This article discusses postconsumer plastics recyclate quantities, the classification of plastics recycling into primary, secondary, tertiary, and quaternary categories, and how the life cycle of plastics is affected by recycling. The recycling processes of polyethylene terephthalate (PET), which accounts for the largest percentage of plastic recycling, high-density polyethylene (HDPE) plastics, the other large-volume plastic recyclate, as well as vinyl resins and polycarbonate resins are described. The life cycle of plastics has four phases: poly formation, part fabrication, product service, and disposal. Landfilling is still the primary method of final disposal, and incineration is another option, but recycling has become a viable alternative. The article presents a comparison between secondary and tertiary recycling.

There are many reasons why plastic materials should not be considered for an application. It is the responsibility of the design/materials engineer to recognize when the expected demands are outside of what the plastic can provide during the expected life-time of the product. This article reviews the numerous considerations that are equally important to help ensure that part failure does not occur. It provides a quick review of thermoplastic and thermoset plastics. The article focuses primarily on thermoset materials that at room temperature are below their glass transition temperature. It describes the motivation for material selection and the goal of the material selection process. The use of material datasheets for material selection as well as the processes involved in plastic material selection and post material selection is also covered.

This article reviews the analytical techniques most commonly used in plastic component failure analysis. These include the Fourier transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and dynamic mechanical analysis. The descriptions of the analytical techniques are supplemented by a series of case studies that include pertinent visual examination results and the corresponding images that aid in the characterization of the failures. The article describes the methods used for determining the molecular weight of a plastic resin. It explains the use of mechanical testing in failure analysis and also describes the considerations in the selection and use of test methods.

This article is a comprehensive collection of engineering tables providing information on the mechanical properties of and the techniques for processing and characterizing polymeric materials, such as thermosets, thermoset-matrix unidirectional advanced composites, and unreinforced and carbon-and glass-reinforced engineering thermoplastics. Values are also provided for chemical resistance ratings for selected plastics and metals, and hardness of selected elastomers.

This article reviews analytical techniques that are most often used in plastic component failure analysis. The description of the techniques is intended to familiarize the reader with the general principles and benefits of the methodologies, namely Fourier transform infrared spectroscopy, energy-dispersive x-ray spectroscopy, differential scanning calorimetry, thermogravimetric analysis, and dynamic mechanical analysis. The article describes the methods for molecular weight assessment and mechanical testing to evaluate plastics and polymers. The descriptions of the analytical techniques are supplemented by a series of case studies to illustrate the significance of each method. The case studies also include pertinent visual examination results and the corresponding images that aided in the characterization of the failures.

The key to any successful part development is the proper choice of material, process, and design matched to the part performance requirements. Understanding the true effects of time, temperature, and rate of loading on material performance can make the difference between a successful application and catastrophic failure. This article provides examples of reliable material performance indicators and common practices to avoid failure. Simple tools and techniques for predicting part mechanical performance integrated with manufacturing concerns, such as flow length and cycle time, are demonstrated. The article describes the prediction of mechanical part performance for stiffness, strength/impact, creep/stress relaxation, and fatigue.

This article is a comprehensive collection of tables that list the values for hardness of plastics, rubber, elastomers, and metals. The tables also list the tensile yield strength and tensile modulus of metals and plastics at room temperature. A comparison of various engineering materials, on the basis of tensile strength, is also provided.

This introductory article describes the various aspects of chemical structure that are important to an understanding of polymer properties and thus their eventual effect on the end-use performance of engineering plastics. The polymers covered include hydrocarbon polymers, carbon-chain polymers, heterochain polymers, and polymers containing aromatic rings. The article also includes some general information on the classification and naming of polymers and plastics. The most important properties of polymers, namely, thermal, mechanical, chemical, electrical, and optical properties, and the most significant influences of structure on those properties are then discussed. A variety of engineering thermoplastics, including some that are regarded as high-performance thermoplastics, are covered in this article. In addition, a few examples of commodity thermoplastics and biodegradable thermoplastics are presented for comparison. Finally, the properties and applications of six common thermosets are briefly considered.

Engineering plastics offer unique product benefits based on physical properties, or combinations of physical properties, that allow vastly improved product performance. Providing an overview of the general characteristics and the mechanical and environmental stress response of engineering plastics, this article discusses various factors, including thermal, mechanical and electrical properties, environmental factors, and material cost that are important in the selection of engineering plastics for specific applications.

This article provides an overview of the physics and math associated with moisture-related failures in plastic components. It develops key equations, showing how they are used to analyze the causes and effects of water uptake, diffusion, and moisture concentration in polymeric materials and resins. It explains how absorbed moisture affects a wide range of properties, including glass transition temperature, flexural and shear modulus,creep, stress relaxation, swelling, tensile and yield strength, and fatigue cracking. It provides relevant data on common polymers, resins, and fiber-resin composites.

This article discusses the thermal properties of engineering plastics and elastomers with respect to chemical composition, chain configuration, and base polymer conformation as determined by thermal analysis. It describes the processing of base polymers with or without additives and their response to chemical, physical, and mechanical stresses whether as an unfilled, shaped article or as a component of a composite structure. It summarizes the basic thermal properties of thermoplastics and thermosets, including thermal conductivity, temperature resistance, thermal expansion, specific heat, and glass transition temperature. It also provides information on polyimide and bismaleimide resin systems. Representative examples of different types of engineering thermoplastics are discussed primarily in terms of structure and thermal properties.

