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Series: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005402
EISBN: 978-1-62708-196-2
... Abstract A phase diagram is a graphical representation of the phase equilibria of materials in terms of temperature, composition, and pressure. This article provides an overview on the background of phase diagram calculation software. It presents an algorithm to calculate binary stable phase...
Abstract
A phase diagram is a graphical representation of the phase equilibria of materials in terms of temperature, composition, and pressure. This article provides an overview on the background of phase diagram calculation software. It presents an algorithm to calculate binary stable phase equilibria. The article summarizes a rapid method to obtain a thermodynamic description of a multicomponent system. It also provides information on thermodynamically calculated phase diagrams.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005206
EISBN: 978-1-62708-187-0
... Abstract This article discusses the application of thermodynamic in the form of phase diagrams for visually representing the state of a material and for understanding the solidification of alloys. It presents the derivation of the relationship between the Gibbs energy functions and phase...
Abstract
This article discusses the application of thermodynamic in the form of phase diagrams for visually representing the state of a material and for understanding the solidification of alloys. It presents the derivation of the relationship between the Gibbs energy functions and phase diagrams, which forms the basis for the calculation of phase diagrams (CALPHAD) method. The article also discusses the calculation of phase diagrams and solidification by using the Scheil-Gulliver equation.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006221
EISBN: 978-1-62708-163-4
... Abstract The application of phase diagrams is instrumental in solid-state transformations for the processing and heat treatment of alloys. A unary phase diagram plots the phase changes of one element as a function of temperature and pressure. This article discusses the unary system that can...
Abstract
The application of phase diagrams is instrumental in solid-state transformations for the processing and heat treatment of alloys. A unary phase diagram plots the phase changes of one element as a function of temperature and pressure. This article discusses the unary system that can exist as a solid, liquid, and/or gas, depending on the specific combination of temperature and pressure. It describes the accomplishment of conversion between weight percentage and atomic percentage in a binary system by the use of formulas. The article analyzes the effects of alloying on melting/solidification and on solid-state transformations. It explains the construction of phase diagrams by the Gibbs phase rule and the Lever rule. The article also reviews the various types of alloy systems that involve solid-state transformations. It concludes with information on the sources of phase diagram.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006223
EISBN: 978-1-62708-163-4
... Abstract Thermodynamic descriptions have become available for a large number of alloy systems and allow the calculation of the phase diagrams of multicomponent alloys. This article begins with a discussion on three laws of thermodynamics: the Law of Conservation of Energy, the Second Law...
Abstract
Thermodynamic descriptions have become available for a large number of alloy systems and allow the calculation of the phase diagrams of multicomponent alloys. This article begins with a discussion on three laws of thermodynamics: the Law of Conservation of Energy, the Second Law of Thermodynamics, and the Third Law of Thermodynamics. It informs that for transformations that occur at a constant temperature and pressure, the relative stability of the system is determined by its Gibbs free energy. The article describes the Gibbs free energy of a single-component unary system and the Gibbs free energy of a binary solution. It schematically illustrates the structure of a binary solid solution with interatomic bonds and shows how the equilibrium state of an alloy can be obtained from the free-energy curves at a given temperature. The article concludes with information on the construction of eutectic and binary phase diagrams from Gibbs free-energy curves.
Book
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.9781627081634
EISBN: 978-1-62708-163-4
Book Chapter
Series: ASM Handbook
Volume: 4D
Publisher: ASM International
Published: 01 October 2014
DOI: 10.31399/asm.hb.v04d.a0005995
EISBN: 978-1-62708-168-9
... Abstract This article is a collection of two iron-carbon phase diagrams. iron-carbon phase diagram weight percent Iron-Carbon Equilibrium Diagrams Fig. 1 Iron-carbon equilibrium diagram from Metal Progress Materials and Process Engineering Databook , American Society...
Abstract
This article is a collection of two iron-carbon phase diagrams.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006231
EISBN: 978-1-62708-163-4
... Abstract This article describes the liquidus plots, isothermal plots, and isopleth plots used for a hypothetical ternary phase space diagram. It discusses the single-phase boundary (SPB) line and zero-phase fraction (ZPF) line for carbon-chromium-iron isopleth. The article illustrates the Gibbs...
Abstract
This article describes the liquidus plots, isothermal plots, and isopleth plots used for a hypothetical ternary phase space diagram. It discusses the single-phase boundary (SPB) line and zero-phase fraction (ZPF) line for carbon-chromium-iron isopleth. The article illustrates the Gibbs triangle for plotting ternary composition and discusses the ternary three-phase phase diagrams by using tie triangles. It describes the peritectic system with three-phase equilibrium and ternary four-phase equilibrium. The article presents representative binary iron phase diagrams, showing ferrite stabilization (iron-chromium) and austenite stabilization (iron-nickel).
