This article provides a detailed account of particle-induced x-ray emission (PIXE), covering the basic principles of PIXE analysis and calibration and quality-assurance protocols employed. A comparative study on PIXE and x-ray fluorescence is then presented. The article also discusses the applications of PIXE in atmospheric physics and chemistry, external proton milliprobes and historical analysis, and PIXE microprobes.

Magnetic-particle inspection is a method of locating surface and subsurface discontinuities in ferromagnetic materials. This article discusses the applications and advantages and limitations of magnetic-particle inspection. It describes magnetic fields in terms of magnetized ring, magnetized bar, circular magnetization, longitudinal magnetization, and effects of flux direction. General applications, advantages, and limitations of the various magnetizing methods used in magnetic-particle inspection are listed in a table. The article discusses the items that must be considered in establishing a set of procedures for the magnetic-particle inspection of a specific part: type of current, type of magnetic particles, method of magnetization, direction of magnetization, magnitude of applied current, and equipment. It concludes with a discussion on demagnetization after magnetic-particle inspection.

Impact or percussive wear is defined as the wear of a solid surface that is due to percussion, which is a repetitive exposure to dynamic contact by another body. Impact wear, however, has many analogies to the field of erosive wear. The main difference is that, in impact wear situations, the bodies tend to be large and contact in a well-defined location in a controlled way, unlike erosion where the eroding particles are small and interact randomly with the target surface. This article describes some generic features and modes of impact wear of metals, ceramics, and polymers. It discusses the processes involved in testing and modeling of impact wear, and includes two case studies.

This article introduces thermal spray coatings and describes the various types of coating processes and coating devices, including the flame spray, electric-arc spray, plasma spray, transferred plasma arc, high-velocity oxyfuel, and detonation gun. It provides information on the surface preparation methods and finishing treatments of coated parts. The article also explains the tests to evaluate the coating quality and the effects of coating structures and mechanical properties on coated parts. It concludes with a discussion on the uses of thermal spray coatings.

Tribology is the science and technology of interacting surfaces in relative motion or, the study of friction, wear, and lubrication. This article focuses on friction and wear processes that aid in the evaluation and selection of materials, for polymers and some composites used in friction and wear applications. It provides information on friction, types of wear, and lubrication. The article includes a brief description of the friction and wear test methods, laboratory-scale friction, and wear testing, usually performed either to rank the performance of candidate materials for an application or to investigate a particular wear process. It describes the wear tests conducted with/without abrasives and explains the concept of PV limit (where P is contact pressure and V is velocity). The article concludes with references and tables of friction and wear test data for polymeric materials.

This article provides a general technical description of thermal spray coatings used for corrosion protection in atmospheric and aqueous environments. It further discusses two basic coating approaches of corrosion protection, namely, the sacrificial coating of thermal spray aluminum (TSA) and thermal spray zinc (TSZ), and the barrier-type coating of corrosion-resistant materials. The emphasis is on sacrificial coatings. The article describes the steps involved in the application of TSA and TSZ: surface preparation, coating deposition, and postspray treatment. It discusses their field exposure tests and application history. The article also contains helpful information on the dense barrier coatings by high-velocity spraying processes along with their corrosion performance.

Shot peening is a method of cold working in which compressive stresses are induced in the exposed surface layers of metallic parts by the impingement of a stream of shot, directed at the metal surface at high velocity under controlled conditions. This article focuses on the major variables, applications, and limitations of shot peening and provides information on peening action, surface coverage, and peening intensity. It discusses the equipment used for shot recycling and shot propelling as well as the types and sizes of media used for peening. The article describes the problems in shot peening of production parts. It concludes with information on the SAE standard J442 that describes the test strips, strip holder, and gage used in measuring shot peening intensity.

