This article illustrates the polymer matrices used for composite materials. It describes the use of prepeg materials in manufacturing high-performance composites. The article discusses the various infusion processes for the development of fiber-reinforced composites, namely, resin transfer molding, vacuum-assisted resin transfer molding, and resin film infusion. It explains the composite- and matrix-toughening methods for fiber-reinforced composites, such as dispersed-phase toughening and interlayer toughening. The article concludes with information on optical microscopy, which provides an insight into the micro- and macrostructure of fiber-reinforced composites.

Hygrothermal behavior of cured composite materials relates to the combined and commonly synergistic effects of moisture absorption and temperature on various physical, chemical and mechanical properties. This article focuses on the influence of resins or matrices, reinforcements, processing, and diffusion on hygrothermal behavior of polymer-matrix composites and provides an outline on general considerations in assessing them. It discusses the hygrothermal testing and conditioning of polymer-matrix composites to assess fundamental hygrothermal behavior. The article provides information on the accelerated aging process for understanding the degradation mechanisms and failure modes in composites. It also describes the effect of moisture absorption on mechanical properties of polymer-matrix composites.

This article presents a comprehendable and comprehensive physics-based approach for characterizing the strength of fiber-reinforced polymer composites. It begins with background information on the goals and attributes of this method. The article then addresses the characterization of fiber failures in laminates, because these are at the highest strengths that can be attained and, therefore, are usually the design objective. An exception would be if the design goal is to maximize energy absorption, rather than static strength. The discussion proceeds to situations in which the matrix fails first, either by intent, by design error, or because of impact damage. The state of the modeling propagation and arrest of matrix damage follows. Comparisons of this physics-based approach are then made to empirically based failure theories.

This article describes the dispersed-phase toughening of thermoset matrices by the development of multiphase-structure thermosetting matrices using rubber and/or thermoplastic materials. It discusses two main methods for manufacturing prepregs, namely, single-pass impregnation and double-pass impregnation. The article illustrates reflected-light optical microscopy techniques to evaluate the morphology of thermoplastic materials for determining the material quality and correlating key microstructural features with material performance.

This article focuses on the process methods and matrix chemistries of ceramic-matrix composites. These methods include pressure-assisted densification, chemical vapor infiltration, melt infiltration, polymer infiltration and pyrolysis, and sol-gel processing. The article discusses the use of a ceramic, preceramic, or metal phase as a fluid or vapor phase reactant to form the matrix. Emphasis is placed on microstructural features that influence ultimate composite properties.

This article discusses the importance of friction and wear and the role of lubricants in composites. It highlights the progress and developments in using different forms of carbon allotropes in composites for improved friction and wear performance of materials. The article focuses on the widely used form known as carbon black (CB) and shows how to deal with friction and wear of polymers and composites when gamma irradiation is involved. It also discusses the role of graphite in composite materials, which is widely used as a dry lubricant. The article examines the tribology of carbon nanotubes (CNTs) as components in composite materials. It also highlights some of the most pronounced examples of graphene use as a reinforcement agent for improving tribological performance in composite matrices. The article concludes with a discussion on the progress of research in diamond-containing composites.

Polymer composite materials are subject to degradation if not appropriately protected from the environment. This article describes the effects of heat and atomic oxygen and ultraviolet-light on composite material surfaces, with illustrations.

This article describes the most significant tests to characterize the properties of constituent materials. It discusses the chemical, physical, and mechanical tests for determining the properties of reinforcement fibers and fabrics. The article provides information on some of the basic materials used for thermoset and thermoplastic resin matrices. It reviews the identification of the individual characteristics of thermoset and thermoplastic resin along with the test methods normally used for their determination. The article contains a table that lists properties and tests for uncured and cured thermoset-matrix resins and prepregs.

The analysis of composite materials using optical microscopy is a process that can be made easy and efficient with only a few contrast methods and preparation techniques. This article is intended to provide information that will help an investigator select the appropriate microscopy technique for the specific analysis objectives with a given composite material. The article opens with a discussion of macrophotography and microscope alignment, and then goes on to describe various illumination techniques that are useful for specific analysis requirements. These techniques include bright-field illumination, dark-field illumination, polarized-light microscopy, interference and contrast microscopy, and fluorescence microscopy. The article also provides a discussion of sample preparation materials such as dyes, etchants, and stains for the analysis of composite materials using optical microscopy.

This article provides a summary of the concepts discussed in the articles under the Section “Constituent Materials” in ASM Handbook, Volume 21: Composites. The Section describes the major matrix resins and reinforcing fibers used in composite materials, as well as some of the intermediate material forms available for composite fabrication.

Microstructural analysis of the composite matrix is necessary to understand the performance of the part and its long-term durability. This article focuses on the microstructural analysis of engineering thermoplastic-matrix composites and the influence of cooling rate and nucleation on the formation of spherulites in high-temperature thermoplastic-matrix carbon-fiber-reinforced composites. It also describes the microstructural analysis of a bio-based thermosetting-matrix natural fiber composite system.

This article explains the key features of the manufacturing techniques for polymer composites. It describes the selection of a technically and economically feasible manufacturing technique for a composite design. The article discusses widely accepted and emerging techniques to manufacture polymer composites such as open-mold techniques.

This article discusses the types, properties, and uses of continuous-fiber-reinforced composites, including glass, carbon, aramid, boron, continuous silicon carbide, and aluminum oxide fiber composites. While polyester and vinyl ester resins are the most used matrix materials for commercial applications, epoxy resins, bismaleimide resins, polyimide resins, and thermoplastic resins are used for aerospace applications. The article addresses design considerations as well as product forms and fabrication processes.

This article highlights the selected applications of advanced polymer-matrix composites, metal-matrix composites, and ceramic matrix composites.

Polymers and polymer composites have become attractive for tribological applications due to their specific material properties. This article begins by discussing the fundamentals of polymer friction and wear. It summarizes the main polymer materials used in tribological applications. The article explains the effects of load, sliding velocity, and temperature on the friction coefficient. It describes three types of wear modes, namely, abrasive, adhesion, and fatigue. The article discusses the frictional behavior of polymer composites and polymer coatings. It concludes by providing information on tribotesting of polymers and polymer composites.

Characterization of nonmechanical properties is performed in the testing and certification of composite materials. This article focuses on the properties of composites that are commonly investigated. The properties include: per ply thickness; constituent content; density; coefficient of thermal expansion and coefficient of moisture expansion; glass transition temperature; thermal conductivity, diffusivity, and specific heat.