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Image
Published: 01 January 2003
Fig. 27 Structure of aliphatic polyurea coatings. X is one of the polyaspartic esters shown as (a), (b), (c), and (d). The speed of reaction and therefore the pot life and cure time increase from (a) (the slowest) to (d) (the fastest). (d) is the most flexible and has the greatest elongation.
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Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006047
EISBN: 978-1-62708-172-6
... Abstract Two-component polyurea elastomeric coating/lining systems are the newest technology in the protective coating/lining industry and a wide variety of applications have been developed. These include coating/lining applications over concrete, geotextile membranes, various metals...
Abstract
Two-component polyurea elastomeric coating/lining systems are the newest technology in the protective coating/lining industry and a wide variety of applications have been developed. These include coating/lining applications over concrete, geotextile membranes, various metals for corrosion and decorative areas, and some plastics. This article discusses the formulation basics of polyurea technology and compares the technology to that of polyurethane and polyurethane/polyurea systems. It addresses performance issues and describes application processing considerations and safety practices of polyurea coating/lining systems.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006036
EISBN: 978-1-62708-172-6
... polyurea because it is the reaction of an aliphatic polyisocyanate with an aliphatic diamine—the polyaspartic ester. However, polyaspartic coatings are very different in both application and coating performance properties from conventional polyureas. For example, polyaspartics allow the formulator...
Abstract
Polyaspartic coating technology has found utility in a variety of coating applications, including corrosion protection and flooring topcoats, as these coatings are based on aliphatic polyisocyanates and aliphatic diamines. This article describes the chemistry of polyaspartic esters and curing characteristics and performance properties of polyaspartic coatings. It also provides information on curing corrosion protection coating systems, polyaspartic floor coatings, and safe-use recommendations for handling isocyanates.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003692
EISBN: 978-1-62708-182-5
... cross-linked resins thermoplastic resins cross-linked thermosetting resins alkyd resins epoxy esters lacquers water-borne coatings epoxies unsaturated polyesters urethane coatings high-temperature curing silicones phenolic linings organic coatings polyurea coatings PAINTS OR LININGS...
Abstract
This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.
Image
Published: 30 September 2015
Fig. 30 Fabricated part—aliphatic polyurea in-mold-coated structural aromatic with chopped glass reinforcement
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Book Chapter
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006335
EISBN: 978-1-62708-179-5
... Abstract Coating of cast irons is done to improve appearance and resistance to degradation due to corrosion, erosion, and wear. This article describes inorganic coating methods commonly applied to cast irons. The coating methods include plating, hot dip coating, conversion coating, diffusion...
Abstract
Coating of cast irons is done to improve appearance and resistance to degradation due to corrosion, erosion, and wear. This article describes inorganic coating methods commonly applied to cast irons. The coating methods include plating, hot dip coating, conversion coating, diffusion coating, cladding, porcelain enameling, and thermal spray. Organic coatings have a wide variety of properties, but their primary use is for corrosion resistance combined with a pleasing colored appearance. The article discusses the various types of organic coatings applied to cast irons. Practically any degree of smoothness or roughness and requirement for color and gloss can be filled by organic coatings. The article describes abrasive blast cleaning, abrasive waterjet cleaning and finishing, vibratory finishing, barrel finishing, and shot peening for processing iron castings.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006040
EISBN: 978-1-62708-172-6
... lined on the water side to reduce or stop leakage. This typically involves the use of either fabric- (glass cloth or scrim cloth) reinforced coatings or thick-film elastomeric systems, such as asphalt-modified polyurethane, flexible polyurethane, or polyurea coatings. Cracks caused by concrete shrinkage...
Abstract
This article presents information regarding the use of protective coatings in municipal potable water systems, including raw water collection and transmission, water treatment plants, and treated water distribution. It provides useful guidance for the selection and use of protective coatings in these municipal water systems. The most commonplace corrosion-damage mechanisms are highlighted. The article describes the most common materials of construction found in municipal water systems, namely, cast iron, ductile iron, carbon steel, precast concrete cylinder pipe and reinforced concrete pipe, prestressed concrete tanks, and stainless steel. It provides information on the most common generic coating systems used for new steel tanks and water storage tanks. It concludes with a discussion of quality watch-outs when selecting or using protective coatings in municipal water systems.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006059
EISBN: 978-1-62708-172-6
... protection. Only carbon steel conveyance pipelines typically involve applied coatings and linings. These corrosion-protection alternatives mainly consist of epoxy or polyurethane coating systems. The external coatings can also include tape wrap systems, polyurea coatings, and other liquid-applied coating...
