This article examines the high-temperature oxidation of silica-forming ceramics under constant temperature and cyclic conditions. The effects of water vapor, impurities, and molten salts are discussed. The article describes the oxidation and corrosion of silica-forming composites, oxide ceramics, non-silica forming nitrides, carbides, and borides. The performance of environmental barrier coatings by material type is also discussed. The article also explains the effects of oxidation and corrosion on the mechanical properties of ceramic-matrix composites. It concludes with information on high-temperature applications, wear properties, and the microscopic analyses of advanced ceramics.

This article provides crystallographic and engineering data for single oxide ceramics, zirconia, silicates, mullite, spinels, perovskites, borides, carbides, silicon carbide, boron carbide, tungsten carbide, silicon-nitride ceramics, diamond, and graphite. It includes data on crystal structure, density, mechanical properties, physical properties, electrical properties, thermal properties, and magnetic properties.

This article is a comprehensive collection of engineering property data in tabulated form for ceramics and glasses. Data are provided for physical and mechanical properties of ceramic materials and color of ceramics fired under oxidizing and reducing conditions. The article also lists the materials characterization techniques for ceramics and glasses.

This article focuses on the ceramic coatings for ceramic and glass substrates. It describes the role of oxides in glazes and discusses the optical and appearance properties of various types of glazes, such as leadless glazes, lead-containing glazes, opaque glazes, and satin and matte glazes. The article provides information on the classification of pigments and the applications of ceramic coatings for decorations on ceramic and glass surfaces.

Many applications of ceramics and glasses require them to be joined to each other or to other materials such as metals. This article focuses on ceramic joining technologies, including glass-metal sealing, glass-ceramic/metal joining, ceramic-metal joining, ceramic-ceramic joining, and the more advanced joining of nonoxide ceramics. It also discusses metallizing, brazing, diffusion bonding, and chemical bonding.

Sintering provides the interparticle bonding that generates the attractive forces needed to hold together the otherwise loose ceramic powder mass. It also improves hardness, strength, transparency, toughness, electrical conductivity, thermal expansion, magnetic saturation, corrosion resistance, and other properties. This article discusses the fundamentals of sintering and its effects on pore structures and particle density. It addresses some of the more common sintering methods, including solid-state, liquid-phase, and gas pressure sintering, and presents alternative processes such as reaction sintering and self-propagating, high-temperature synthesis. It also describes several pressure densification methods, including hot isostatic pressing, gas pressure sintering, molten particle deposition, and sol-gel processing. The article concludes with a section on grain growth that discusses the underlying mechanisms and kinetics and the relationship between grain growth and densification.

This article provides an overview of the types, properties, and applications of traditional and advanced ceramics and glasses. Principal product areas for traditional ceramics include whitewares, glazes, porcelain enamels, structural clay products, cements, and refractories. Advanced ceramics include electronic ceramics, optical ceramics, magnetic ceramics, and structural ceramics.

Structural applications for advanced ceramics include mineral processing equipment, machine tools, wear components, heat exchangers, automotive products, aerospace components, and medical products. This article begins with an overview of the wear-resistant applications and the parameters affecting wear of ceramics, namely, hardness, thermal conductivity, fracture toughness, and corrosion resistance. The next part of the article addresses temperature-resistant applications of advanced ceramics. Specific applications of ceramic materials addressed include cutting tools, pump and valve components, rolling elements and bearings, paper and wire manufacturing, biomedical implants, heat exchangers, adiabatic diesel engines, advanced gas turbines, and aerospace applications.

The characterization, testing, and nondestructive evaluation of ceramics and glasses are vital to manufacturing control, property improvement, failure prevention, and quality assurance. This article provides a broad overview of characterization methods and their relationship to property control, both in the production and use of ceramics and glasses. Important aspects covered include the means for characterizing ceramics and glasses, the corresponding rationale behind them, and relationship of chemistry, phases, and microconstituents to engineering properties. The article also describes the effects that the structure of raw ceramic materials and green products and processing parameters have on the ultimate structure and properties of the processed piece. The effects that trace chemistry and processing parameters have on glass properties are discussed. The article describes mechanical tests and failure analysis techniques used for ceramics.

Ceramic materials serve important insulative, capacitive, conductive, resistive, sensor, electrooptic, and magnetic functions in a wide variety of electrical and electronic circuitry. This article focuses on various applications of advanced ceramics in both electric power and electronics industry, namely, dielectric, piezoelectric, ferroelectric, sensing, magnetic and superconducting devices.

The design process for ceramic materials is more complex than that of metals because of low-strain tolerance, low fracture toughness and brittleness. The application of structural ceramics to engineering systems hinges on the functional benefits to be derived and is manifested in the conceptual design for acceptable reliability. This article discusses the design considerations for the use of structural ceramics for engineering applications. It describes the conceptual design and deals with fast fracture reliability, lifetime reliability, joints, attachments, interfaces, and thermal shock in detailed design procedure. The article provides information on the proof testing of ceramics, and presents a short note on public domain software that helps determine the reliability of a loaded ceramic component. The article concludes with several design scenarios for gas turbine components, turbine wheels, ceramic valves, and sliding parts.

