The primary market for metal powder is the production of powder metallurgy (PM) parts, which are dominated primarily by iron and copper powders. This article reviews the chemical and pyrotechnics applications of ferrous and nonferrous powders. It describes the characteristics of iron powder used in oxygen scavengers and chemical reactive warmers and heaters. Metal powders used as fuels in solid propellants, pyrotechnic devices, explosives, and similar applications are reviewed. Atomized aluminum, magnesium, tungsten, and zirconium powders are also discussed.

The inhibitors currently in use are generally complex mixtures of reaction products and have been formulated to meet the demands of a very competitive industry. This article discusses these demands on inhibitor formulation. The varying characteristics and number of organic inhibitors are explained by the varying characteristics of oil wells and gas wells. Water injection systems and pipelines are also discussed. The article describes the factors that influence the corrosivity of produced fluids and the various treatments applicable for oil, gas, and pumping wells. It examines the primary causes of corrosion inhibition in waterfloods: oxygen contamination and acid gases dissolved in the brine. A discussion on the bacteria-induced corrosion is provided. The article also explains various tests available for field corrosion monitoring. It details the methods used to monitor corrosion rates and inhibitor effectiveness. The article concludes information on the computerization of inhibitor treating programs.

This article briefly describes water and steam chemistry, which influence the effect of corrosion in boilers. The appropriate control measures to prevent corrosion in boilers are also presented. The article provides a discussion on the common causes of fluid-side corrosion such as flow-accelerated corrosion, oxygen pitting, chelant corrosion, caustic corrosion, acid corrosion, organic corrosion, phosphate corrosion, hydrogen damage, and corrosion-assisted cracking.

This article discusses the environmental factors and kinetics of atmospheric corrosion, aqueous corrosion, and soil corrosion of carbon steels. It also provides information on corrosion in concrete and steel boilers.

This article discusses the particular corrosion problems encountered and the corrosion control methods used in petroleum production (i.e., upstream) and the storage and transportation of oil and gas (i.e., midstream) up to the refinery (i.e., downstream). These control methods include proper material selection, protective coatings, cathodic protection systems, use of inhibitors, use of nonmetallic materials, and control of the environment. The article reviews the aspects of corrosion that tend to be unique to corrosion as encountered in applications involving oil and gas exploration and production. It discusses corrosion problems that are specific to the various types of environments or equipment used in secondary recovery, including producing wells, producing flow lines, and injection wells. Corrosion mitigation methods and guidelines are also discussed for each type of environment.

The corrosion process that occurs in industrial systems is often difficult to discern until extensive deterioration has occurred. For boilers to function properly, the incoming water must be processed to meet the water quality required for the boiler. This article discusses pretreatment methods of the incoming water and preboiler corrosion protection methods. It analyzes internal treatment and condensate treatment of boilers. The article discusses three types of cooling systems: once-through systems, open recirculating systems, and closed recirculating systems. The corrosion processes which occur in water-recirculating systems and the effect of dissolved gases, temperature, pH, suspended solids, dissolved salts, and scale deposition on corrosivity of water, are also reviewed. The article also considers anodic and cathodic inhibitors and the control of corrosion in municipal water systems.

This article provides useful information on the occurrence of corrosion in crude oil refinery units, namely, crude unit, catalytic and thermal cracking units, hydroprocessing units, amine sweetening units, and sour water units. Types and applications of corrosion inhibitors, namely, neutralizers, filming inhibitors, scavengers, microbiocides, and anti-foulants and scale inhibitors, are reviewed. The article describes the direct and indirect corrosion monitoring methods used to reduce equipment damage due to corrosion events and to assess the reliability and useful service life of process equipment.

This article addresses the major heat-transfer components of the water-steam loop of a power plant. It describes the various types of condensers, including water-cooled condensers and air-cooled condensers. The article explains the corrosion mechanisms encountered in the condensers, including erosion-corrosion, galvanic corrosion, and pitting corrosion. It discusses the types of deaerators and deals with their corrosion problems. The article provides a discussion on two types of feedwater heaters: channel feedwater heaters and header feedwater heaters. It summarizes the corrosion problems associated with common feedwater heater tube materials.

Failures in boilers and other equipment taking place in power plants that use steam as the working fluid are discussed in this article. The discussion is mainly concerned with failures in Rankine cycle systems that use fossil fuels as the primary heat source. The general procedure and techniques followed in failure investigation of boilers and related equipment are discussed. The article is framed with an objective to provide systematic information on various damage mechanisms leading to the failure of boiler tubes, headers, and drums, supplemented by representative case studies for a greater understanding of the respective damage mechanism.

This article explains the main types and characteristic causes of failures in boilers and other equipment in stationary and marine power plants that use steam as the working fluid with examples. It focuses on the distinctive features of each type that enable the failure analyst to determine the cause and suggest corrective action. The causes of failures include tube rupture, corrosion or scaling, fatigue, erosion, and stress-corrosion cracking. The article also describes the procedures for conducting a failure analysis.