Abstract
This article provides information on the municipal wastewater system components such as piping, pump stations, headworks, clarifiers, aeration structures, digesters, biosolids dewatering equipment, and sludge stabilization. It explains the major corrosion damage mechanisms to which those component parts of the system are exposed. It presents useful guidelines for selecting and using protective coatings in municipal sewerage collection systems and water reclamation facilities in wastewater treatment plants. The article includes annotated flow diagrams of a wastewater collection system, wastewater treatment plants, and spreadsheets listing the most widely used generic coating systems by structure and substrate material. It concludes with a section on quality watchouts when selecting or using protective coatings in municipal wastewater systems.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006014
EISBN: 978-1-62708-172-6
... coatings. Examples of thermosetting coatings are two-part epoxies, polyurethanes, polyureas, polyesters, polysiloxanes, and many organic zinc coatings. A coating system for steel in a mild environment may consist of power tool cleaning (SSPC-SP 3) or brush-off blast cleaning (SSPC-SP 7) and application...
Abstract
This article reviews the various substrates for coatings, namely, steel, cast iron, galvanized steel, aluminum, stainless steel, nonferrous metals, concrete, and wood. General guidance for surface preparation and coating selection is provided along with unique requirements for the particular substrate(s).
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006037
EISBN: 978-1-62708-172-6
... Abstract Polymeric floor coatings refer to flooring materials composed of multicomponent thermoset resins formulated with various fillers and pigments that are installed in situ, usually over concrete substrates. Polymeric flooring systems, specified for all industrial and commercial...
Abstract
Polymeric floor coatings refer to flooring materials composed of multicomponent thermoset resins formulated with various fillers and pigments that are installed in situ, usually over concrete substrates. Polymeric flooring systems, specified for all industrial and commercial environments, use a variety of polymer chemistries and are constructed in a variety of methods and designs. This article provides a description of the service conditions for the polymeric flooring systems. It provides information on polymeric flooring systems, including thin-film coatings, self-leveling systems, membrane systems, broadcast systems, troweled systems, and terrazzo. The article also focuses on properties, applications, testing, and factors and requirements to be considered during the installation of polymeric floor coatings. It concludes with a discussion about coating failures, including bonding, cracking, chemical attack, and moisture that affect the polymeric floor coatings on concrete.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006011
EISBN: 978-1-62708-172-6
... of polyurethane coatings include polyester, polyacrylate (acrylic), and polyether polyols. Isocyanate reactions with water and amines to form polyureas also have an important role in anticorrosion coatings. Single-component polyurethane coatings (i.e., moisture cured) are based on the reaction with water to form...
Abstract
Polyurethane is any polymer consisting of a chain of repeating organic units joined by urethane linkages. Polyurethane polymers are formed through step-growth polymerization by making a monomer containing at least two isocyanate functional groups to react with another monomer containing at least two hydroxyl (alcohol) groups. This article provides a detailed account of the protective coatings used in the building, infrastructure, and architectural markets. It focuses on the various types of polyurethane coatings used in these applications: moisture-cure and two-pack aromatic coatings as primers and topcoats, moisture-cure aromatic elastomeric high-build coatings, moisture-cure aliphatic topcoats, two-pack aliphatic polyurethane coatings as topcoats, and one- and two-pack polyurethane dispersion coatings as sealers and topcoats. It also includes a section on the health effects of isocyanates.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006010
EISBN: 978-1-62708-172-6
... Application for Polyureas and High-Solid Coatings Protective Coatings Inspector Program Protective Coatings Specialist Program Spray Application Basics Water-Jetting Program As of January 1, 2013, SSPC, as part of the QP 1 program, established requirements for certification of applicators...
Abstract
This article defines quality, quality assurance, quality control, and quality management of processes, products, and services. It describes the evolution of quality control and quality assurance in the coatings industry. The article also discusses the standards, quality programs, and certifications in the coatings industry.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006050
EISBN: 978-1-62708-172-6
.... Polyureas are thick-film products applied by plural-component spray that cure quickly for rapid return to service. They also have excellent chemical resistance. This is the same technology used for truck bed liners. Polyaspartic coatings are a variation of polyureas that are applied by standard spray...
Abstract
This article identifies the coatings applied to many substrates for both beautification and protection, and the inherent conflicts that exist between the coatings and the buildings they are designed to protect; emphasis is placed on masonry walls. It provides information on the purposes of the coatings in the commercial buildings. The article briefly describes some of the most common types of substrates found in buildings and the coatings commonly associated with each substrate. The selection of the coating system depends on the substrate and service expectations. The article addresses the primary causes of masonry coating problems and also provides a detailed discussion on the wall design considerations, moisture considerations, and coating system challenges in the masonry buildings.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006005
EISBN: 978-1-62708-172-6
... References 1. Primeaux D. , Polyurea-Based Coatings , Protective Organic Coatings , Vol 5B , ASM Handbook , ASM International , 2015 2. “How to Draw Organic Molecules,” IvyRose Holistic , www.ivy-rose.co.uk/Chemistry/Organic/How-to-draw-organic-molecules.php Selected References...
