This article presents the major thermal spray processes and their subsets, presenting each of the commercially significant processes together with some of their important variations. Each process is presented along with the attributes that influence coating structure and performance. The article summarizes the essential equipment components and necessary controls. The various thermal spray processes are conventional flame spray, detonation gun, high-velocity oxyfuel spray, electric arc spray, and plasma arc spray. Other processes, such as cold spray, underwater plasma arc spray, and extended-arc and other high-energy plasma arc spray, are also considered.

Thermal spray is a generic term for a group of coating processes used to apply metallic, ceramic, cermet, and some polymeric coatings for a broad range of applications. This article provides a brief description of commercially important thermal spray processes, namely, powder-fed flame spray, wire- or rod-fed flame spray, electric arc spray, plasma arc spray, vacuum plasma spray, high-velocity oxyfuel spray, detonation gun deposition, and cold spray, and their advantages. It provides details on the microstructural characteristics of thermal spray coatings. The article also presents information on a wide variety of materials that can be thermal sprayed, such as metals, ceramics, intermetallics, composites, cermets, polymers, and functionally gradient materials. Tables are included, which list the thermal spray processes and coating properties of importance for various industrial applications.

This article introduces thermal spray coatings and describes the various types of coating processes and coating devices, including the flame spray, electric-arc spray, plasma spray, transferred plasma arc, high-velocity oxyfuel, and detonation gun. It provides information on the surface preparation methods and finishing treatments of coated parts. The article also explains the tests to evaluate the coating quality and the effects of coating structures and mechanical properties on coated parts. It concludes with a discussion on the uses of thermal spray coatings.

This article discusses various control processes carried out in powder feeding, thermal spraying, and gas flow of the thermal spray process to standardize the coating quality. Quality of the entire powder feeding process can be achieved by controlling the processing of feeding equipment as well as the characteristics of the powder being fed. Gas flow control can be achieved by using rotameters, critical orifices, and thermal mass flowmeters, whose ability to provide useful information is defined by their resolution, accuracy, linearity, and repeatability. The commercial thermal spray controls discussed here include the open-loop input-based, open-loop output-based, closed-loop input-based, and closed-loop output-based or adaptive controls. The article discusses the common causes and practical solutions for arc starting problems. It also outlines certain important developments in measuring individual and collective particle velocities, temperature, and trajectories as well as other plume characteristics for the plasma spray process.

Significant expansion of thermal spray technology occurred with the invention of plasma spray, detonation gun, and high-velocity oxyfuel (HVOF) deposition technologies. This article provides a brief history of the major initiating inventions/developments of thermal spray processes. It provides information on feedstock materials developed for specific thermal spray processes.

Ceramic coatings are applied to metals to protect them against oxidation and corrosion at room temperature and at elevated temperatures. This article provides a detailed account of the factors to be considered when selecting a ceramic coating and describes the characteristics of various coating materials, namely, silicate glasses, oxides, carbides, silicides, and cermets. It reviews ceramic coating methods: brushing, spraying, dipping, flow coating, combustion flame spraying, plasma-arc flame spraying, detonation gun spraying, pack cementation, fluidized-bed deposition, vapor streaming, troweling, and electrophoresis. The article also includes information on the evaluation of the quality of ceramic coatings.

Hardfacing is a form of surfacing that is applied for the purpose of reducing wear, abrasion, impact, erosion, galling, or cavitation. This article describes the deposition of hardfacing alloys by oxyfuel welding, various arc welding methods, laser welding, and thermal spray processes. It discusses the categories of hardfacing alloy, such as build-up alloys, metal-to-metal wear alloys, metal-to-earth abrasion alloys, tungsten carbides, and nonferrous alloys. A summary of the selection guide for hardfacing alloys is presented in a table. The article describes the procedures for stainless steel weld cladding and the factors influencing joint integrity in dissimilar metal joining. It concludes with a discussion on joining carbon and low-alloy steels to various dissimilar materials (both ferrous and nonferrous) by arc welding.

