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pitch-based carbon fibers

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Book Chapter

By Paul J. Walsh
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0009241
EISBN: 978-1-62708-195-5
... Abstract The earliest commercial use of carbon fibers is often attributed to Thomas Edison's carbonization of cotton and bamboo fibers for incandescent lamp filaments. This article describes the manufacture of PAN-based carbon fibers and pitch-based carbon fibers. It discusses the properties...
Image
Published: 01 January 2001
Fig. 4 The modulus of a carbon fiber is determined by the preferred orientation, microstructure, and elastic constants. The relationship between modulus and preferred orientation for a pitch-based carbon fiber is shown. More
Image
Published: 01 November 1995
Fig. 4 Relationship between modulus and preferred orientation for a pitch-based carbon fiber More
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003064
EISBN: 978-1-62708-200-6
... concentrators and, hence, reduce tensile strength. Pitch Precursors Pitch precursors based on petroleum asphalt, coal tar, and polyvinyl chloride can also be used to produce carbon fiber. Pitches are relatively low in cost and high in carbon yield. Their most significant drawback is nonuniformity from...
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006897
EISBN: 978-1-62708-392-8
.... Properties of polyacrylonitrile (PAN) and pitch-based carbon fibers are shown in Table 2 . Carbon fibers are approximately 5 to 10 mm (0.2 to 0.4 in.) in diameter and are usually composed of carbon atoms. Carbon fibers have several benefits, including excessive stiffness, high tensile energy, low weight...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003480
EISBN: 978-1-62708-195-5
... for obtaining high thermal conductivity are pitch-based carbon (also called graphite) fibers, which are used in continuous and discontinuous forms, and two types of ceramic particles, silicon carbide (SiC) and beryllia (beryllium oxide, BeO). As a rule, continuous fibers are much more efficient than...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003422
EISBN: 978-1-62708-195-5
... Precursor Impregnants The two general categories of matrix precursors used for carbon-carbon densification are thermosetting resins, such as phenolics and furfurals, and pitches based on coal tar and petroleum. The thermosetting resins polymerize to form cross- linked, infusible solids. As a result...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003359
EISBN: 978-1-62708-195-5
... loss of fiber properties. More expansive coverage of these fibers is provided in the article “Ceramic Fibers” in this Volume. Carbon Fibers Two classes of carbon fiber, polyacrylonitrile (PAN) and pitch-based fibers, derive quite different structures and properties: the PAN being higher...
Image
Published: 01 January 1990
Fig. 5 Carbon fiber axial modulus versus axial coefficient of thermal expansion for mesophase (pitch-base) and polyacrylonitride-base (pan-base) graphite fibers. Source: Ref 18 More
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003033
EISBN: 978-1-62708-200-6
... precursors to carbon fiber. Carbon fiber based on a PAN precursor generally has a higher tensile strength than a fiber based on any other precursor. This is due to a lack of surface defects, which act as stress concentrators and therefore reduce tensile strength. Pitch Precursors Pitch precursors...
Series: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002465
EISBN: 978-1-62708-194-8
... mandrels Three-dimensional woven/filament wound carbon/carbon (also braided) Phenolic, pitch, and furan resins convertible with inert atmosphere heat to densified carbon char Carbon (rayon, pan, pitch base), graphite fiber prior processed to 1650–2760 °C (3000–5000 °F) for fiber weaving dry...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003373
EISBN: 978-1-62708-195-5
.... Their thermoplastic behavior requires that they either be confined within the object by external means, or be chemically treated (stabilized) prior to heating to carbonization temperatures. Petroleum- or coal-based pitch materials are a good example of this type. Most pitches are solids at room temperature. They can...
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001318
EISBN: 978-1-62708-170-2
... the 1980s, a significant level of research activity focused on the protection of high-performance carbon-carbon that used heat-stabilized polyacrylonitrile (PAN) or pitch-based fibers. These composites have higher strength, higher elastic moduli, and lower thermal expansion coefficients than the rayon-based...
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003031
EISBN: 978-1-62708-200-6
... for the production of low-cost, high-performance carbon fibers was the use of either petroleum- or coal-based pitch as an inexpensive precursor. Pitch-based fibers having elastic moduli of up to 830 GPa (120 × 10 6 psi) are commercially available and are being used in several specialized applications. However...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003398
EISBN: 978-1-62708-195-5
... Conductivity Pitch-based carbon fibers offer considerably higher thermal conductivity ( K L ) than metals and have a much lower density. This comparison is shown in Table 10 . The main use of these fibers is in space applications and thermal cores for electronic modules. The in-plane thermal...
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001101
EISBN: 978-1-62708-162-7
..., secondary processing such as diffusion bonding or pultrusion is needed to make structural elements. Squeeze casting also is feasible for the fabrication of this composite ( Ref 23 ). Fig. 5 Carbon fiber axial modulus versus axial coefficient of thermal expansion for mesophase (pitch-base...
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006936
EISBN: 978-1-62708-395-9
... to detection and characterization. This article focuses on the three common methods for ultrasonic nondestructive inspection of plastics, namely pitch-catch, through-transmission, and pulse-echo, as well as the three basic types of ultrasonic NDE scans: the A-scan, B-scan, and C-scan. The discussion includes...
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003032
EISBN: 978-1-62708-200-6
... reinforcement materials include the base fiber, which is a special variation of high-tenacity rayon tire cord reinforcement, pitch fibers, and polyacrylonitrile fibers. The base fiber is woven into plain, leno, and satin weaves and subsequently carbonized at below 1650 °C (3000 °F). Polyacrylonitrile fibers...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003449
EISBN: 978-1-62708-195-5
... in a significant cost savings. The fiber reinforcement within a CFCC is typically either SiC or carbon, although a number of other oxide and nonoxide fibers are currently under development and several are commercially available. The properties of several ceramic- and carbon-base fibers can be found in Tables...
Book Chapter

Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003039
EISBN: 978-1-62708-200-6
...-modulus fibers and higher energy costs, and because large-scale production economies have not yet been imposed. All fibers, except ultrahigh-modulus pitch and extremely high-modulus pitch, have been successfully filament wound. Carbon and graphite fibers (in order of ascending modulus of strand...