Ceramic-forming processes usually start with a powder which is then compacted into a porous shape, achieving maximum particle packing density with a high degree of uniformity. This article compares and contrasts several forming processes, including mechanical consolidation, dry pressing, cold isostatic pressing, slip casting, tape casting, roll compaction, extrusion, and injection molding. It describes the advantages, equipment and tooling, and material requirements of green machining, the machining of ceramics in an unfired state with the intent of producing parts as close to as possible to their final shape. The article also provides useful information on drying methods, shrinkage, and defects as well as the removal of organic processing aids such as dispersants, binders, plasticizers, and lubricants.

Traditional ceramics, one of two general classes, are commonly used in high-volume manufacturing to make building materials, household products, and various industrial goods. Although there is a tendency to equate traditional ceramics with low technology, sophisticated processes and advanced manufacturing techniques are often used where these materials are employed. This article examines several traditional ceramics, including structural clay, whiteware, glazes, enamels, portland cements, and concrete. It also provides a detailed account of fabrication methods, properties, and applications. As an example, common applications for structural clay include facing materials, load-bearing units, pavers, and ceramic tiles.

Ceramic and glass manufacturers take environmental regulations into consideration during all stages of the product cycle, from research and development to purchasing, processing, end use, and disposal. Ceramic and glass products are finding application in the construction industry and as raw materials for other processes. This article describes the recycling of in-process scrap and industrial wastes (fly ash, red mud, metallurgical waste, and other waste products), and applications of these recycled products. It focuses on environmental regulations such as Resource Conservation and Recovery Act and Clean Air Act. The Clean Air Act requires all states to meet minimum emissions standards for nitrogen-oxygen compounds, volatile organic compounds, and carbon monoxide.

This article describes testing and characterization methods of ceramics for chemical analysis, phase analysis, microstructural analysis, macroscopic property characterization, strength and proof testing, thermophysical property testing, and nondestructive evaluation techniques. Chemical analysis is carried out by X-ray fluorescence spectrometry, atomic absorption spectrophotometry, and plasma-emission spectrophotometry. Phase analysis is done by X-ray diffraction, spectroscopic methods, thermal analysis, and quantitative analysis. Techniques used for microstructural analysis include reflected light microscopy using polarized light, scanning electron microscopy, transmission electron microscopy, energy dispersive analysis of X-rays, and wavelength dispersive analysis of X-rays. Macroscopic property characterization involves measurement of porosity, density, and surface area. The article describes testing methods such as room and high-temperature strength test methods, proof testing, fracture toughness measurement, and hardness and wear testing. It also explains methods for determining thermal expansion, thermal conductivity, heat capacity, and emissivity of ceramics and glass and measurement of these properties as a function of temperature.

Ceramics usually require some form of machining prior to use to meet dimensional and surface quality standards. This article focuses on abrasive machining, particularly grinding, and addresses common methods and critical process factors. It covers cylindrical, centerless, and disk grinding and provides information on tooling, wheel selection, work material, and operational factors. It also discusses precision slicing and slotting, lapping, honing, and polishing as well as abrasive waterjet, electrical discharge, laser, and ultrasonic machining.

Ceramics are used widely in a number of different clinical applications in the human body. This article provides a brief history of the bioceramics field and information on the classification of the different types of bioceramics. These include bioinert ceramics, bioactive ceramics, and bioresorbable ceramics. The article describes the third-generation bioceramics, classified by Hench and Polak, such as silicate-substituted hydroxyapatite and bone morphogenic protein-carrying calcium phosphate coatings. It reviews several examination methods that are used to test the biocompatibility of ceramics, namely, biosafety testing, biofunctionality testing, bioactivity testing, and bioresorbability testing.

Nanotechnology and smart-coating technologies have been reported to show great promise for improved performance in critical areas such as corrosion resistance, durability, and conductivity. This article exemplifies nanofilms and nanomaterials used in coatings applications, including carbon nanotubes, silica, metals/metal oxides, ceramics, clays, buckyballs, graphene, polymers, titanium dioxide, and waxes. These can be produced by a variety of methods, including chemical vapor deposition, plasma arcing, electrodeposition, sol-gel synthesis, and ball milling. The application of nanotechnology and the development of smart coatings have been dependent largely on the availability of analytical and imaging techniques such as Raman spectroscopy, scanning and transmission electron microscopy, atomic force microscopy, and scanning tunneling microscopy.

Analysis of bifilms provides a simple, powerful, and elegant concept to explain many features of the metallurgy of castings. This article describes the effects of bifilms in metals. Mechanisms for the entrainment of bifilms are reviewed. The article describes the effect of furling and unfurling on mechanical properties of the solidified cast metal. It provides a discussion on the mechanisms of unfurling to determine the casting properties of the metals. These include gas precipitation, shrinkage, linear contraction, dendrite pushing, and nucleation and growth of intermetallics. The article also describes the role of bifilm defects in fracture.

This article focuses on ceramics, glasses, glass-ceramics, and their derivatives, that is, inorganic-organic hybrids, in the forms of solid or porous bodies, oxide layers/coatings, and particles with sizes ranging from nanometers to micrometers, or even millimetres. These include inert crystalline ceramics, porous ceramics, calcium phosphate ceramics, and bioactive glasses. The article discusses the compositions of ceramics and carbon-base implant materials, and examines their differences in processing and structure. It describes the chemical and microstructural basis for their differences in physical properties, and relates properties and hard-tissue response to particular clinical applications. The article provides information on glass or glass-ceramic particles for cancer treatments.