The hazards associated with thermal spray deposition processes include ultraviolet and infrared radiation; acoustical noise; and by-product production in the forms of nitrous oxides, ozone, fumes, and dust. The most important consideration in health and safety is to use the engineered controls of hazards. This article provides a brief description of the spray booth, the most commonly used engineering tool to separate the operator from the thermal spray process and confine the associated hazards. It also presents guidelines on the proper and safe handling of industrial gases and ventilation and heat exhaust. The article provides information on the personal protective equipment for eyes and skin from radiation, and ears from noise. It also discusses other potential safety hazards associated with thermal spraying, namely, magnetic fields and infrasound.

The shielding gas used in an arc welding process has a significant influence on the overall performance of the welding system. These gases are argon, helium, oxygen, hydrogen, nitrogen, and carbon dioxide. This article discusses the shielding gas selection criteria for plasma arc welding, gas metal arc welding, and flux cored arc welding. It describes the basic properties of shielding gases, namely, dissociation, recombination, reactivity potential, oxidation potential, and gas purity. The article also provides information on the influence of the shielding gas on weld mechanical properties and self-shielded flux cored arc welding.

The shielding gas used in a welding process has a significant influence on the overall performance of the welding system. This article discusses the basic properties of a shielding gas in terms of ionization potential, thermal conductivity, dissociation and recombination, reactivity/oxidation potential, surface tension, gas purity, and gas density. It describes the characteristics of the components of a shielding gas blend. The article discusses the selection of shielding gas for gas-metal arc welding (GMAW), gas-tungsten arc welding (GTAW), and plasma arc welding (PAW), as well as the influence of shielding gas on weld mechanical properties. It concludes with a discussion on flux-cored arc welding.

This article is a compilation of definitions for terms related to welding fundamentals and all welding processes. The processes include arc and resistance welding, friction stir welding, laser beam welding, explosive welding, and ultrasonic welding.

Thermal spray coatings (TSCs) are surface coatings engineered to provide wear-, erosion-, abrasion-, and corrosion-resistant coatings for original equipment manufacture and for the repair and upgrading of in-service equipment. This article presents an overview of five thermal spray processes and the specific flame and arc spray processes used to preserve large steel components and structures. It describes the TSC selection guide and an industrial process procedure guide for applying aluminum and zinc TSCs onto steel.

This article describes the benefits that can be achieved by using thermal spray on particular engine parts of an automobile. These include improvement in fuel consumption, wear resistance and bonding, and reduction of oil consumption, exhaust heat loss, and cooling heat loss. Typical engine parts are cylinder blocks, cylinder bores, cast iron cylinder liners, piston rings, connecting rod bearings, turbochargers, engine valve lifters, exhaust system parts, and oxygen sensors. The article also describes the benefits of using thermal spray on transmission parts such as synchronizer rings and torque converters.

This article provides information on personal protective equipment (PPE), consistent with the Occupational Safety and Health Administration's Personal Protective Equipment Standard (29 CFR 1910.132-138). This standard is intended to protect individuals from the risk of injury by creating a barrier against workplace hazards. This article provides guidelines for establishing PPE programs with an overview of the responsibilities for employers, supervisors, and employees, assessing hazards associated with thermal spray operations, and training workers about PPE, as well as guidelines for selecting, using, and maintaining PPE. It presents an overview of eye, face, head, hand, foot, hearing, fall, and respiratory protection. Respiratory and hearing protection should be used in conjunction with industrial hygiene monitoring.

This article provides an overview of thermal spray processes. It describes the microstructural character of thermal spray coatings as well as the criteria for coating selection. The optimization, parameterization, and surface preparation and treatments for the thermal spray coatings are also discussed. The article illustrates the adhesion of polymer coatings and the thermal spray process used to remove lead-base paint. It provides information on the specifications, standardization, and guidelines for thermal spray applicators.