The discovery of the high-critical-temperature oxide superconductors has accelerated the interest for superconducting applications due to its higher-temperature operation at liquid nitrogen or above and thus reduces the refrigeration and liquid helium requirement. It also permits usage of the high-critical-temperature oxides in magnets or power applications in high-current-carrying wire or tape with acceptable mechanical capability. This article discusses the powder techniques mainly based on the production of an oxide powder precursor, which is then subjected to various processing, including powder-in-tube processing, vapor deposition processing, and melt processing. It further discusses the microstructural, anisotropy and weak link influences on these processes.

This article discusses three types of powder-feeder systems that are commonly used throughout the thermal spray (TS) industry: gravity-based devices, rotating wheel devices, and fluidized-bed systems. It provides information on the various mechanical methods for producing powders, namely, crushing, milling, attriting, and machining. The article describes two prime methods of agglomeration. One method uses a binder by way of agglutination, while the other relies on a sintering operation. The article discusses the technology and principles of the processes that relate to thermal spraying, and offers an understanding for choosing particular feedstock materials that are classified based on the thermal spray process, material morphology, chemical nature of the material, and applications. Sieving, the most common method of separating powders into their size fractions, is also reviewed. The article also provides information on the topical areas and precautions to be undertaken to protect the operator from safety hazards.

The chemical process being catalyzed should have a high productivity within a specified reactor volume with high reaction rates for the desired reactions and low rates for undesired reaction pathways. This article reviews the general catalyst preparation procedures, namely, impregnation, ion exchange, and precipitation. Catalyst carriers are usually high-surface-area inorganic materials with complex pore structures, into which catalytic materials such as palladium, platinum, cobalt, chromium oxide, and vanadium pentoxide are deposited using these procedures. The article also provides information on catalyst powder processing.

Materials resulting from thermal spray processes are often different from their wrought, forged, and cast counterparts. Assessing the usefulness of thermal spray coatings requires understanding, developing, and using appropriate testing and characterization methods that are generally borrowed from other materials science disciplines. This article focuses on commonly used testing and characterization methods: metallography, image analysis, hardness, tensile adhesion testing, corrosion testing, x-ray diffraction, non-destructive testing, and powder characterization. It provides information on how the materials themselves respond to the various test methods. The article focuses on the test methods themselves, including those test parameters that can be varied and the influence of each on the results obtained.

Carbon-carbon composites (CCCs) are introduced in fields that require their high specific strength and stiffness, in combination with their thermoshock resistance, chemical resistance, and fracture toughness, especially at high temperatures. The use of CCCs has expanded as the price of carbon fibers has dropped and their mechanical properties have increased. This article begins with an overview of the carbon conversion processes, fiber properties and microstructures, and interfacial bonding and environmental interaction of carbon fibers, followed by a detailed discussion on the various techniques available for processing CCCs for specific applications, including preform fabrication (fiber weaving), densification, application of protective coatings, and joining. The article closes with a description of the mechanical and physical properties and applications of CCCs. The main applications of CCCs, in terms of money and mass, are in the military, space, and aircraft industries.

This article focuses on the process methods and matrix chemistries of ceramic-matrix composites. These methods include pressure-assisted densification, chemical vapor infiltration, melt infiltration, polymer infiltration and pyrolysis, and sol-gel processing. The article discusses the use of a ceramic, preceramic, or metal phase as a fluid or vapor phase reactant to form the matrix. Emphasis is placed on microstructural features that influence ultimate composite properties.

Refractory metals are extracted from ore concentrates or scrap, processed into intermediate chemicals, and then reduced to metal, usually in powder form. This article discusses the raw materials needed and the processing steps for producing pure and alloyed refractory metal powders. The effects of processing conditions on the physical and chemical properties of tungsten, molybdenum, tantalum, niobium, and rhenium powders are reviewed.

Cellular or foam structures can be described by means of two broader cases: foams in which the pores are all connected to each other and with the environment (open-pore foams) and foams in which every single pore is completely enclosed by the matrix (closed-pore foams). This article describes the four process groups for the production of open- and closed-pore metal foams. It discusses the principles of the foaminal process with the description of various foaming agents, solidified metal foam, and geometries and derived structures of metal foams. The use of syntactic metal foam in various fields is included. The article reviews the mechanical properties of closed-pore metal foams, details the machining and joining procedures of the metal foams, and presents the applications of the metal foam.

This article describes manufacturing procedures that produce aluminum foams and have since become industrially important and successful. It discusses the foaming of melts by blowing agents and foaming of melts by gas injection. The article focuses on aluminum foams based on the Foaminal technology, because those foams dominate the technical applications of aluminum foams. It also discusses the mechanical properties of metal foams, such as general compression behavior, elastic behavior, strain-rate sensitivity, tensile behavior, ductility, fatigue, and mechanical damping. The article concludes with information on the applications of highly porous metal structures.

