Two-component polyurea elastomeric coating/lining systems are the newest technology in the protective coating/lining industry and a wide variety of applications have been developed. These include coating/lining applications over concrete, geotextile membranes, various metals for corrosion and decorative areas, and some plastics. This article discusses the formulation basics of polyurea technology and compares the technology to that of polyurethane and polyurethane/polyurea systems. It addresses performance issues and describes application processing considerations and safety practices of polyurea coating/lining systems.

This article provides an overview of curing techniques, adhesive chemistries, surface preparation, adhesive selection, and medical applications for adhesives. The curing techniques are classified into moisture, irradiation, heat, and anaerobic. The article highlights the common types of curable adhesives used for medical device assembly, including acrylics, cyanoacrylates, epoxies, urethanes, and silicones. Other forms of adhesives, such as hot melts, bioadhesives, and pressure-sensitive adhesives, are also discussed. Adhesives are used for medical device assembly, hard-tissue attachment in the fields of orthopedics and dentistry, and soft-tissue attachment such as wound closure. The typical characteristics and applications of biocompatible medical device adhesives are listed in a table. The article concludes with a section on selection of materials for medical adhesives.

Additives for plastics and elastomers are used to increase the ease of processing and to improve the properties of the final product. Additives improve processing characteristics by increasing lubricity and by stabilizing the polymer. Additives that improve properties include those that decrease static charge development and microbial activity and those that improve flame retardation characteristics, color, light stability, impact resistance, density and mechanical properties. This article focuses on the additives for polymers and elastomers that are used for improving processing--blowing agents, mold-release agents, lubricants, plasticizers, and heat stabilizers--and for improving properties antimicrobials, antioxidants, antistatic agents, colorants, fillers and fiber reinforcements, flame retardants, impact modifiers, light stabilizers, plasticizers, and heat stabilizers. Furthermore, it discusses the method for addition of these additives and the problems faced during compounding.

Injection molding is a process of forcing or injecting a fluid plastic material into a closed mold. The process generally has the advantages of being more readily automated and of permitting finer part details. Injection-molding compounds are thermoplastic or thermosetting materials and their composites that are specifically formulated for the injection-molding process. This article discusses the injection molding process, which includes the two basic categories of thermoplastic and thermoset injection molding, and lists the common thermoplastic and thermoset molding compounds and applications. It also describes the operation of the different types of injection molding machines as well as mold design and process controls. The article also describes the selection of injection-moldable thermosets, and provides an overview of part performance, properties, blowing agents, and aesthetic concerns related to thermoplastic structural-foam injection molding.

Blow molding has emerged as a commercially viable process for manufacturing parts for nonpackaging/industrial markets. This article discusses the machinery required, processing methods, mold types, process parameters, part designs and material distribution of blow molding. It provides an outline of the parison programming system equipped with blow molders to control the parison thickness. The article describes factors that are usually considered to minimize material distribution problems, namely, design, material selection, process control, part performance, and cost.

This article describes the extrusion process, which converts soft, plastic material into a particular form using an extruder, or screw conveyer. It discusses the two main types of plastic extruders, twin-screw and single-screw, estimation of extruder capacity, and design and operations (heating, cooling, downstream sizing, corrugating, and crossheading) of the screw, the most important component of any extruder. It discusses the shapes produced by screw extrusion and the types of extrusion products produced by extrusion processes, including blown-film extrusion, flat-film or sheet extrusion, chill-roll film extrusion, pipe or tube extrusion, wire and cable coverings, extrusion coating, and profile extrusion, and provides some discussion on multiple-screw extruders. The article describes the dimensional accuracy of extrusion products, and lists common defects that occur frequently in the extrusion process.

Rotational molding is a simple but unique process that has the capability of producing small to large hollow items with very uniform wall thicknesses. Providing an overview of the operating principles of rotational molding, this article discusses the key selection factors, including function and property requirements for resins and additives; size, shape, design, and cost of molded parts; equipment type and size; and the type of mold to be used. Commonly used molds include cast aluminum, fabricated sheet metal, nickel deposit, machined aluminum, silicone, fiberglass, and prototype molds.

Thermoforming is a manufacturing process in which thermoplastic sheets are heated, softened, clamped onto a mold, and made to conform to the shape of the mold or forming tool. It is ideally suited to large-volume runs of small items. This article focuses on major phases of thermoforming, namely, sheet transportation, heating, forming/cooling, and trimming, and different thermoforming techniques: basic female forming; basic male forming; matched-mold thermoforming; plug-assist thermoforming; pressure bubble plug-assist vacuum thermoforming; vacuum snapback thermoforming; air-slip thermoforming; and trapped-sheet, contact heat, and pressure thermoforming. It concludes with a discussion on machines and the economic concerns of thermoforming.

This article outlines the fundamentals of polymer science and emphasizes the aspects that are necessary and useful to applications of engineering plastics. The basic structure of polymers influences the properties of both polymers and the plastics made from them. An understanding of this basic structure permits the engineers to understand which polymers may be acceptable for a certain application, and which may not. There are various possible classification schemes for polymers. Typical classification categories include polymerization process, chemical elements that make up the monomer, or crystalline versus noncrystalline structure. The article describes the various aspects of chemical structure that are important to an understanding of polymer properties and, thus, affect eventual end uses. It discusses different types of names assigned to polymers. The article details the aspects of polymer structure and examines the properties of polymers and the way they are altered by structure.

This article discusses the types, properties, and uses of continuous-fiber-reinforced composites, including glass, carbon, aramid, boron, continuous silicon carbide, and aluminum oxide fiber composites. While polyester and vinyl ester resins are the most used matrix materials for commercial applications, epoxy resins, bismaleimide resins, polyimide resins, and thermoplastic resins are used for aerospace applications. The article addresses design considerations as well as product forms and fabrication processes.

