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Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003374
EISBN: 978-1-62708-195-5
..., contact angle, work of adhesion, solid surface energy, and wetting and wicking. The article describes the change in interphase depending on the reinforcing fiber such as glass fiber, polymeric fiber, and carbon fiber. It emphasizes fiber-matrix adhesion measurements by direct methods, indirect methods...
Abstract
Fiber-matrix adhesion is a variable to be optimized in order to get the best properties and performance in composite materials. This article schematically illustrates fiber matrix interphase for composite materials. It discusses thermodynamics of interphase in terms of surface energy, contact angle, work of adhesion, solid surface energy, and wetting and wicking. The article describes the change in interphase depending on the reinforcing fiber such as glass fiber, polymeric fiber, and carbon fiber. It emphasizes fiber-matrix adhesion measurements by direct methods, indirect methods, and composite laminate tests. The effects of interphase and fiber-matrix adhesion on composite mechanical properties, such as composite on-axis properties, composite off-axis properties, and composite fracture properties, are also discussed.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003461
EISBN: 978-1-62708-195-5
... to effectively handle directionally dependent loads and stresses. It is important to note that not only are composite materials anisotropic because of the macrostructures (fiber orientation and laminate sequence), but also because of the anisotropy in the materials from which they are made. For example, many...
Abstract
As with most engineering materials, the failure of composite materials, no matter how complex, can be divided into three discrete arenas: improper design, improper manufacturing, and improper use of the end product. This article reviews the failure causes from a broad perspective, so that the composites designer, manufacturer, and user can readily see some of the more common issues associated with unique materials. It discusses the three discrete arenas of failure of composite materials: improper design, improper manufacturing, and improper use of the end product.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003033
EISBN: 978-1-62708-200-6
... Abstract This article addresses the types, properties, forms, and applications of fibers that are available for use in fiber-reinforced polymeric matrix composites, including glass, graphite, carbon, aramid, boron, silicon carbide, ceramic, continuous oxide and discontinuous oxide fibers...
Abstract
This article addresses the types, properties, forms, and applications of fibers that are available for use in fiber-reinforced polymeric matrix composites, including glass, graphite, carbon, aramid, boron, silicon carbide, ceramic, continuous oxide and discontinuous oxide fibers. It describes the functions, types, and chemical composition of fiber sizing agents. The article discusses the styles, properties, applications, and weaving methods of unidirectional, two-directional and multidirectionally reinforced fabrics. The article also reviews the use of prepreg resins in aerospace and lower performance applications.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003012
EISBN: 978-1-62708-200-6
... to be more sensitive to light and heat. Fillers and Fiber Reinforcements Inorganic materials can often be combined with polymeric materials to form composite systems with improved properties, where the polymeric material is the matrix and the inorganic material is dispersed as a discrete phase ( Ref 4...
Abstract
Additives for plastics and elastomers are used to increase the ease of processing and to improve the properties of the final product. Additives improve processing characteristics by increasing lubricity and by stabilizing the polymer. Additives that improve properties include those that decrease static charge development and microbial activity and those that improve flame retardation characteristics, color, light stability, impact resistance, density and mechanical properties. This article focuses on the additives for polymers and elastomers that are used for improving processing--blowing agents, mold-release agents, lubricants, plasticizers, and heat stabilizers--and for improving properties antimicrobials, antioxidants, antistatic agents, colorants, fillers and fiber reinforcements, flame retardants, impact modifiers, light stabilizers, plasticizers, and heat stabilizers. Furthermore, it discusses the method for addition of these additives and the problems faced during compounding.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0009074
EISBN: 978-1-62708-177-1
... Abstract This article focuses on the sample preparation methods for titanium honeycomb composites, boron fiber composites, and titanium/polymeric composite hybrids. These include mounting, sectioning, grinding, and polishing. The article also provides information on the sample preparation...
Abstract
This article focuses on the sample preparation methods for titanium honeycomb composites, boron fiber composites, and titanium/polymeric composite hybrids. These include mounting, sectioning, grinding, and polishing. The article also provides information on the sample preparation of unstaged and staged prepreg materials for optical analysis.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0009076
EISBN: 978-1-62708-177-1
... Abstract This article describes the various aspects relating to the selection and preparation of ultrathin-section specimens of fiber-reinforced polymeric composites for examination by transmitted light microscopy. It provides information on the contrast-enhancement methods used by transmitted...
Abstract
This article describes the various aspects relating to the selection and preparation of ultrathin-section specimens of fiber-reinforced polymeric composites for examination by transmitted light microscopy. It provides information on the contrast-enhancement methods used by transmitted-light microscopy and optimization of microscope conditions. Examples of composite ultrathin sections analyzed using transmitted-light microscopy contrast methods are also presented.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006929
EISBN: 978-1-62708-395-9
... materials and resins. It explains how absorbed moisture affects a wide range of properties, including glass transition temperature, flexural and shear modulus,creep, stress relaxation, swelling, tensile and yield strength, and fatigue cracking. It provides relevant data on common polymers, resins, and fiber...
