Temperature control in heat treating is of paramount importance in maintaining the quality and achieving the desired metallurgical results. This article provides a detailed account of the factors affecting temperature control in heat treating furnaces, with information on temperature control systems, including contact sensors, noncontact sensors, controllers, energy-flow regulators, measurement instruments, and set-point programmers. Common contact sensors include temperature scales, thermocouples, and resistance temperature detectors, whereas optical pyrometers and on-line radiation thermometers fall under the noncontact type. The article describes two types of instrumentation used in heat treating: field test instruments for temperature-uniformity surveys and system-accuracy tests; and controlling, monitoring, and recording instruments for digital instrumentation.

This article provides an overview of the basic theory of infrared (IR), including emissivity and E slope. It explains how the IR thermometer works, and provides guidance on choosing a thermometer, in particular, deciding between a two-color and a single-wavelength thermometer and installing and maintaining them. The article discusses typical applications of induction heating, and describes how the IR thermometer controls the temperature. While the majority of the article discusses spot thermometers, thermal imagers, which are fast and are used for both research and control of the induction process, are also addressed.

Thermal inspection comprises all methods in which heat-sensing devices or substances are used to detect irregular temperatures. Inspection of workpieces can be used to detect flaws and undesirable distribution of heat during service. Though there are several methods of thermal inspection and many types of temperature-measuring devices and substances, this article focuses only on thermography, which is the mapping of isotherms, or contours of equal temperature, over a test surface, and on thermometry, which is the measurement of temperature. Thermography techniques can be classified as contact thermographic methods using cholesteric liquid crystals, thermally quenched phosphors, and heat-sensitive paints, and noncontact techniques using hand-held infrared scanners, high-resolution infrared imaging systems, and thermal wave interferometer systems. Contact thermometric inspection devices include bolometers, thermocouples, thermopiles, and meltable substances, whereas radiometers and pyrometers come under the noncontact category.

Control of temperature and furnace atmospheres has become increasingly critical to successful heat treating. Temperature instrumentation and control systems used in heat treating include temperature sensors, controllers, final control elements, measurement instruments, and set-point programmers. This article describes these items and discusses the classifications and control of furnace atmospheres. The article also describes the surface carbon control devices available for the wide variety of furnace atmospheres and evaluation of carbon control. Finally, the article provides a set of guidelines for safety procedures that are common to all industrial heat treating furnace installations.

This article provides an in-depth review of thermocouples and the metals from which they are made. It explains how dissimilar metal conductors in contact at opposite ends can generate an electromotive force if the junctions are heated or cooled to different temperatures. The article discusses thermocouple circuits and instrumentation, calibration methods, insulation requirements, operating ranges, measurement errors, and maintenance procedures. It also provides property data and emf curves for common metals and thermocouple types, and contains information on color coding used around the world.

Film radiography requires the development of the exposed film so that the latent image becomes visible for viewing. It describes the general characteristics of film, including speed, gradient, and graininess, and the factors affecting film selection and exposure time. The article discusses the three major inspection techniques for tubular sections, namely, the double-wall, double-image technique; the double-wall, single-image technique; and the single-wall, single-image technique. It illustrates the arrangements of penetrameters and identification markers for the radiography of plates, cylinders, and flanges. The article discusses various control methods, including the use of lead screens; protection against backscatter and scatter from external objects; and the use of masks, diaphragms, collimators, and filtration. The radiographic appearance of specific types of flaws is also discussed. The article concludes with a discussion on two methods of radiographic film processing: manual and automatic processing.

Hyperthermia is a type of cancer treatment that requires directing a carefully controlled dose of heated nanoparticles to the cancerous tumor that leads to the destruction of cancer cells. Nanoparticles are used as the heat generating sources within the cancer cells and the tumors. The problem in controlling the temperature of nanoparticles is solved by the use of induction heating, which uses a high-frequency alternating magnetic field localized in the area of interest. This article provides an overview of this technique along with the description of its major components, namely, nanoparticles, induction heating setup, and magnetic field strength.