Corrosion is the electrochemical reaction of a material and its environment. This article addresses those forms of corrosion that contribute directly to the failure of metal parts or that render them susceptible to failure by some other mechanism. Various forms of corrosion covered are galvanic corrosion, uniform corrosion, pitting, crevice corrosion, intergranular corrosion, selective leaching, and velocity-affected corrosion. In particular, mechanisms of corrosive attack for specific forms of corrosion, as well as evaluation and factors contributing to these forms, are described. These reviews of corrosion forms and mechanisms are intended to assist the reader in developing an understanding of the underlying principles of corrosion; acquiring such an understanding is the first step in recognizing and analyzing corrosion-related failures and in formulating preventive measures.

This article focuses on the significant fundamental powder characteristics, which include particle size, particle size distribution, particle shape, and powder purity, followed by an overview of general and individual powder production processes such as mechanical, chemical, electrochemical, atomizing, oxide reduction, and thermal decomposition processes. It also covers the consolidation of powders by pressing and sintering, as well as by high density methods. Further emphasis is provided on the distinguishing features of powders, their manufacturing processes, compacting processes, and consolidated part properties. In addition, a glossary of powder metallurgy terms is included.

Ores, which consist of the primary valuable mineral, predominant gangue content, valuable by-products, and detrimental impurities, are extracted and directed to mineral processing. This article describes the mineral processing facilities, such as crushers, grinders, concentrators, separators, and flotation devices that are used for particle size reduction, separation of particles according to their settling rates in fluids and dewatering of concentrate particles. It explains the basic principles, flow diagrams, ore concentrate preparation methods, and equipment of major types of metallurgical processes, including pyrometallurgical, hydrometallurgical, and electrometallurgical processes.

Sintering provides the interparticle bonding that generates the attractive forces needed to hold together the otherwise loose ceramic powder mass. It also improves hardness, strength, transparency, toughness, electrical conductivity, thermal expansion, magnetic saturation, corrosion resistance, and other properties. This article discusses the fundamentals of sintering and its effects on pore structures and particle density. It addresses some of the more common sintering methods, including solid-state, liquid-phase, and gas pressure sintering, and presents alternative processes such as reaction sintering and self-propagating, high-temperature synthesis. It also describes several pressure densification methods, including hot isostatic pressing, gas pressure sintering, molten particle deposition, and sol-gel processing. The article concludes with a section on grain growth that discusses the underlying mechanisms and kinetics and the relationship between grain growth and densification.

This article describes the general categories and metallurgy of heat treatable aluminum alloys. It briefly reviews the key impurities and each of the principal alloying elements in aluminum alloys, namely, copper, magnesium, manganese, silicon, zinc, iron, lithium, titanium, boron, zirconium, chromium, vanadium, scandium, nickel, tin, and bismuth. The article discusses the secondary phases in aluminum alloys, namely, nonmetallic inclusions, porosity, primary particles, constituent particles, dispersoids, precipitates, grain and dislocation structure, and crystallographic texture. It also discusses the mechanisms used for strengthening aluminum alloys, including solid-solution hardening, grain-size strengthening, work or strain hardening, and precipitation hardening. The process of precipitation hardening involves solution heat treatment, quenching, and subsequent aging of the as-quenched supersaturated solid solution. The article briefly discusses these processes of precipitation hardening. It also reviews precipitation in various alloy systems, including 2xxx, 6xxx, 7xxx, aluminum-lithium, and Al-Mg-Li systems.

Erosion is the progressive loss of original material from a solid surface due to mechanical interaction between that surface and a fluid, a multicomponent fluid, an impinging liquid, or impinging solid particles. The detrimental effects of erosion have caused problems in a number of industries. This article describes the processes involved in erosion of ductile materials, brittle materials, and elastomers. Some examples of erosive wear failures are given on abrasive erosion, liquid impingement erosion, cavitation, and erosion-corrosion. In addition, the article provides information on the selection of materials for applications in which erosive wear failures can occur.

