This article discusses the chief magnetic characteristics of permanent magnet materials. It provides a detailed description on nominal compositions; principal magnet designations; magnetic, physical, and mechanical properties; selection criteria; and applications of the permanent magnet materials, which include magnet steels, magnet alloys, alnico alloys, platinum-cobalt alloys, cobalt and rare-earth alloys, hard ferrites, iron-chromium-cobalt alloys, and neodymium-iron-boron alloys.

Premanent magnet refers to solid materials that have sufficiently high resistance to demagnetizing fields and sufficiently high magnetic flux output to provide useful and stable magnetic fields. Permanent magnet materials include a variety of alloys, intermetallics, and ceramics. This article discusses the composition, properties, and applications of permanent magnetic materials, such as hysteresis alloys used in motors. It primarily focuses on the stability of magnetic fields that influences reversible and irreversible losses in magnetization with time, and the choice of magnet material, component shape and magnetic circuit arrangement.

In some phase diagrams, the appearance of several reactions is the result of the presence of intermediate phases. These are phases whose chemical compositions are intermediate between two pure metals, and whose crystalline structures are different from those of the pure metals. This article describes the order-disorder transformation that typically occurs on cooling from a disordered solid solution to an ordered phase. It provides a table that lists selected superlattice structures and alloy phases that order according to each superlattice. The article informs that spinodal decomposition has been particularly useful in the production of permanent magnet materials, because the morphologies favor high magnetic coercivities. It also describes the theory of spinodal decomposition with a simple binary phase diagram.

This article contains tables that present engineering data for the following metals and their alloys: aluminum, copper, iron, lead, magnesium, nickel, tin, titanium, zinc, precious metals, permanent magnet materials, pure metals, rare earth metals, and actinide metals. Data presented include density, linear thermal expansion, thermal conductivity, electrical conductivity, resistivity, and approximate melting temperature. The tables also present approximate equivalent hardness numbers for austenitic steels, nonaustenitic steels, austenitic stainless steel sheet, wrought aluminum products, wrought copper, and cartridge brass. The article lists conversion factors classified according to the quantity/property of interest.

This article contains a table that lists the density of metals and alloys. It presents information on aluminum, copper, iron, lead, magnesium, nickel, tin, titanium, and zinc, an their respective alloys. Information on wrought alloys, permanent magnet materials, precious metals, and rare earth metals is also listed.

Powder metallurgy (PM) techniques are effective in making magnetically soft components for use in magnetic part applications. This article provides an account of the factors affecting magnetism, permeability, and hysteresis losses. It includes information on the magnetic properties of PM materials that are used in the magnetic part applications, namely, pure iron, phosphorus irons, ferritic stainless steels, 50 nickel-50 iron, and silicon irons. The article describes the factors that affect and optimize magnetic properties. It contains a table that lists the magnetic properties possible in metal injection molding parts. The article also discusses ferromagnetic cores used in alternating current applications and some permanent magnets, such as rare earth-cobalt magnets and neodymium-iron-boron (neo) magnets.

Microstructural analysis of specialized types of magnetic materials is centered on the examination of optical, electron, and scanning probe metallographic techniques unique to magnetic materials. This article provides a comprehensive overview of magnetic materials, their characteristics and sample preparation procedures. It reviews the methods pertaining to the microstructural examination of bulk magnetic materials, including microscopy techniques specified to magnetic materials characterization, with specific examples. The techniques used in the study of magnetic domain structures (microstructure) include the magneto-optical Kerr method, the Faraday method, the Bitter technique, scanning electron microscopy (magnetic contrast Types I and II), scanning electron microscopy with polarization analysis, Lorentz transmission electron microscopy, and magnetic force microscopy. The article also illustrates the microstructure of different types of soft magnetic material and permanent magnets.

Rare earth metals belong to Group IIIA of the periodic table that includes scandium, yttrium, and the lanthanide elements which are lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium. This article classifies the rare earth metals based on their purity level, which are designated as research grades (>99.8% pure) and commercial grades (95% - 98% pure), and describes the preparation and purification, including solid-state electrolysis. It further discusses physical, mechanical, and chemical properties; electronic configurations; crystal structures, and explains the alloy forming characteristics of rare earth elements. The article concludes by describing the various applications of commercial-grade rare earth elements and commercial alloys, which incorporates rare earth elements as additives.

This article contains a table that lists the electrical conductivity and resistivity of selected metals, alloys, and materials at ambient temperature. These include aluminum and aluminum alloys; copper and copper alloys; electrical heating alloys; instrument and control alloys; relay steels and alloys; thermostat metals; electrical contact materials; and magnetically soft materials.