Abstract
This article provides an overview of the physics and math associated with moisture-related failures in plastic components. It develops key equations, showing how they are used to analyze the causes and effects of water uptake, diffusion, and moisture concentration in polymeric materials and resins. It explains how absorbed moisture affects a wide range of properties, including glass transition temperature, flexural and shear modulus,creep, stress relaxation, swelling, tensile and yield strength, and fatigue cracking. It provides relevant data on common polymers, resins, and fiber-resin composites.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0009094
EISBN: 978-1-62708-177-1
... This collection of articles is designed as an instructional reference for preparing fiber-reinforced polymeric-matrix composite materials for examination by optical microscopy and the techniques of optical microscopy used for analysis. It is also meant to be a teaching tool for those who want...
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0009075
EISBN: 978-1-62708-177-1
... of the individual components present. The carbon fibers tend to be very reflective (show a high degree of contrast) and are easily resolved in polymeric resins. By comparison, glass fiber composites tend to absorb light equally across the spectrum, making it difficult to distinguish the individual components...
Abstract
The analysis of composite materials using optical microscopy is a process that can be made easy and efficient with only a few contrast methods and preparation techniques. This article is intended to provide information that will help an investigator select the appropriate microscopy technique for the specific analysis objectives with a given composite material. The article opens with a discussion of macrophotography and microscope alignment, and then goes on to describe various illumination techniques that are useful for specific analysis requirements. These techniques include bright-field illumination, dark-field illumination, polarized-light microscopy, interference and contrast microscopy, and fluorescence microscopy. The article also provides a discussion of sample preparation materials such as dyes, etchants, and stains for the analysis of composite materials using optical microscopy.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003419
EISBN: 978-1-62708-195-5
... reinforcing fiber ideally should be surrounded by matrix without any voids. Fully polymerized thermoplastics have very high molecular weights, meaning that their melt viscosities are at least two orders of magnitude higher than melt viscosities for thermosets, which makes impregnation significantly more...
Abstract
This article describes the characteristics of thermoplastic composites and its material forms. It presents the steps and considerations in manufacturing the thermoplastic composites. The article describes the various techniques of manufacturing, such as consolidation, autoclave molding, diaphragm forming, compression molding, roll forming, bladder molding, liquid molding, filament winding, and pultrusion.
Image
Published: 01 December 2004
. Dark-field illumination, 25× objective. (c) Boron fiber polymeric-matrix composite cross section. Bright-field illumination, 50× objective (200× original magnification)
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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001319
EISBN: 978-1-62708-170-2
... H.X. , and Chang H.W. , Gas Plasma Treatment of Spectra ô Fiber , SAMPE Quarterly , Vol 19 ( No. 4 ), July 1988 21. Nguyen H.X. , Riahi G. , Wood G. , and Poursartip A. , Optimization of Polyethylene Fiber Reinforced Composites Using a Plasma Surface Treatment...
Abstract
This article provides an overview of plasma surface treatments for plastics. It covers the equipment and methods used in plasma processing, providing detailed explanations of the plasma discharge reactions and how they affect surface state and topography. It also provides information on contamination removal, plasma surface modification, plasma-induced grafting, and plasma film deposition.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0009084
EISBN: 978-1-62708-177-1
... on Composite Toughness and Its Measurement , J. Compos. Mater. , Vol 31 ( No. 6 ), 1997 , p 552 – 579 10.1177/002199839703100602 5. Nam J.D. and Seferis J.C. , Anisotropic Thermo-Oxidative Stability of Carbon Fiber Reinforced Polymeric Composites , SAMPE Q. , Vol 24 ( No. 1...
Abstract
Polymer composite materials are subject to degradation if not appropriately protected from the environment. This article describes the effects of heat and atomic oxygen and ultraviolet-light on composite material surfaces, with illustrations.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003030
EISBN: 978-1-62708-200-6
... of friction for various unfilled and filled polymeric materials under dry conditions Material (filler) PV limit at 22 °C (72 °F), MPa · m/s (at velocity, V , m/s) Coefficient of friction PTFE 0.06 (0.5) 0.04–0.1 PTFE (glass fiber) 0.35 (0.05–5.0) 0.1–0.25 PTFE (graphite fiber) 1.05...
Abstract
Tribology is the science and technology of interacting surfaces in relative motion or, the study of friction, wear, and lubrication. This article focuses on friction and wear processes that aid in the evaluation and selection of materials, for polymers and some composites used in friction and wear applications. It provides information on friction, types of wear, and lubrication. The article includes a brief description of the friction and wear test methods, laboratory-scale friction, and wear testing, usually performed either to rank the performance of candidate materials for an application or to investigate a particular wear process. It describes the wear tests conducted with/without abrasives and explains the concept of PV limit (where P is contact pressure and V is velocity). The article concludes with references and tables of friction and wear test data for polymeric materials.