Abstract
This article provides an overview of chemistry and chemical interactions necessary to understand protective coatings. It includes information on elements, atoms, molecules, types of bonding, valence electrons, functional groups, polymer formation, and chemical bonding structures.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003474
EISBN: 978-1-62708-195-5
... of the partially reacted matrix is completed in the molding process. Faster dual-acting presses with accurately controlled parallelism, closing speed, and pressing force are also used in production. These presses have the potential to reduce press cycle time to less than 1 min. Molded coating can be applied during...
Abstract
This article discusses the advantages of polymer matrix composite for automotive application in terms of design drivers, noise, vibration, harshness efficiency, process materials property constraints, safety and reliability, design optimization, structural and appearance requirements, recyclability, and processability. It describes the properties of high-volume composites used in automotive industries. The article provides a discussion on state-of-the-art and developing technologies in automotive field.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006051
EISBN: 978-1-62708-172-6
.... The isocyanate can be combined with other generic materials to enhance chemical, moisture, low-temperature, and abrasion resistance. Aromatic urethanes are typically used as primers, adhesion promoters, and intermediate coats. Polyureas Fast- to very-fast-curing, highly elastic thick-film coatings with good...
Abstract
A coating can be defined as a substance spread over a surface to provide protection or to serve decorative purposes. This article discusses two industrial coating components, namely, nonvolatile components such as the resin or binder, pigments, and any additives that may be incorporated into the formulation; and volatile components such as solvents, or water in emulsions and their composition. It provides general information on volatile organic compounds. The article describes the film-forming mechanisms of various coating types, namely, lacquers, chemically converting coatings, latex coatings, alkyds and other resins, which cure by oxidation, moisture-curing polyurethanes and inorganic zinc primers, and powder coatings. The article concludes with a discussion on the functions of the primer, intermediate coat, and topcoat in coating systems.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006072
EISBN: 978-1-62708-172-6
... Abstract This article provides a basic overview of bridge corrosion, where it occurs on steel and concrete bridge structures, and how to prevent corrosion by using coatings. It describes types of bridge designs, with illustrations, and presents information on how corrosion occurs in different...
Abstract
This article provides a basic overview of bridge corrosion, where it occurs on steel and concrete bridge structures, and how to prevent corrosion by using coatings. It describes types of bridge designs, with illustrations, and presents information on how corrosion occurs in different bridge zones and areas, with illustrations. The article concludes with a discussion on the common methods of coating systems applications on bridge structures and key elements in coating condition assessment.
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006492
EISBN: 978-1-62708-207-5
... coatings and paints. It addresses some of the more common corrosion mechanisms, including corrosion driven by pH extremes, pitting corrosion, crevice corrosion, galvanic corrosion, and filiform corrosion. The article also describes in-plant as well as field application procedures for cleaning and coating...
Abstract
Although aluminum alloys are inherently corrosion resistant, there are many operating environments where they require additional protection. This article describes the conditions under which aluminum is prone to corrode and explains how to prevent it through the addition of conversion coatings and paints. It addresses some of the more common corrosion mechanisms, including corrosion driven by pH extremes, pitting corrosion, crevice corrosion, galvanic corrosion, and filiform corrosion. The article also describes in-plant as well as field application procedures for cleaning and coating, and discusses the advantages and limitations of the various materials and chemicals used.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006070
EISBN: 978-1-62708-172-6
... Abstract Soluble salts on a surface can affect a steel substrate or coating in two principal ways: corrosion acceleration and osmotic blistering. This article provides a detailed discussion on the mechanisms for each of these deleterious effects. It describes the most detrimental anions...
Abstract
Soluble salts on a surface can affect a steel substrate or coating in two principal ways: corrosion acceleration and osmotic blistering. This article provides a detailed discussion on the mechanisms for each of these deleterious effects. It describes the most detrimental anions with regard to corrosion, namely, chlorides, sulfates, and nitrates, and provides information on recognition and testing of the presence of soluble salts. The salt-measurement techniques and commercially available equipment are also described. The article provides information on research regarding tolerable levels of salts beneath coatings. The information shows that there appears to be a threshold limit to the salt contamination that a given coating/coating system can tolerate in a given environment.
Book Chapter
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006939
EISBN: 978-1-62708-395-9
... enhancers, based on their end use. Most common applications include the use of more than one type of surface modifier to improve both appearance and properties. Surface modifiers have been used extensively in the field of polymer processing and coatings. However, more recently, surface modifiers as well...
Abstract
Polymer materials are key building blocks of the modern world, commonly used in packaging, automobiles, building materials, electronics, telecommunications, and many other industries. These commercial applications of polymeric materials would not be possible without the use of additives. This article is divided into five sections: mechanical property modifiers, physical property modifiers, biological function modifiers, processing aids, and colorants. It describes three classes of additives that are used to inhibit biological activity, six classes of mechanical property modifiers, three classes of physical property modifiers, and two classes of both colorants and processing aids.
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