This article explains how ceramic powders are made. It begins by briefly describing the raw materials used in structural clay products, whitewares, refractories, and advanced ceramics. It then examines various additives that promote uniformity at different stages of the process. After a description of the comminution process (wet and dry milling methods), it discusses batching and mixing operations and granulation methods. The article also deals with the effect of process variables and the steps involved in chemical synthesis, including preparation from solution and gas-phase reactions, filtration and washing, and powder recovery techniques. It concludes with a discussion on characterization, centering on size distribution analysis, specific surface area, density, porosity chemical composition, phase, and surface composition.

Ceramic-matrix composites (CMCs) have ability to withstand high temperatures and have superior damage tolerance over monolithic ceramics. This article describes important processing techniques for CMCs: cold pressing, sintering, hot pressing, reaction-bonding, directed oxidation, in situ chemical reaction techniques, sol-gel techniques, pyrolysis, polymer infiltration, self-propagating high-temperature synthesis, and electrophoretic deposition. The advantages and disadvantages of each technique are highlighted to provide a comprehensive understanding of the achievements and challenges that remain in this area.

This article describes the various pure forms of carbon matrices and the corresponding methods used to create them or incorporate them into a matrix of a composite. These forms include graphite, diamond, fullerenes, and nanotubes. The article discusses the three types of liquid precursors, namely, thermoplastic, thermosetting, and evaporative or solvent carriers. It provides a description of the advantages and limitations of various methods involved in chemical vapor infiltration. The article concludes with a discussion on matrix contribution to composite properties.

This article presents the principles of chemical vapor deposition (CVD) with illustrations. It discusses the types of CVD processes, namely, thermal CVD, plasma CVD, laser CVD, closed-reactor CVD, chemical vapor infiltration, and metal-organic CVD. The article reviews the CVD reactions of materials related to hard, tribological, and high-temperature coatings and to free-standing structures. It concludes by reviewing the advantages, disadvantages, and applications of CVD.

This article describes the manufacture, post-processing, fabrication, and properties of carbon-carbon composites (CCCs). Manufacturing techniques with respect to the processibility of different geometries of two-directional and multiaxial carbon fibers are listed in a table. The article discusses matrix precursor impregnants, liquid impregnation, and chemical vapor infiltration (CVI) for densification of CCCs. It presents various coating approaches for protecting CCCs, including pack cementation, chemical vapor deposition, and slurry coating. Practical limitations of coatings are also discussed. The article concludes with information on the mechanical properties of CCCs.

Ternary molybdenum chalcogenides stands for a vast class of materials, whose general formula is MxMO6X8, where, M is a cation and X is a chalcogen (sulfur, selenium, or tellurium). Possible applications of some of these are as high field superconductors (that is, >20 T, or 200 kG). This article discusses the fabrication methods of PbMo6S8 (PMS) and SnMo6S8 (SMS), including hot processing and cold processing. It provides a short note on the superconducting properties of PMS wire filaments and their applications in processes requiring high magnetic fields, such as high-energy physics, thermonuclear fusion, and nuclear magnetic resonance.

This article presents a summary of the current and new materials and processing techniques for thermal barrier coatings (TBCs) and environmental barrier coatings (EBCs). Different thermal spraying and postspraying processing techniques are required to produce coatings with optimal performance. For TBCs and EBCs, the elastic modulus, mechanical strength, and toughness values are extremely important in predicting failure behavior under stress and strain conditions, mainly for modeling purposes. Sand and/or volcanic ash particles are molten in the hot zones of turbines and deposited over TBCs and EBCs. They form calcium-magnesium-aluminosilicate (CMAS) glassy deposits.

This article discusses the methods and procedures used to extract, purify, and synthesize tungsten carbide powder, metal, and other refractory carbide/nitride powders used in hard metal production. Selection of powders, additives, equipment, and processes for making ready-to-press hard metal powders is also discussed. The article also provides information on the emerging technologies for tungsten carbide synthesis and binders in hard metal production, such as cobalt, iron, and nickel.

Ceramic-matrix composites (CMCs) are being developed for a number of high-temperature and high-performance applications in industrial, aerospace, and energy conservation sectors. This article focuses on processing, fabrication, testing, and characterization methods of CMCs, namely, discontinuously reinforced composites and continuous-fiber-reinforced composites. Processing methods include cold pressing, sintering, hot pressing, reaction bonding, melt infiltration, directed metal oxidation, sol-gel and polymer pyrolysis, self-propagating high-temperature synthesis and joining. A table summarizes the properties of various ceramic reinforcements and industrial applications of these composites.

Sintering provides the interparticle bonding that generates the attractive forces needed to hold together the otherwise loose ceramic powder mass. It also improves hardness, strength, transparency, toughness, electrical conductivity, thermal expansion, magnetic saturation, corrosion resistance, and other properties. This article discusses the fundamentals of sintering and its effects on pore structures and particle density. It addresses some of the more common sintering methods, including solid-state, liquid-phase, and gas pressure sintering, and presents alternative processes such as reaction sintering and self-propagating, high-temperature synthesis. It also describes several pressure densification methods, including hot isostatic pressing, gas pressure sintering, molten particle deposition, and sol-gel processing. The article concludes with a section on grain growth that discusses the underlying mechanisms and kinetics and the relationship between grain growth and densification.