This article describes key processing methods and related design, manufacturing, and application considerations for plastic parts. The methods include injection molding, extrusion, thermoforming, blow molding, rotational molding, compression molding/transfer molding, composites processing, and casting. The article describes principal features incorporated into the design of plastic parts. It concludes with a discussion on the materials selection methodology for plastics.

This article focuses on manufacturing-related failures of injection-molded plastic parts, although the concepts apply to all plastic manufacturing processes It provides detailed examples of failures due to improper material handling, drying, mixing of additives, and molecular packing and orientation. It also presents examples of failures stemming from material degradation improper use of metal inserts, weak weld lines, insufficient curing of thermosets, and inadequate mixing and impregnation in the case of thermoset composites.

This article tabulates materials that are known to have been used in orthopaedic and/or cardiovascular medical devices. The materials are grouped as metals, ceramics and glasses, and synthetic polymers in order. These tables were compiled from the Medical Materials Database which is a product of ASM International and Granta Design available by license online and as an in-house version. The material usage was gleaned from over 24,000 U.S. Food and Drug Administration (USFDA), Center for Devices and Radiological Health, Premarket notifications (510k), and USFDA Premarket Approvals, and other device records that are a part of this database. The database includes other material categories as well. The usage of materials in predicate devices is an efficient tool in the material selection process aiming for regulatory approval.

Thermal analysis provides a powerful tool for researchers and engineers in determining both unknown and reproducible behavioral properties of polymer molecules. This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition, chain configuration, conformation of the base polymers, processing of the base polymers with or without additives; and the response to chemical, physical, and mechanical stresses of base polymers as unfilled, shaped articles or as components of composite structures. It also describes thermal analysis techniques, including differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and rheological analysis. This article also summarizes the basic thermal properties used in the application of engineering plastics, such as thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass transition temperatures. It concludes with a discussion of the thermal and related properties of nine thermostat resin systems divided into three groups by low, medium, and high service temperature capabilities.

While there are many fracture mechanisms that can lead to the failure of a plastic component, environmental stress cracking (ESC) is recognized as one of the leading causes of plastic failure. This article focuses on unpacking the basic concepts of ESC to provide the engineer with a better understanding of how to evaluate and prevent it. It then presents factors that affect and contribute to the susceptibility of plastic to ESC: material factors, chemical factors, stress, and environmental factors. The article includes the collection of background information to understand the circumstances surrounding the failure, a fractographic evaluation to assess the cracking, and analytical testing to evaluate the material, design, manufacturing, and environmental factors.

This article discusses the classification of the attachment and joining methods in plastics, including mechanical fastening, adhesive bonding, solvent bonding, and welding. It describes the mechanical fastening techniques used to join both similar and dissimilar materials with machine screws or bolts, nuts and washers, molded-in threads, self-threading screws, rivets, spring-steel fasteners, press fits, and snap fits. The article explains solvent bonding used for thermoplastic parts, and tabulates the solvent types used with various plastics. It also describes the surface preparation of plastics, chemical treatment for adhesion, and tabulates the adhesive types for bonding plastics to plastics and plastics to nonplastics. The article briefly describes the welding processes of thermoplastics, including fusion welding (hot-tool, hot gas, extrusion, and focused infrared), friction welding (vibration, spin, and ultrasonic), and electromagnetic welding (resistance, induction, dielectric, and microwave). It concludes with the evaluation of welds using destructive and nondestructive testing.

Plastic product failures are directly attributed to one of the following four reasons: omission of a critical performance requirement, improper materials specification, design error, and processing/manufacturing error. Therefore, product failures can be minimized or eliminated if all of these parameters are comprehensively examined during the design process. This article focuses on all of these factors, except processing-related failures, which are outside the design and engineering domain. It is dedicated to the identification and avoidance of common problems associated with the selection and designing of plastic parts. The article provides information on the material-related design criteria that depend on the applications, environmental conditions of use, and performance requirements. It discusses physical properties of plastics based on their relevance to real-world environmental conditions. The most-common design problems related to design considerations are also covered.

Molding compounds are plastic materials in varying stages of pellets or granulation that consist of resin, filler, pigments, reinforcement, plasticizers, and other ingredients ready for use in a molding operation. This article describes the material components and physical properties of sheet molding compounds (SMC). The three types of resin paste mixing techniques, such as batch, batch/continuous, and continuous, for an SMC operation are reviewed. The article discusses the design features and functional operations of the two types of SMC machines, namely, continuous-belt and beltless machines. It explains the formulation and processing of bulk molding compounds and reviews molding methods for bulk molding compounds, including compression, transfer, and injection molding. The effects of the fiber type and length and the matrix type on thermoset bulk molding compounds are discussed. It describes the four injection molding processes of injection molding compounds such as feeding, transporting, injecting, and flowing.

This article focuses on technologies in the protective coatings field, namely, polysiloxane hybrids and related materials. Industrial maintenance topcoats, including silicone alkyds, silicone epoxies, and polysiloxanes are reviewed. The article discusses two major application areas of protective coatings, namely, architectural coatings and automotive clear coats.