Mechanical testing is an evaluative tool used by the failure analyst to collect data regarding the macro- and micromechanical properties of the materials being examined. This article provides information on a few important considerations regarding mechanical testing that the failure analyst must keep in mind. These considerations include the test location and orientation, the use of raw material certifications, the certifications potentially not representing the hardware, and the determination of valid test results. The article introduces the concepts of various mechanical testing techniques and discusses the advantages and limitations of each technique when used in failure analysis. The focus is on various types of static load testing, hardness testing, and impact testing. The testing types covered include uniaxial tension testing, uniaxial compression testing, bend testing, hardness testing, macroindentation hardness, microindentation hardness, and the impact toughness test.

This article considers the main characteristics of wear mechanisms and how they can be identified. Some identification examples are reported, with the warning that this task can be difficult because of the presence of disturbing factors such as contaminants or possible additional damage of the worn products after the tribological process. Then, the article describes some examples of wear processes, considering possible transitions and/or interactions of the mechanism of fretting wear, rolling-sliding wear, abrasive wear, and solid-particle erosion wear. The role of tribological parameters on the material response is presented using the wear map concept, which is very useful and informative in several respects. The article concludes with guidelines for the selection of suitable surface treatments to avoid wear failures.

After solidification and cooling, further processing and finishing of the castings are required. This article describes the general operations of shakeout, grinding, cleaning, and inspection of castings, with particular emphasis on automation technology. It illustrates the vertical core knockout machine and the A-frame core knockout machine and lists the advantages and disadvantages of the knockout machines. The article describes the general factors in automated or manual gate removal process. It concludes with discussion on the various types of inspection, such as liquid penetrant inspection, pressure testing, radiographic inspection, magnetic particle inspection, and ultrasonic inspection.

Cemented carbides belong to a class of hard, wear-resistant, refractory materials in which the hard carbide particles are bound together, or cemented, by a ductile metal binder. Cermet refers to a composite of a ceramic material with a metallic binder. This article discusses the manufacture, composition, classifications, and physical and mechanical properties of cemented carbides. It describes the application of hard coatings to cemented carbides by physical or chemical vapor deposition (PVD or CVD). Tungsten carbide-cobalt alloys, submicron tungsten carbide-cobalt alloys, and alloys containing tungsten carbide, titanium carbide, and cobalt are used for machining applications. The article also provides an overview of cermets used in machining applications.

Wear of metals occurs by plastic displacement of surface and near-surface material, and by detachment of particles that form wear debris. This article presents a table that contains the classification of wear. It describes the testing and evaluation of wear and talks about the abrasive wear, lubrication and lubricated wear, and selection of steels for wear resistance. The article discusses the effect of alloying elements, composition, and mechanical properties of carbon and low-alloy steels at elevated temperatures. It talks about the fatigue resistance characteristics of steels, and describes the forms of embrittlement associated with carbon and low-alloy steels. The article provides information on the effect of composition, manufacturing practices, and microstructure on notch toughness of steels. Finally, it explains the effects of alloy elements, inclusion content, microstructure and heat treatment on fracture toughness of steels.

In the handling of molten aluminum, it is fairly common to use filters as a part of the melting unit and in the gating and/or riser system. This article describes the methods of in-furnace and in-mold filtration, with emphasis on the filtration of molten aluminum. It discusses the factors that influence the formation of inclusions. The article describes the three basic methods of mechanically removing or separating inclusions from molten metal. The methods include sedimentation, flotation, and positive filtration. The article provides a discussion on the types of molten-metal filters, including bonded-particle filters, cartridge filters, and ceramic foam filters. It lists the factors that are important in achieving optimum performance of any in-furnace filtering application. The article concludes with information on filtered metal quality.

Powder forging is an extension of the conventional press and sinter powder metallurgy process, which is recognized as an effective technology for producing a variety of parts to net or near-net shape. This article focuses on the material considerations, such as powder characteristics, alloy development, and inclusion assessment; and process considerations, such as process stages, tool design, and secondary operations; of ferrous alloy powder forging. The mechanical properties of powder forged materials are also reviewed. The article discusses the quality assurance tests for powder forged materials: the part dimensions and surface finish measurement, magnetic particle inspection, metallographic analysis, and nondestructive testing. It concludes with a discussion on the applications of powder forged parts with examples.