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polymer quenchants
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Series: ASM Handbook
Volume: 4F
Publisher: ASM International
Published: 01 February 2024
DOI: 10.31399/asm.hb.v4F.a0007003
EISBN: 978-1-62708-450-5
... of the linear polymeric structure. Although it is possible to produce polymers by such processes, this approach is not industrially used to prepare the PAG copolymers used to formulate aqueous PAG-based quenchants. To aid in communication, specification writing, purchasing, and so on, it is recommended...
Abstract
This article presents the fundamentals and nomenclature of polymer quenchants and provides a detailed discussion on the polymers used for quenching formulation. The article describes the effect of polymer structure on the quenching mechanism. It also presents the factors affecting polymer quenchant performance. The article details the use of polymer quenchants for intensive quenching and then focuses on the wire patenting processes and polymer quenchant analysis. The article presents the application of polymer quenchants for induction hardening. Finally, it provides details on cooling curve analysis of polymer quenchants.
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Published: 01 August 2013
Fig. 111 Cooling rates of different polymer quenchants at 20% concentration at 25 and 60 °C (80 and 140 °F). PVA, polyvinyl alcohol; PAG, polyalkylene glycol; PVP, polyvinyl pyrrolidone
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Published: 01 February 2024
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Published: 01 February 2024
Fig. 59 Drag-out test results by Hilder. (a) Data for various polymer quenchants, concentrations, and agitation conditions. Test specimen is configured to model typical shapes that may be encountered with actual product parts. PAG, polyalkylene glycol; PVP, polyvinyl pyrrolidone. (b) Effect
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in Quench Factor Characterization of Quenchants for Hardening of Steel
> Steel Heat Treating Technologies
Published: 30 September 2014
Fig. 3 Illustration of the ability of a relatively fast aqueous polymer quenchant to harden different section sizes of AISI 1045 carbon steel. Polymer quenchant concentration: 10%; bath temperature: 32 °C (90 °F)
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in Quench Factor Characterization of Quenchants for Hardening of Steel
> Steel Heat Treating Technologies
Published: 30 September 2014
Fig. 4 Illustration of the ability of a relatively slow aqueous polymer quenchant to harden different section sizes of AISI 4140 low-alloy steel. Polymer quenchant concentration: 20%; bath temperature: 60 °C (140 °F)
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Published: 01 February 2024
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Published: 01 February 2024
Fig. 136 Cooling curve performance of a severely degraded aqueous polymer quenchant compared to water and a fresh solution at the same nominal concentration, bath temperature, and agitation. GPC, gel permeation chromatography
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Published: 01 February 2024
Fig. 137 Effect of various types of oil contaminants on aqueous polymer quenchant cooling curve behavior
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Published: 01 February 2024
Series: ASM Handbook
Volume: 4B
Publisher: ASM International
Published: 30 September 2014
DOI: 10.31399/asm.hb.v04b.a0005932
EISBN: 978-1-62708-166-5
... the polymerization of ethyl oxazoline ( Fig. 15 ) and have the most oillike quenching characteristics of all the polymer quenchants commercially available. As a result, PEOX quenchants are being used in a wide range of applications, from induction hardening of steel and cast iron to tank quenching of high...
Abstract
This article describes various quenchants, namely, water and inorganic salt solutions, polymers (polyvinyl alcohol, polyalkylene glycol, polyethyl oxazoline, polyvinyl pyrrolidone and sodium polyacrylates), quench oils, and molten salts, which are used for heat treatment of ferrous alloys. It also provides information on the steps for controlling quenching performance for polymer quenchants and oils with an emphasis on measuring quenchant performance, safety measures, and oxidation.
Series: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005780
EISBN: 978-1-62708-165-8
... Abstract This article, with the aid of illustrations and curves, describes an experiment used to understand the cooling characteristics and transformation behavior of steel wires during patenting. The two aqueous polymer quenchants used as alternatives for lead baths, are carboxymethyl...
Abstract
This article, with the aid of illustrations and curves, describes an experiment used to understand the cooling characteristics and transformation behavior of steel wires during patenting. The two aqueous polymer quenchants used as alternatives for lead baths, are carboxymethyl cellulose and polyvinyl alcohol. A small amount of polymer additive in spraying could modify the physical properties of the spray medium and improve atomizing status. The concentration-fog flux effect further improves the flexibility of spraying and makes it easier to control the cooling process.
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Published: 01 August 2013
quenchant 1). (c) Explosive wetting with large bubbles remaining on the surface, with polymer depositions remaining on the metal surface (polymer quenchant 2 at lower concentration). (d) Repeated explosive wetting, with large bubbles remaining on the surface (polymer quenchant 2 at higher concentration)
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Published: 01 February 2024
quenchant 1). (c) Explosive wetting, with large bubbles remaining on the surface and polymer depositions remaining on the metal surface (polymer quenchant 2 at lower concentration). (d) Repeated explosive wetting, with large bubbles remaining on the surface (polymer quenchant 2 at higher concentration)
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Published: 01 February 2024
Fig. 124 Quenchant solution viscosity as a function of concentration and temperature for an aqueous solution of a polymer quenchant. A unique family of curves such as these may be obtained for each polymer quenchant of interest.
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Published: 01 February 2024
Fig. 57 The degradation rate of a polyalkylene glycol (PAG) quenchant depends on the molecular weight of the polymer used to formulate it. The repeat-quench test was used to develop these relative degradation curves for 20% aqueous polymer quenchants based on PAG polymers having relative
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Published: 01 February 2024
Fig. 91 Concentration dependence of Kondratyev numbers ( Kn ) for inverse solubility of aqueous polyalkylene glycol polymer quenchant solutions used for cooling time computations. 1: UCON Quenchant E (1%); 2: UCON Quenchant E (5%); 3: UCON Quenchant A (20%); 4: UCON Quenchant E (20%). All
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Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006506
EISBN: 978-1-62708-207-5
... and thin sections, resulting in localized plastic flow and distortion observed after quenching or during machining. Usually, distortion is controlled in aluminum parts by adding polymers to water quenchants to reduce the convective or film coefficient between the part and the water, as discussed further...
Abstract
The fundamental objective of quenching is to preserve, as nearly as possible, a metastable solid solution formed at the solution heat treating temperature, by rapidly cooling to some lower temperature, usually near room temperature. This article provides an overview of the factors used to determine a suitable cooling rate and the appropriate quenching process to develop a suitable cooling rate. It discusses the three distinct stages of quenching: vapor stage, boiling stage, and convection stage. The article reviews the factors that affect the rate of cooling in production operations. It discusses the quenchants that are used in quenching aluminum alloys, namely, hot or cold water and polyalkylene glycol. The article also describes the racking practices for controlling distortion and the level of residual stresses induced during the quench.
Series: ASM Handbook
Volume: 4F
Publisher: ASM International
Published: 01 February 2024
DOI: 10.31399/asm.hb.v4F.9781627084505
EISBN: 978-1-62708-450-5
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in Modeling of Quenching, Residual-Stress Formation, and Quench Cracking
> Metals Process Simulation
Published: 01 November 2010
Fig. 14 Effect of quenchant flow rate on the cooling characteristics of (a) reference oil, (b) 20% polyalkylen glycol polymer quenchant, and (c) water at 40 °C (105 °F). Source: Ref 37
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