This article describes the processes involved in photochemical aging and weathering of polymeric materials. It explains how solar radiation, especially in the UV range, combines with atmospheric oxygen, driving photooxidation and the development of unstable photoproducts that cause various types of damage when they decompose, including the scission of carbon bonds and polymer chains. The article illustrates some of the degradation reactions that occur in different polymers and presents an overview of the strategies used to prevent such reactions or otherwise mitigate their effects.

This article explains how an engineer might go about assessing the risk of microbiologically influenced corrosion (MIC) in an industrial situation. It describes the systems that are susceptible to the effects of MIC by sulfate-reducing bacteria (SRB). The article discusses the effects of microorganisms other than SRB on metals. SRB-related problems, which are the most common MIC issue, are also explored. The article describes the test procedures used to enumerate microbiological populations. It concludes with a discussion on risk assessment based on operating conditions.

This article describes the various factors that affect the extent of corrosion resulting from galvanic coupling. The factors include galvanic series, polarization behavior, and geometric relationship of metals and alloys. The article briefly discusses the various modes of attack that lead to galvanic corrosion of anodic members. It also explains the three electrochemical techniques of screening tests for predicting galvanic corrosion. The electrochemical techniques comprise of potential measurements, current measurements, and polarization measurements. The article provides a detailed discussion on the performance of alloy groupings. It concludes with information on various control methods that reduce or eliminate galvanic-corrosion effects.

This article focuses on lubricants classified as either internal combustion engine or nonengine lubricants, and the lubricant additives. The functional groups of chemically active and inert additives, as well as friction modifiers and other additives, are described in detail. The chemically active additives include dispersants, detergents, antiwear, and extreme-pressure agents, oxidation inhibitors, and rust and corrosion inhibitors. The chemically inert additives include emulsifiers, demulsifiers, pour-point depressants, foam inhibitors, and viscosity improvers. The article also discusses the multifunctional nature of additives and concludes with information on lubricant formulation.

This article describes the casting characteristics and practices of copper and copper alloys. It discusses the melting and melt control of copper alloys, including various melt treatments to improve melt quality. These treatments include fluxing and metal refining, degassing, deoxidation, grain refining, and filtration. The article provides a discussion on these melt treatments for group I to III alloys. It describes the three categories of furnaces for melting copper casting alloys: crucible furnaces, open-flame furnaces, and induction furnaces. The article explains the important factors that influence the selection of a casting method. It discusses the production of copper alloy castings. The article concludes with information on the gating and feeding systems used in production of copper alloy castings.

This article focuses on the use of indium and bismuth in low-melting-temperature solders and fusible alloys. It describes how the two elements typically occur in nature and how they are recovered and processed for commercial use. It also provides information on designations, classification, composition, properties (including temperatures ranges), and some of the other ways in which indium and bismuth alloys are used.

This article describes the control of water chemistry in the steam cycle of a power plant for achieving corrosion control, deposition prevention, and higher cycle efficiency. It discusses the materials requirements of the components exposed to supercritical water in supercritical (SC) and ultrasupercritical (USC) power plants. These components include high-pressure steam piping and headers, superheater and reheater tubing, water wall tubing in the boiler, high-and intermediate-pressure rotors, rotating blades, and bolts in the turbine section. The article reviews the boiler alloys, used in SC and USC boilers, such as ferritic steels, austenitic steels, and nickel-base alloys. It provides information on the materials used in turbine applications such as ferritic rotor steels, turbine blade alloys, and bolting materials. The article explains various factors influencing steamside corrosion in SC power plants. It also deals with the role of overall efficiency in the USC power generation.

This article focuses on the mechanisms of microbiologically influenced corrosion as a basis for discussion on the diagnosis, management, and prevention of biological corrosion failures in piping, tanks, heat exchangers, and cooling towers. It begins with an overview of the scope of microbial activity and the corrosion process. Then, various mechanisms that influence corrosion in microorganisms are discussed. The focus is on the incremental activities needed to assess the role played by microorganisms, if any, in the overall scenario. The article presents a case study that illustrates opportunities to improve operating processes and procedures related to the management of system integrity. Industry experience with corrosion-resistant alloys of steel, copper, and aluminum is reviewed. The article ends with a discussion on monitoring and preventing microbiologically influenced corrosion failures.

The steam turbine is the simplest and most efficient engine for converting large amounts of heat energy into mechanical work. This article discusses the primary corrosion mechanisms such as corrosion fatigue, stress-corrosion cracking (SCC), pitting, corrosion, and erosion-corrosion, in steam turbines. It illustrates the various causes of the corrosiveness of the steam turbine environments through a Mollier diagram. The article describes the four parts of design disciplines that affect turbine corrosion, namely, mechanical design, heat transfer, flow and thermodynamics, and physical shape. It lists the ways to control the steam and surface chemistry, and design and material improvements to minimize turbine corrosion.