Search Results for photochemical aging

This article describes the processes involved in photochemical aging and weathering of polymeric materials. It explains how solar radiation, especially in the UV range, combines with atmospheric oxygen, driving photooxidation and the development of unstable photoproducts that cause various types of damage when they decompose, including the scission of carbon bonds and polymer chains. The article illustrates some of the degradation reactions that occur in different polymers and presents an overview of the strategies used to prevent such reactions or otherwise mitigate their effects.

Photochemical machining (PCM), also known as chemical blanking, is a metal-etching process that uses a photoresist to define the locations where the metal will be etched. This article describes the major steps used in the PCM process, namely, the preparation of the phototool, selection of the metal, preparation of the workpiece, masking with photoresists, etching, and stripping and inspection. The article reviews various design considerations for the PCM process. These include dimensional limitations, tolerances, and edge quality. The article also discusses the advantages, disadvantages, and applications of the PCM process.

This article presents a general overview of outdoor weather aging factors, their effects on the performance of polymeric materials, and the accelerated test methods that can be used to investigate those effects. These test methods are used to characterize material performance when subjected to specific, often controlled, and well-defined factors. The article also presents an overview of weathering instrument types that simulate outdoor stress factors.

This article describes weathering and environmental factors that contribute to degradation in plastics, including temperature variations, moisture, sunlight, oxidation, microbiologic attack, and other environmental elements. It presents a general overview of aging factors, their effects on plastic materials, and the accelerated test methods that can be used to estimate the reaction of a plastic component during actual use. The article focuses on the determination of service temperature as it indicates the ability of a material to retain a certain property, when exposed to elevated temperatures for an extended period of time. It concludes by describing various degradation processes, namely, thermal degradation, thermal oxidative degradation, photooxidative degradation, environmental corrosion, and chemical corrosion and discussing the ways of detecting these degradation processes.

Nickel-base alloys can be machined by techniques that are used for iron-base alloys. This article discusses the effects of distortion and microstructure on the machinability of nickel alloys. It tabulates the classification of nickel alloys based on machining characteristics. The article describes the machining operations performed on nickel alloys, such as turning, planing and shaping, broaching, reaming, drilling, tapping and threading, milling, sawing, and grinding. It provides information on the cutting fluids used in the machining of nickel alloys. The article also analyzes nontraditional machining methods that are suitable for shaping high-temperature, high-strength nickel alloys. These include electrochemical machining, electron beam machining, and laser beam machining.

This article discusses the composition of the major components of dental composite resins: organic resin matrix, filler, coupling agents, and initiator-accelerator systems. It describes the properties of composite resins that are related to the amount and type of filler and resin-matrix compositions. The article also discusses the compositions, properties, and clinical applications of polyacid-modified composite resins and resin-modified glass-ionomer cements. It concludes with information on biodegradation and biocompatibility of resin-based restorative materials.

Addition of beryllium, up to about 2 wt″, produces dramatic effects in copper, nickel, aluminum, magnesium, gold, zinc, and other base metal alloys. This article provides information on the chemical composition, microstructure, heat treatment, fabrication characteristics, production steps and physical metallurgy of beryllium-copper, beryllium-nickel, and beryllium-aluminum alloy, and tabulates their mechanical, electrical and physical properties, and temper designations. It describes the important features of this alloy group, including information on safe handling. Additionally, the article presents examples of the beneficial properties of beryllium-copper alloys and quantifies some of the major reasons for their selection for particular applications.

Paints and protective coatings are the most common means of protecting materials from deterioration. This article focuses on coating degradation that results from the environmental interaction with the coatings. The major environmental influences of the degradation include energy (solar radiation, heat and temperature variation, and nuclear radiation), permeation (moisture, solvent retention, chemical, and oxygen), stress (drying and curing, vibration, and impact and abrasion), and biological influences (microbiological and macrobiological).

This article discusses coating products available for use in the aerospace industry that are compliant with regulations requiring reductions in emissions from organic solvents. The coating products addressed include primers, topcoats, and chemical milling maskants. It describes their characteristics and limitations compared to conventional noncompliant materials. The article addresses the methods and products commonly used achieve regulatory compliance: waterborne coatings, exempt-solvent-based coatings, high-solids coatings, powder coating, and electro-deposition.

This article focuses on a variety of laser beam machining (LBM) operations of aluminum and its alloys, namely, laser cutting, laser drilling, laser milling, laser turning, laser grooving, laser scribing, laser marking, and laser micromachining. It presents different approaches for carrying out machining operations, laser processing parameters, efficiency and accuracy of the process, and the effect of laser processing parameters on the quality of the machined surface. The article provides an overview of the various conventional (chip forming) and nonconventional machining techniques employed for aluminum-based materials. A comparison of the various aspects of LBM with other non-conventional techniques is also presented. The article also describes the features of LBM techniques employed for aluminum and its alloys for different types of machining.

