a broad range of applications. This article discusses the primary and secondary production of aluminum and the classification system for cast and wrought products. It describes some of the more common manufactured forms, including commercial wrought aluminum products, aluminum alloy engineered castings, powder metallurgy parts, and metal-matrix composites. The article also reviews fabrication characteristics such as machining, forming, forging, and joining. It concludes with a description of the major industrial applications of wrought and cast aluminum alloys.

Titanium metal passes through three major steps during processing from ore to finished product: reduction of titanium ore to sponge (porous form), melting of sponge and scrap to form ingot, and remelting and casting into finished shape. This article describes primary fabrication, including all operations that convert ingot into general mill products, such as billet, bar, plate, sheet, strip, tube, and wire. The section on secondary fabrication describes processes such as die forging, extrusion, hot and cold forming, machining, chemical milling, and joining. The article presents a short note on powder metallurgy products of titanium. Casting processes and properties are covered in the final section.

Metal-matrix composites (MMCs) are a class of materials with potential for a wide variety of structural and thermal applications. This article discusses the mechanical properties of MMCs, namely aluminum-matrix composites, titanium-matrix composites, magnesium-matrix composites, copper-matrix composites, superalloy-matrix composites, and intermetallic-matrix composites. It describes the processing methods of discontinuous aluminum MMCs which include casting processes, liquid-metal infiltration, spray deposition and powder metallurgy. The article provides useful information on aluminum MMC designation system and also describes the types of continuous fiber aluminum MMCs, including aluminum/boron MMC, aluminum/silicon carbide MMC, aluminum/graphite MMC, and aluminum/alumina MMC.

This article describes the heat treating (stress relieving, normalizing, annealing, quenching, tempering, martempering, austempering, and age hardening) of different types of steels, including ultrahigh-strength steels, maraging steels, and powder metallurgy steels. Tabulating the recommended temperatures for normalizing and austenitizing, it provides information on mechanism, cooling media, principal variables, process procedures, and applications of heat treating. In addition, the article gives a short note on the cold and cryogenic treatment of steel.