Electrogravimetry is a method used to separate and quantify ions of a substance, usually a metal. Quantification of these ions primarily depends on the rate of movement of charged species (ions) in an electric field. This article details the various types of electrometric titrations, namely, conductometric titration, oscillometric (high frequency) titration, potentiometric titration, amperometric titration, biamperometric titration, bipotentiometric titration, and coulometric titration. It also provides a brief outline of the applications of electrometric titrations.

This article describes various methods of electrochemical analysis, namely coulometry, electrogravimetry, voltammetry, electrometric titration, and nanometer electrochemistry. The discussion covers the general uses, sample requirements, application examples, advantages, and limitations of these methods. Some of the factors pertinent to electrochemical cells are also provided. In addition, the article provides information on various potentiometric membrane electrodes used to quantify numerous ionic and nonionic species.

Potentiometric membrane electrodes are electrochemical devices that can be used to quantify numerous ionic and nonionic species. This class of electrochemical sensors can be divided into ion-selective and gas-sensing membrane electrodes. The first half of this article mainly focuses on the subclasses, the membrane potential, electrode selectivity limitations and the methods of analysis of the ion-selective membrane electrodes. These methods of analysis include the use of calibration curves, addition techniques, subtraction techniques, and titration. The second half outlines gas sensing membrane electrodes, and discusses important elements that must be considered in addition to the potentiometric membrane electrode to ensure proper electrode response. These elements are reference electrodes, temperature controls, recording of the potential with respect to time, electrode storages, and sample pretreatment. The article also explains the applications of the potentiometric membrane electrodes with the aid of an example.

This article provides information on basic chemical equilibria, wet analytical chemistry, and the appropriateness of classical wet methods. It focuses on nonoxidizing acids and oxidizing acids. The article includes information on the qualitative methods used to identify materials by wet chemical reaction. Gravimetry, in which a chemical species is weighed; titrimetry, which involves volume measurement of a liquid reactant; and a host of separation techniques, which require diverse forms of laboratory manipulation, are discussed. The article briefly describes the partitioning of oxidation states as well as those applications in surface studies and rapid material identification in which chemical techniques have proved useful.

This article discusses the major methods of elemental analysis, namely, the combustion method for carbon, hydrogen, and nitrogen; the Kjeldahl method for nitrogen; and the Schoniger flask method for other common elements. It also discusses the methods of functional group analysis for acids, alcohols, aldehydes and ketones, amines, esters, aromatic hydrocarbons, peroxides, phenols, water (Karl Fischer method), and alkenes.

Phosphating is used in the metalworking industry to treat substrates like iron, steel, galvanized steel, aluminum, copper, and magnesium and its alloys. This article provides an overview of the types, uses, and theory of phosphate coatings and their formation. It also discusses the composition of phosphating baths, phosphate layers, and their analysis, as well as the process hardware necessary to realize these treatments. A summary of the different types of phosphate layers is tabulated, and the chemical formulas for a number of different phosphate compounds that are theoretically possible in crystalline phosphate layers are illustrated. The article presents four chemically important phosphating steps, namely, cleaning, activation or conditioning, phosphating, and posttreatment plus standard rinsing. It describes the physical and chemical properties by gravimetric analysis, chemical analysis, structure and morphology, thermal analysis, and alkaline resistance.

The function of lubricants is to control friction and wear in a lubricating system containing machine elements such as gears and bearings. This article discusses the basic properties of lubricants to help scientists and engineers understand the principles behind lubricant selection. It reviews the functions of additives, such as friction modifiers, antiwear additives, viscosity modifiers, corrosion inhibitors, oxidation inhibitors, dispersants, and detergents. The article discusses the physical properties of liquid lubricants and the performance characteristics of lubricants. It describes the most common lubricant categories and provides information on the health and safety aspects of using liquid lubricants. The article concludes with a discussion on the lubricant-application method that plays a vital role in how the lubricant functions.

This article is a compilation of definitions of terms related to materials characterization techniques.

This article explains how ceramic powders are made. It begins by briefly describing the raw materials used in structural clay products, whitewares, refractories, and advanced ceramics. It then examines various additives that promote uniformity at different stages of the process. After a description of the comminution process (wet and dry milling methods), it discusses batching and mixing operations and granulation methods. The article also deals with the effect of process variables and the steps involved in chemical synthesis, including preparation from solution and gas-phase reactions, filtration and washing, and powder recovery techniques. It concludes with a discussion on characterization, centering on size distribution analysis, specific surface area, density, porosity chemical composition, phase, and surface composition.

