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Image
Published: 01 January 1994
Fig. 1 Schematic of a hot water rinse station in a spray phosphating line
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Image
Published: 01 January 1994
Fig. 3 Sequence of operations for spray zinc phosphating of 80 mm (3.2 in.) mortar shell casings before painting. Total area, inside and outside, of each shell was 0.1 m 2 (1 ft 2 ); coating weight ranged from 1.7 to 2.1 g/m 2 (5.6 × 10 −3 to 6.9 × 10 −3 oz/ft 2 ). Solution
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Image
Published: 01 January 1994
Fig. 4 Immersion phosphating tank for batch coating of small components. Drum into which parts are loaded is shown in immersion position.
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Image
Published: 01 January 1994
Fig. 7 Automatic, conveyorized cleaning, immersion zinc phosphating, and lubricating of 80 mm (3.2 in.) mortar shell blanks (1010 steel) before cold forming. Average area of shell blanks was 0.1 m 2 (1 ft 2 ); coating weight, 16 g/m 2 (5.2 × 10 −2 oz/ft 2 ). Conveyor speed was 0.033 m/s
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Image
Published: 01 January 1994
Fig. 9 Sequence of operations for spray zinc phosphating of automotive bodies Stage Type Composition Temperature Time,s °C °F 1 Organic solvent Mineral spirits 30 86 60 2 Alkaline cleaner Titanated, alkali 6.0 g/L (5.0 × 10 −2 lb/gal) 60–65 140–150 70 3
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Image
Published: 01 January 1994
Fig. 10 Plot of zinc phosphating concentrate consumed vs. area covered for small threaded components coated to 10.8 g/m2 (3.5 × 10 −2 oz/ft 2 ) with barrel phosphating
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Image
Published: 01 January 1994
Fig. 16 Methods for removing sludge from a phosphating tank. (a) Settling tank. (b) Continuously operating cloth belt filter. (c) Tilting plate separator, thickener, and filter press. Source: Ref 15
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Image
Published: 01 December 1998
Fig. 5 Immersion phosphating tank for batch coating of small parts. Drum into which parts are loaded is shown in immersion position
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Book Chapter
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001274
EISBN: 978-1-62708-170-2
... Abstract This article focuses on the types, composition, and applications of phosphate coatings and describes the characteristics of phosphate-coated ferrous and nonferrous materials, including steel and aluminum. It addresses five successive process fundamentals: cleaning, rinsing, phosphating...
Abstract
This article focuses on the types, composition, and applications of phosphate coatings and describes the characteristics of phosphate-coated ferrous and nonferrous materials, including steel and aluminum. It addresses five successive process fundamentals: cleaning, rinsing, phosphating, rinsing after phosphating, and chromic acid rinsing. The article describes the techniques for controlling the chemical composition of various phosphating solutions. It discusses the equipment and factors that influence equipment requirements in immersion and spray systems. The article also describes the controlling procedures of coating weight and crystal size. It provides guidelines for choosing phosphate coatings based on application, coating weight requirements, and recommended process parameters. The article concludes with a discussion on safety precautions and the treatment of effluents from phosphating plants.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003678
EISBN: 978-1-62708-182-5
... Abstract Phosphating is used in the metalworking industry to treat substrates like iron, steel, galvanized steel, aluminum, copper, and magnesium and its alloys. This article provides an overview of the types, uses, and theory of phosphate coatings and their formation. It also discusses...
Abstract
Phosphating is used in the metalworking industry to treat substrates like iron, steel, galvanized steel, aluminum, copper, and magnesium and its alloys. This article provides an overview of the types, uses, and theory of phosphate coatings and their formation. It also discusses the composition of phosphating baths, phosphate layers, and their analysis, as well as the process hardware necessary to realize these treatments. A summary of the different types of phosphate layers is tabulated, and the chemical formulas for a number of different phosphate compounds that are theoretically possible in crystalline phosphate layers are illustrated. The article presents four chemically important phosphating steps, namely, cleaning, activation or conditioning, phosphating, and posttreatment plus standard rinsing. It describes the physical and chemical properties by gravimetric analysis, chemical analysis, structure and morphology, thermal analysis, and alkaline resistance.
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006884
EISBN: 978-1-62708-392-8
... Abstract Calcium phosphates react to form more stable salts in aqueous solutions. This phenomenon has been applied to the solidification process for the dental and medical cement calcium phosphate cement, which consists of multiple phases of calcium phosphates and calcium salts; solidification...
Abstract
Calcium phosphates react to form more stable salts in aqueous solutions. This phenomenon has been applied to the solidification process for the dental and medical cement calcium phosphate cement, which consists of multiple phases of calcium phosphates and calcium salts; solidification occurs by the formation of hydroxyapatite. Dicalcium phosphate consists of crystal water along with anhydrous and dihydrate salts. This article summarizes research achievements regarding dicalcium phosphate dihydrate (DCPD) production with controlled morphology and reactivity, including effects of an additive and of production conditions on precipitation. It also summarizes achievements made in the hybridization of nano-apatite onto DCPD particles.
Image
Published: 01 June 2012
Fig. 8 Solubility diagram of some calcium phosphates. DCPA, dicalcium phosphate anhydrous; DCPD, dicalcium phosphate dehydrate; OCP, octacalcium phosphate; α- and β-TCP, tricalciumphosphate; HA, hydroxyapatite; and TTCP, tetracalcium phosphate. Source: Ref 40
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Image
Published: 01 January 1994
Fig. 2 Plot of manganese phosphate coating weight vs. time of exposure of steel surface to phosphating solution
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Image
Published: 01 January 1994
Fig. 5 Drum used in batch phosphate coating of small components
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Image
Published: 01 January 1994
Fig. 11 Photomicrographs of microstructures for principal phosphate coatings. (a) Heavy zinc phosphate. (b) Microcrystalline zinc phosphate. (c) Iron phosphate (primarily iron oxide). (d) Manganese phosphate. 125×
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Image
Published: 01 January 1994
Fig. 12 Immersion tank for coating lightweight phosphated components with a soluble oil. Skimming trough removes floating globules of oil that might cling to parts.
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Image
Published: 01 January 1994
Fig. 13 Tank used for dip coating of phosphated parts with greaselike materials that require temperature monitoring
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Image
Published: 01 January 1994
Fig. 15 Sludge-settling methods for immersion phosphate tanks. (a) Sloping bottom. (b) Removable settling box. (c) Conical-formed floor. Source: Ref 14
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Image
Published: 01 January 1994
Fig. 17 Flowchart showing typical sludge output produced by zinc phosphate coil coating line. Source: Ref 17
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Published: 01 January 1994
Fig. 18 Flowchart showing sludge output produced by zinc phosphate coil coating line retrofitted with a filter press. Source: Ref 17
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