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006246
EISBN: 978-1-62708-163-4
... Abstract This article presents ternary alloy phase diagrams to be used primarily by engineers to solve industrial problems. The diagrams presented are for stable equilibrium conditions, with the exception of metastable conditions for some diagrams involving carbon and iron. In some ternary...
Abstract
This article presents ternary alloy phase diagrams to be used primarily by engineers to solve industrial problems. The diagrams presented are for stable equilibrium conditions, with the exception of metastable conditions for some diagrams involving carbon and iron. In some ternary diagrams involving carbon and iron, the symbol M is used to represent both iron and the other metallic element when the two metals substitute for each other in a carbide phase.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006247
EISBN: 978-1-62708-163-4
... Abstract This article provides a discussion on binary alloy phase diagrams published in this handbook. All diagrams presented are for stable equilibrium conditions, except where metastable conditions are indicated. binary alloy phase diagrams crystal structure The 1083 binary...
Abstract
This article provides a discussion on binary alloy phase diagrams published in this handbook. All diagrams presented are for stable equilibrium conditions, except where metastable conditions are indicated.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003085
EISBN: 978-1-62708-199-3
... Abstract Alloy phase diagrams are useful for the development, fabrication, design and control of heat treatment procedures that will produce the required mechanical, physical, and chemical properties of new alloys. They are also useful in solving problems that arise in their performance...
Abstract
Alloy phase diagrams are useful for the development, fabrication, design and control of heat treatment procedures that will produce the required mechanical, physical, and chemical properties of new alloys. They are also useful in solving problems that arise in their performance in commercial applications, thus improving product predictability. This article describes different equilibrium phase diagrams (unary, binary, and ternary) and microstructures, description terms, and general principles of reading alloy phase diagrams. Further, the article discusses plotting schemes; areas in a phase diagram; and the position and shapes of the points, lines, surfaces, and intersections, which are controlled by thermodynamic principles and properties of all phases that comprise the system. It also illustrates the application of the stated principles with suitable phase diagrams.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006145
EISBN: 978-1-62708-163-4
... Abstract This article is a compilation of binary alloy phase diagrams for which arsenic (As) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary...
Abstract
This article is a compilation of binary alloy phase diagrams for which arsenic (As) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006171
EISBN: 978-1-62708-163-4
... Abstract This article is a compilation of binary alloy phase diagrams for which indium (In) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary...
Abstract
This article is a compilation of binary alloy phase diagrams for which indium (In) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006149
EISBN: 978-1-62708-163-4
... Abstract This article is a compilation of binary alloy phase diagrams for which beryllium (Be) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary...
Abstract
This article is a compilation of binary alloy phase diagrams for which beryllium (Be) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006219
EISBN: 978-1-62708-163-4
... Abstract This article is a compilation of binary alloy phase diagrams for which ytterbium (Yb) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary...
Abstract
This article is a compilation of binary alloy phase diagrams for which ytterbium (Yb) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006220
EISBN: 978-1-62708-163-4
... Abstract This article is a compilation of binary alloy phase diagrams for which zinc (Zn) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system...
Abstract
This article is a compilation of binary alloy phase diagrams for which zinc (Zn) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006209
EISBN: 978-1-62708-163-4
... Abstract This article is a compilation of binary alloy phase diagrams for which tantalum (Ta) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary...
Abstract
This article is a compilation of binary alloy phase diagrams for which tantalum (Ta) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006199
EISBN: 978-1-62708-163-4
... Abstract This article is a compilation of binary alloy phase diagrams for which rhodium (Rh) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary...
Abstract
This article is a compilation of binary alloy phase diagrams for which rhodium (Rh) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006210
EISBN: 978-1-62708-163-4
... Abstract This article is a compilation of binary alloy phase diagrams for which terbium (Tb) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary...
Abstract
This article is a compilation of binary alloy phase diagrams for which terbium (Tb) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006173
EISBN: 978-1-62708-163-4
... Abstract This article is a compilation of binary alloy phase diagrams for which lanthanum (La) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary...
Abstract
This article is a compilation of binary alloy phase diagrams for which lanthanum (La) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006200
EISBN: 978-1-62708-163-4
... Abstract This article is a compilation of binary alloy phase diagrams for which ruthenium (Ru) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary...
Abstract
This article is a compilation of binary alloy phase diagrams for which ruthenium (Ru) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
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