This article is an informative primer on sealants and the role they play in engineered assemblies. It discusses the physical, thermal, chemical, and electrical properties of sealant materials and the various forms in which they are applied, including liquids, pastes, and extruded tapes. It also describes classifications and types, comparing and contrasting sealants made from oil-based caulks, asphalts, coal tar resins, latex acrylic sealants, polyvinyl acetate caulks, solvent acrylics, butyl sealants, polysulfides, polyurethanes, modified silicones, anaerobics, vinyl plastisols, and polypropylenes. In addition, the article provides practical design insight, addressing application requirements, seal configurations, and joint stresses. It concludes with a brief discussion on the use of sealants in aerospace, automotive, electrical, and construction applications.

This article discusses the family characteristics, commercial forms, applications, resin grades, and mechanical and physical properties of traditional engineering thermoplastics in their neat (unmodified) form and as compounds and composites, namely, acrylonitrile-butadiene-styrenes, acrylics, high-density polyethylenes, reinforced polypropylenes, high-impact polystyrenes, polyvinyl chloride, styrene-acrylonitriles, and styrene-maleic anhydrides.

This article describes elastomeric coatings that are suitable for painting flexible plastic substrates. It focuses on coatings systems that find utility in automotive exterior applications, where the requirements of appearance and durability are most severe. The article discusses acrylic polyols, condensation polymers, vapor curing systems, water-based coatings, and coatings for thermoplastic olefins.

Electrodeposition of tin alloys is used to protect steel against corrosion or wear, to impart resistance to etching, and to facilitate soldering. This article focuses on the compositions, operating conditions, advantages, and limitations of methane sulfonic acid plating solutions and fluoborate plating solutions for tin-lead. It briefly describes the solution compositions and operating conditions of tin-bismuth, tin-nickel, and tin-zinc.

Lead has been deposited from a variety of electrolytes, including fluoborates, fluosilicates, sulfamates, and methane sulfonic acid baths. This article provides a discussion on these electrolytic baths and includes information on the process sequence, equipment requirements, and applications of lead plating.

This article describes the steps, bath composition and characteristics, equipment, plating rate, deposit thickness, and applications for different types of nonelectrolytic deposition processes, including electroless nickel plating, electroless copper plating and mechanical plating.

Electroless nickel plating is used to deposit nickel without the use of an electric current. This article provides an overview of the solution composition and characteristics of the electroless nickel bath. It focuses on the metallurgical, mechanical and physical properties of electroless nickel-phosphorus coatings and electroless nickel-boron coatings. The effect of electroless nickel coatings on the fatigue strength of steel is also described. The article includes information on the recommended pretreatment procedures for different ferrous alloys, aluminum alloys, and copper alloys. It presents a detailed account of the equipment and various processes—including bulk and barrel plating—involved in electroless nickel plating, and discusses hydrogen relief methods. The article includes a comprehensive table on nickel plating applications, and concludes with information on electroless nickel coatings on composites and plastics.

This article is a collection of tables that present information on the physical properties of periodic table elements, and maximum service temperatures, dielectric constants and typical dielectric properties of selected nonmetallic materials.

This article covers the three most popular techniques used to characterize the very outermost layers of solid surfaces: Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), and time-of-flight secondary ion mass spectrometry (TOF-SIMS). Some of the more important attributes are listed for preliminary insight into the strengths and limitations of these techniques for chemical characterization of surfaces. The article describes the basic theory behind each of the different techniques, the types of data produced from each, and some typical applications. Also discussed are the different types of samples that can be analyzed and the special sample-handling procedures that must be implemented when preparing to do failure analysis using these surface-sensitive techniques. Data obtained from different material defects are presented for each of the techniques. The examples presented highlight the typical data sets and strengths of each technique.

Differential scanning calorimetry (DSC) is the most common thermal technique for polymer characterization. This article provides a detailed account of the various factors and processes involved in DSC. The discussion covers the equipment used, specimen preparation process, calibration requirements, data analysis, and provides examples of the applications and interpretation of DSC.

This article describes the coating materials, surface-preparation requirements, and application techniques used to protect underground pipelines. It provides a valuable insight into the types of polymer-based coatings that are both cost-effective and widely accepted in the pipeline industry.

This article tabulates materials that are known to have been used in orthopaedic and/or cardiovascular medical devices. The materials are grouped as metals, ceramics and glasses, and synthetic polymers in order. These tables were compiled from the Medical Materials Database which is a product of ASM International and Granta Design available by license online and as an in-house version. The material usage was gleaned from over 24,000 U.S. Food and Drug Administration (USFDA), Center for Devices and Radiological Health, Premarket notifications (510k), and USFDA Premarket Approvals, and other device records that are a part of this database. The database includes other material categories as well. The usage of materials in predicate devices is an efficient tool in the material selection process aiming for regulatory approval.

Iron has been electroplated from a variety of electrolytes, whose bath parameters result in coatings that have widely divergent characteristics according to the specific characteristics desired in the finished product. This article provides an overview of the process description and processing equipment and discusses the properties, advantages, limitations, and principal applications of iron plating. It also describes the environmental, health, and safety considerations of iron plating.

This article focuses on the electroless gold plating technique, describing the advantages and limitations, applications, and properties of plated deposits. It also reviews process variables of the technique, including gold concentration, reducing agent, agitation, and contaminants.

Additives for plastics and elastomers are used to increase the ease of processing and to improve the properties of the final product. Additives improve processing characteristics by increasing lubricity and by stabilizing the polymer. Additives that improve properties include those that decrease static charge development and microbial activity and those that improve flame retardation characteristics, color, light stability, impact resistance, density and mechanical properties. This article focuses on the additives for polymers and elastomers that are used for improving processing--blowing agents, mold-release agents, lubricants, plasticizers, and heat stabilizers--and for improving properties antimicrobials, antioxidants, antistatic agents, colorants, fillers and fiber reinforcements, flame retardants, impact modifiers, light stabilizers, plasticizers, and heat stabilizers. Furthermore, it discusses the method for addition of these additives and the problems faced during compounding.

This article is a comprehensive collection of engineering tables providing information on the mechanical properties of and the techniques for processing and characterizing polymeric materials, such as thermosets, thermoset-matrix unidirectional advanced composites, and unreinforced and carbon-and glass-reinforced engineering thermoplastics. Values are also provided for chemical resistance ratings for selected plastics and metals, and hardness of selected elastomers.

Physically, tantalum is a dark, blue-gray, lusterless metal that exists in two crystalline forms: an alpha-phase with a body-centered cubic structure, and a brittle beta-phase with a tetragonal orientation. This article tabulates the physical and material properties of tantalum. It discusses the use of tantalum in medical electronics and the advantage of tantalum over stainless steel. The article describes the manufacturing and medical applications of tantalum foam.

This article provides a summary of biocompatibility or biological response of metals, ceramics, and polymers used in medical implant, along with their clinical issues. The polymers include ultrahigh-molecular-weight polyethylene, nonresorbable polymer, and resorbable polymers.

The compression molding process is most commonly called the sheet molding compound (SMC) process in reference to the precursor sheet molding compound material it uses. This article discusses the types of materials used for sheet manufacture, and describes the manufacturing and processing parameters of SMC components, providing details on tooling and process advantages and limitations. The article provides a general overview of the types of compression molding processes, including structural compression molding and thermoplastic compression molding.