Casting can be done with either expendable molds for one-time use or permanent molds for reuse many times. This article lists the various methods used to fabricate expendable molds from permanent patterns. The methods include molding of sand with clay, inorganic binders, or organic resins; shell molding of sand with a thin resin-bonded shell; no-bond vacuum molding of sand; plaster-mold casting; ceramic-mold casting; rammed graphite molding; and magnetic (no-bond) molding of ferrous shot. The article tabulates a general comparison of casting methods and discusses the basic requirements of foundry molds.

This article presents an overview of the electric and magnetic parameters and discusses the significance of these parameters for electronic applications. It describes the components of analog and digital electronic circuits. The article reviews the augmenting technologies: magnetic and special technologies such as electrooptical.

This article discusses the ferromagnetic properties of soft magnetic materials, explaining the effects of impurities, alloying elements, heat treatment, grain size, and grain orientation on soft magnetic materials. It describes the types of soft magnetic materials, which include high-purity iron, low-carbon irons, silicon (electrical) steels, nickel-iron alloys, iron-cobalt alloys, ferritic stainless steels, amorphous metals, and ferrites (ceramics). Finally, the article provides a short note on alloys for magnetic temperature compensation.

Cobalt finds its use in various applications owing to its magnetic properties, corrosion resistance, wear resistance, and its strength at elevated temperatures. This article discusses the mining and processing of cobalt and cobalt alloys. It describes the types of cobalt alloys, including wear-resistant alloys, high-temperature alloys, corrosion-resistant alloys, and special-purpose alloys. The article provides data on the chemical composition, mechanical properties, and physical properties of these alloys. Further, it provides information on the uses of cobalt in superalloys, cemented carbides, magnetic materials, low-expansion alloys, and high-speed tool steels.

Magnetic-particle inspection is a nondestructive testing technique used to locate surface and subsurface discontinuities in ferromagnetic materials. Beginning with an overview of the applications, advantages, and limitations of magnetic-particle inspection, this article provides a detailed account of the portable power sources available for magnetization, and the different ways of generating magnetic fields using yokes, coils, central conductors, prod contacts, direct-contact, and induced current. In addition, the article discusses the characteristics and classification, and properties of magnetic particles and suspended liquids. Finally, the article outlines the types of discontinuities (surface and subsurface) that can be identified by magnetic-particle inspection and the importance of demagnetization after inspection.

Magnetic field testing includes some widely used nondestructive evaluation methods to inspect magnetic materials for defects such as cracks, voids, and inclusions and to assess other material properties, such as grain size, texture, and hardness. This article discusses the principles of such defect detection, providing details on the origin, generation, and assessment of leakage field data. In addition, it discusses the metallurgical and magnetic properties of magnetic materials and the applications of magnetic field testing.

This article describes the basic features of electromagnetic acoustic transducers (EMATs) and discusses their existing and some potential uses within the field of ultrasonic nondestructive evaluation (UNDE). It provides sufficient basic and practical information to make an informed choice when considering the transducer to be used for any particular UNDE application. The article describes how different types of EMATs operate and presents their fundamental and some practical limitations. It summarizes the representative literature for electromagnetic acoustic transducer UNDE applications. Some successful uses of EMATs are mentioned to illustrate the depth, range, and potential of commercial EMAT applications. The article concludes with information on the commercial sources for EMAT systems and components.

Material properties are the link between the basic structure and composition of the material and the service performance of a part or component. This article describes the most significant properties that must be considered when choosing a metal for a given application, namely physical properties (mass characteristics and thermal, electrical, magnetic, radiation, and optical properties), chemical properties (corrosion and oxidation resistance) and mechanical properties (tensile and yield strength, elongation, toughness, hardness, creep, and fatigue). The article also contains tables that list room-temperature physical properties, vapor pressures, and mechanical properties for various metals.

Magnetically soft materials are characterized by their low coercivity, an essential requirement for irons and steels selected for any application involving electromagnetic induction cycling. This article provides information on ferromagnetic material properties and how they are affected by impurities, alloying additions, heat treatment, residual stress, and grain size. It also describes classification and testing methods for magnetically soft materials such as high-purity iron, low-carbon steels, silicon steels, iron-aluminum alloys, nickel-iron alloys, iron-cobalt alloys, ferrites, and stainless steels. The article also addresses corrosion resistance and provides insights on the selection of alloys for power generation applications, including motors, generators, and transformers. A short note on the design and fabrication of magnetic cores is also included.