This article is a compilation of terms and definitions related to materials characterization.

In this article, an in-depth overview of petroleum quenching oils is provided, including oil composition, use, mechanism of the oil quenching processes, oil degradation, toxicology and safety, and quenching bath maintenance.

This article provides a brief introduction to lubrication as a method to reduce friction between two surfaces. It discusses the surface characteristics of parts and explores how lubrication helps separate two contacting surfaces and thereby decreases the coefficient of friction. The article details the classifications of lubrication regimes, namely, boundary, mixed, hydrodynamic, and elastohydrodynamic lubrications. It discusses the various types of lubricant materials and additives, including liquid lubricants, solid lubricants, gaseous lubricants, greases, green lubricants, and nanomaterials. The article also reviews the properties of lubricants. It describes the tribological evaluation of lubricants, including stribeck test, four-ball test, block-on-ring test, pin-in-vee test, and reciprocating motion test.

This article addresses the impact of emerging technologies on future lubricant and tribology requirements. The connection between lubricant and tribological requirements is shown by briefly describing basic lubrication and friction processes in major engine components incorporating emerging technologies. The article introduces automotive lubricant development activities and the foundation of future automotive engine-lubricant trends. It discusses how emerging powertrain technology impacts future automotive lubricant and technology requirements, focusing on the effects of engine oils and additives on engine performance to meet powertrain performance requirements. A detailed overview of automotive engine oil performance evaluation methods and specifications, and their impact on the types of advanced lubricants being developed as well as future automotive engine testing requirements, is provided.

This article focuses on different aspects of wear particle analysis. It discusses the different wear regimes in the wear rate versus time (bathtub) curve. The article explains the essence of condition monitoring and how to properly sample lubricants for condition monitoring. It also discusses in-service lubricant analysis for condition monitoring, focusing on the spectrometric oil analysis program. The article describes the characteristics of wear particles and analytical techniques for characterizing them. It also describes the characteristics of different types of wear particles and the mechanisms by which they are generated. The article concludes with a summary of the major applications of wear particle analysis.

This article presents the primary considerations and mechanisms for corrosion and explains how they are involved in the selection of materials for process equipment in refineries and petrochemical plants. It discusses the material selection criteria for a number of ferrous and nonferrous alloys used in petroleum refining and petrochemical applications. The article reviews the mechanical properties, fabricability, and corrosion resistance of refinery steels. It describes low- and high-temperature corrosion, hydrogen embrittlement, and cracking such as stress-corrosion, sulfide stress, and stress-oriented hydrogen-induced cracking. The article considers hydrogen attack, corrosion fatigue, and liquid metal embrittlement and the methods of combating them. It explains the causes of velocity-accelerated corrosion and erosion-corrosion. The article summarizes some corrective measures that can be implemented to control corrosion. The applicable standards for materials used in corrosive service conditions in upstream and downstream petroleum service are presented in a tabular form.

This article provides an overview of common quenching media, the factors involved in the mechanism of quenching, and process variables, namely, surface condition, mass and section size of the workpiece, and flow rate of the quenching liquid. It describes the methods of quenchant characterization using hardening-power and cooling-power tests. The article discusses the fundamentals involved in heat-transfer coefficient and heat flux of quenching processes. This discussion is followed by various actual examples of applications of these methods using simplified equations. Quenchant evaluation, classification, selection, and maintenance are reviewed in detail. The article addresses the various reasons for quench oil variability and complications due to aging and contamination.

Bridges and highways are core components of transportation system and range from pavements with earth, gravel, or stone covered by a thin bituminous surface course to a continually reinforced Portland cement concrete (PCC) roadway with or without a bituminous wear course. This article provides information on bridges and dowels and the reinforcement used in PCC roadways that suffer from corrosion. An overview is provided on the rise in awareness of the corrosion issues affecting bridges and highways. The chemistry and structure of concrete and its role as an electrolyte in promoting corrosion are also discussed. The article addresses reinforcement, including conventional, prestressed, cable stays, and corrosion-resistant reinforcement. It deals with the electrochemical methods for the inspection and corrosion control of embedded reinforcement. The article also reviews the corrosion of metal bridges and corrosion control, including the use of weathering steels and coating systems.