Book Chapter
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003377
EISBN: 978-1-62708-195-5
... * The value of ν L * for polymeric matrix composites at the usual 60 vol% of fiber is of the order of 0.25, while the ratio E T * / E L * is of the order of 0.1 to 0.2. Consequently, the denominator is usually practically equal to unity; hence, the approximation: (Eq 13...
Abstract
A unidirectional fiber composite (UDC) consists of aligned continuous fibers that are embedded in a matrix. This article describes a variety of analytical methods that are used to determine the various physical properties of the UDC. These properties include elasticity, thermal expansion coefficients, moisture swelling coefficients, static and dynamic viscoelastic properties, conductivity, and moisture diffusivity.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003356
EISBN: 978-1-62708-195-5
... composites and concludes with a discussion on biodegradable composites. bio-based resins natural fiber fatty-acid distribution plant oils triglyceride-based monomer acrylated epoxidized soybean oil maleinized soyoil monoglyceride maleinized hydroxylated oil polymer properties ballistic impact...
Abstract
This article describes the synthesis, manufacturing, and properties of both the neat soy-based resins and the glass, flax, and hemp composites. A tabulation of the fatty-acid distribution in various plant oils is provided. The article discusses synthetic pathways for triglyceride-based monomers and provides a discussion on acrylated epoxidized soybean oils (AESO), maleinized soyoil monoglyceride (SOMG/MA), and maleinized hydroxylated oil (HO/MA). The polymer properties of the AESO, SOMG/MA, and HO/MA are also discussed. The article explains the ballistic impact resistance of soy resin composites and concludes with a discussion on biodegradable composites.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0009071
EISBN: 978-1-62708-177-1
... rods to high-performance airplane parts, the use of fiber-reinforced composite materials is becoming more popular due to their high strength-to-weight ratio combined with easy manufacturing methods. Fiber-reinforced polymeric-matrix composites consist of reinforcing fibers and a polymer resin...
Abstract
This article illustrates the polymer matrices used for composite materials. It describes the use of prepeg materials in manufacturing high-performance composites. The article discusses the various infusion processes for the development of fiber-reinforced composites, namely, resin transfer molding, vacuum-assisted resin transfer molding, and resin film infusion. It explains the composite- and matrix-toughening methods for fiber-reinforced composites, such as dispersed-phase toughening and interlayer toughening. The article concludes with information on optical microscopy, which provides an insight into the micro- and macrostructure of fiber-reinforced composites.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003351
EISBN: 978-1-62708-195-5
... properties and understanding of the origins of those properties is important for the task of defining a composite structure for a particular application. This knowledge is needed to understand how that structure will respond to an imposed load or stimulus under a set of conditions. Often, fiber properties...
Abstract
This article provides a summary of the concepts discussed in the articles under the Section “Constituent Materials” in ASM Handbook, Volume 21: Composites. The Section describes the major matrix resins and reinforcing fibers used in composite materials, as well as some of the intermediate material forms available for composite fabrication.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006869
EISBN: 978-1-62708-395-9
... to the increment in friction and high temperature of the contact zone. These are attributed to fiber breakage and the thermal failure of the polymeric matrix ( Ref 21 ). In general, when SFRPs undergo the wear process, the higher portion of the load is sustained by the fibers. Therefore, the polymeric matrix...
Abstract
Reinforced polymers (RPs) are widely used in structural, industrial, automotive, and engineering applications due to their ecofriendly nature and the potential to manipulate their properties. This article addresses the technical synthesis of RPs, referring to their tribological behavior, to provide insights into the contribution and interaction of influential parameters on the wear behavior of polymers. It provides a brief discussion on the effects of significant parameters on RP tribology. The article describes abrasive and adhesive wear and provides a theoretical synthesis of the literature regarding the wear mechanisms of RPs. It also describes the synthesis of abrasive wear failure of different types of RPs and highlights the contribution of these influential parameters. The article addresses the synthesis of adhesive wear failure of different types of RPs.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003432
EISBN: 978-1-62708-195-5
... to document the presence of each ingredient and to ensure that the proper chemical reaction state has been obtained. These resins can be used to make preimpregnated reinforcing fibers (prepreg) or to infiltrate a fiber preform via resin transfer molding, vacuum assisted resin transfer molding, or resin film...
Abstract
This article focuses on epoxy because this resin category has widespread use and because it is tested using quality control measures typical of most resin systems. It explains that a typical resin system will consist of one or more epoxy resins, a curing agent, and a catalyst to control the rate of reaction. The article describes the component material tests, mixed resin system tests, and prepreg tests for the resin system. These tests include high-performance liquid chromatography, infrared spectroscopy, and gel permeation chromatography. The article contains a table that lists typical resin and prepreg property tests.
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