Ultrasonic inspection is a nondestructive technique that is useful in both quality control and research applications for flaw detection in fiber-reinforced composite materials. This article describes ultrasonic nondestructive analysis by outlining its three basic types of scans. It reviews the important quality control techniques used during the manufacture of composite components by analyzing tooling control, material control, pattern orientation control, and in-process control.

Relatively limited effort has gone into developing repair processes and materials for composites, in contrast to the significant labor and expense that has gone into the development of these materials for numerous critical applications. As composites gain wider acceptance as aerospace materials, there is a need to understand the requirements of the end users regarding repair of these advanced materials. This article focuses on the repair of graphite-epoxy structures designed in a variety of forms for a wide range of load intensities. Five repair concepts developed for generic laminate repair have been validated in this article through the required environmental and load condition tests. These include bonded-scarf joint flush repair, double-scarf joint flush repair, blind-side banded-scarf repair, blind-side sandwich repair, and bonded external patch repair. A brief note on thermoplastic repair concepts is also provided in this article.

Thermal analysis provides a powerful tool for researchers and engineers in determining both unknown and reproducible behavioral properties of polymer molecules. This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition, chain configuration, conformation of the base polymers, processing of the base polymers with or without additives; and the response to chemical, physical, and mechanical stresses of base polymers as unfilled, shaped articles or as components of composite structures. It also describes thermal analysis techniques, including differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and rheological analysis. This article also summarizes the basic thermal properties used in the application of engineering plastics, such as thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass transition temperatures. It concludes with a discussion of the thermal and related properties of nine thermostat resin systems divided into three groups by low, medium, and high service temperature capabilities.

This article describes the use of conventional machining techniques, laser cutting and water-jet cutting for producing finished composite parts. It explains two representative polymer-matrix composites--graphite and aramid composites--and discusses the machining and drilling problems such as delamination and fiber or resin pullout. The article describes machining and drilling techniques and the necessary tools and cutting parameters. It presents a description of laser cutting. The article also provides information on the advantages, disadvantages, cutting characteristics, and applications of water-jet cutting and abrasive water-jet cutting.

The structural efficiency of a composite structure is established by its joints and assembly. Adhesive bonding, mechanical fastening, and fusion bonding are three types of joining methods for polymer-matrix composites. This article provides information on surface treatment and the applications of adhesive bonding. It discusses the types of adhesives, namely, epoxy adhesives, epoxy-phenolic adhesives, condensation-reaction PI adhesives, addition-reaction PI adhesives, bismaleimide adhesives, and structural adhesives. The article provides information on fastener selection considerations, including corrosion compatibility, fastener materials and strength, head configurations, importance of clamp-up, interference fit fasteners, lightning strike protection, blind fastening, and sensitivity to hole quality. Types of fusion bonding are presented, namely, thermal welding, friction welding, electromagnetic welding, and polymer-coated material welding.

This article introduces the principal methodologies and some advanced technologies that are being applied for nondestructive evaluation (NDE) of fiber-reinforced polymer-matrix composites. These include acoustic emission, ultrasonic, eddy-current, computed tomography, electromagnetic acoustic transducer, radiography, thermography, and low-frequency vibration methods. The article also provides information on NDE methods commonly used for metal-matrix composites.

This article discusses the several aspects of biocompatibility of polymers, including selection of a suitable polymer, specific use of a material, contact of polymer on body site, and duration of the contact. It describes factors influencing the biological response to the polymer in a biocompatibility perspective. These include raw materials, manufacturing process, cleaning and sterilization, and biodegradation and biostability. The article reviews the general testing of polymer, such as chemical, mechanical and thermal tests, to ensure that the polymer is stable and has not been adversely altered due to sterilization or processing. It concludes with a description of the guidance, provided by the regulatory authorities, on the biocompatibility testing of polymers and polymer-containing devices that can aid in selecting the right analysis.

Polymers offer a wide range of choices for medical applications because of their versatility in properties and processing. This article provides an overview of polymeric materials and the characteristics that make them a unique class of materials. It describes the ways to classify polymers, including the polymerization method, how the material deforms, or molecular origin or stability. The article contains tables that list common medical polymers used in medical devices. It describes the medical polymer selection criteria and regulatory aspects of materials selection failure analysis and prevention. Failure analysis and prevention processes to determine the root cause of failures that arise at different stages of the product life cycle are reviewed. The article describes the mechanisms of plastic product failure analysis. It discusses the trends in the use of medical polymers, such as high-performance polymers for implants, tissue engineering, and bioresorbable polymers.

This article explains how ceramic powders are made. It begins by briefly describing the raw materials used in structural clay products, whitewares, refractories, and advanced ceramics. It then examines various additives that promote uniformity at different stages of the process. After a description of the comminution process (wet and dry milling methods), it discusses batching and mixing operations and granulation methods. The article also deals with the effect of process variables and the steps involved in chemical synthesis, including preparation from solution and gas-phase reactions, filtration and washing, and powder recovery techniques. It concludes with a discussion on characterization, centering on size distribution analysis, specific surface area, density, porosity chemical composition, phase, and surface composition.

The large majority of the commercially important glasses are processed from a carefully calculated batch of raw materials that is then melted in special furnaces. Providing an introduction to melting practices of glass production, this article focuses on various finishing methods of glass products, including forming, grinding and polishing, and explores the advantages, disadvantages and steps involved in sol-gel process. It also discusses the types, processes and properties of annealed, laminated, and tempered glass, and presents the steps involved in glass decoration. The article gives a detailed account of production, properties and application of fiberglass, optical fibers, glass spheres and ceramic glasses, and describes the forms, classification, compositions and properties of glass/metal and glass-ceramic/metal seals.