This article discusses the environmental influences on protective coating films that can result in deterioration. These environmental factors can be classified into four groups: (1) energy: solar, heat; (2) permeation: moisture, solvent, chemical, and gas; (3) stress: drying and curing-internal stress, and vibration-external stress; and (4) biological influences such as microbiological, mildew, and marine fouling.

Simulated service testing is the most reliable predictor of corrosion behavior that is important for specific objectives. These include materials selection, predicting the probable service life of a product or structure, evaluating new commercial alloys and processes, and calibrating laboratory corrosion tests in short of in-plant tests and actual service experience. This article provides a detailed discussion on the types of atmospheres used in simulated service testing. It describes the specifics of atmospheric-corrosion test that include equipment, test arrangement, and test specimen; factors affecting atmospheric corrosion; and evaluation of exposed atmospheric-corrosion panels. The article concludes with a discussion on the empirical model used for analyzing the atmospheric-corrosion measurements for estimating the service life of the part being evaluated.

Nanotechnology and smart-coating technologies have been reported to show great promise for improved performance in critical areas such as corrosion resistance, durability, and conductivity. This article exemplifies nanofilms and nanomaterials used in coatings applications, including carbon nanotubes, silica, metals/metal oxides, ceramics, clays, buckyballs, graphene, polymers, titanium dioxide, and waxes. These can be produced by a variety of methods, including chemical vapor deposition, plasma arcing, electrodeposition, sol-gel synthesis, and ball milling. The application of nanotechnology and the development of smart coatings have been dependent largely on the availability of analytical and imaging techniques such as Raman spectroscopy, scanning and transmission electron microscopy, atomic force microscopy, and scanning tunneling microscopy.

Life-cycle engineering is a part-, system-, or process-related tool for the investigation of environmental parameters based on technical and economic measures. This article focuses on life-cycle engineering as a method for evaluating impacts. It describes the four steps of life-cycle analysis, namely, goal definition and scoping, inventory analysis, impact assessment and interpretation, and improvement analysis. The article discusses the applications of life-cycle analysis results and presents a case history of life-cycle analysis of an automobile fender.

This article presents a general survey of corrosive agents and processes that exist within what are usually considered the protective environments of museums and historic collections. It reviews the corrosion influencing factors, such as humidity, temperature, and light. The article provides a list of pollutants and their sources in museums and collections. It discusses the sources of corrosion, including plastic and wood, sulfur, and carbonyl compounds. The article describes the preservation steps for materials in museum to eliminate the corrosive sources acting on the objects and to avoid other potentially damaging materials.

This article describes post-processing techniques for machining, finishing, heat treating, and deburring used to remove additive manufacturing (AM) metallic workpieces from a base plate and subsequent techniques to enhance printed workpieces. The AM processes include powder bed fusion, binder jetting, and direct energy deposition. The discussion provides information on powder removal, powder recycling and conditioning, part removal, and part enhancement. The mechanism, applications, advantages, and limitations of mechanical, radiation, and chemical-finishing processes as well as the properties of the resulting material are also covered.

This article discusses the principal process steps, specifications, defects, applications, advantages, and disadvantages of chemical milling (CM) in aerospace industries. The process steps include precleaning, masking, scribing, etching, final cleaning, stripping, and mechanical finishing. The article describes the variables that affect undercut and surface finish obtained by CM. The mechanical properties of chemically milled parts are also discussed.

Laser surface hardening is a noncontact process that provides a chemically inert and clean environment as well as flexible integration with operating systems. This article provides a brief discussion on the various conventional surface-modification techniques to enhance the surface and mechanical properties of ferrous and nonferrous alloys. The techniques are physical vapor deposition, chemical vapor deposition, sputtering, ion plating, electroplating, electroless plating, and displacement plating. The article describes five categories of laser surface modification, namely, laser surface heat treatment, laser surface melting such as skin melting or glazing, laser direct metal deposition such as cladding, alloying, and hardfacing, laser physical vapor deposition, and laser shock peening. The article provides detailed information on absorptivity, laser scanning technology, and thermokinetic phase transformations. It also describes the influence of cooling rate on laser heat treatment and the effect of processing parameters on temperature, microstructure, and case depth hardness.

This article reviews the applications of traditional glasses in architecture, transportation, construction, houseware, containers, and fibers. It also describes uses of specialty glasses for aerospace and military applications, biomedical and dental applications, chemical-resistant applications, lighting, information display, electronic processing and electronic devices, optical and ophthalmic products, and communications equipment.

Polyvinylidene fluoride (PVDF)-based coatings are typically used in outdoor applications that require exceptionally high performance and excellent long-term exterior durability with little maintenance. This article provides a background of three fluoropolymers most commonly used for coatings, namely, PVDF, polyvinyl fluoride, and polytetrafluoroethylene. It focuses on general properties, polymerization, resin types, coating formulation, technology of organic coatings, coating properties, and health and related safety considerations of PVDF. The article describes the application and typical end uses of PVDF-based coatings and the opportunities for improvement in PVDF-based coatings as with all organic coatings.