The atmosphere within a furnace chamber is a basic factor in achieving the desired chemical reactions with metals during heat treating. This article presents the fundamentals of heat treating atmospheres, and describes two groups of atmosphere control, namely, furnace atmosphere control and supply atmosphere control. The two basic types of atmospheric supply systems are generated atmospheres and nitrogen-base atmospheres. The article provides a brief overview of the gas reactions associated with oxidation and carbon control to ensure either carburization, or to prevent decarburization. It demonstrates how the carbon potential control is achieved by controlling water vapor concentration, carbon dioxide concentration, or oxygen partial pressure. The article also describes the various devices and analyzers used to monitor sampled gas from furnace atmospheres, namely, chromatographs, oxygen probes, Orsat analyzers, infrared analyzers, dewpoint analyzers, and hot-wire analyzers. Finally, it discusses the advantages, disadvantages, and limitations of these analyzers.

Batch furnaces and continuous furnaces are commonly used in heat treating. This article provides a detailed account of various heat treating equipment and its furnace types, including salt bath equipment (externally heated, immersed-electrode and submerged-electrode furnaces), and fluidized-bed equipment (external-resistance-heated fluidized beds). It describes various auxiliary equipment used in cold-wall furnaces, namely, heating elements and pumping systems. Five types of heat-resistant alloys are used for furnace parts, trays, and fixtures: Fe-Cr alloys, Fe-Cr-Ni alloys, Fe-Ni-Cr alloys, nickel-base alloys and cobalt-base alloys. The article lists the recommended applications for alloys for parts and fixtures for various types of heat treating furnaces.

Plasma (ion) nitriding is a method of surface hardening using glow-discharge technology to introduce nascent (elemental) nitrogen to the surface of a metal part for subsequent diffusion into the material. This article describes the procedures and applications of plasma nitriding methods of steel. These methods include direct-current plasma nitriding, pulsed-current plasma nitriding, and active-screen plasma nitriding. The article reviews cold-walled and hot-walled furnaces used for plasma nitriding. It provides information on the importance of controlling three process parameters: atmosphere, pressure, and part temperature. The article includes a discussion on the influence of nitrogen concentration on case structure formation on nitrided steel, and explains the significance of microstructure, hardness, and fatigue strength on nitrided case. It also discusses processing, laboratory studies, and applications of nitrocarburizing of steel.

This article provides readers with a brief review of the applications of thermography in additive manufacturing (AM), which still is largely a research and development (R&D) effort. There is a particular focus on metals-based laser powder-bed fusion (L-PBF), although applications in directed-energy deposition (DED) and electron beam PBF (E-PBF) also are mentioned. The metrological basis of thermography is discussed in the article. Background information on radiation thermometry is provided, including how the various equations are applied. Finally, specific examples and lessons learned from various AM thermographic studies at the National Institute of Standards and Technology (NIST) are provided.

This article describes weathering and environmental factors that contribute to degradation in plastics, including temperature variations, moisture, sunlight, oxidation, microbiologic attack, and other environmental elements. It presents a general overview of aging factors, their effects on plastic materials, and the accelerated test methods that can be used to estimate the reaction of a plastic component during actual use. The article focuses on the determination of service temperature as it indicates the ability of a material to retain a certain property, when exposed to elevated temperatures for an extended period of time. It concludes by describing various degradation processes, namely, thermal degradation, thermal oxidative degradation, photooxidative degradation, environmental corrosion, and chemical corrosion and discussing the ways of detecting these degradation processes.

Functional fusion-bonded epoxy (FBE) coatings are used as external pipe coatings, base layer for three-layer pipe-coating systems, internal pipe linings, and corrosion coatings for concrete reinforcing steel (rebar). This article provides information on the chemistries of FBE, and discusses the application procedures for internal and external FBE pipe coating. The procedures involve pipe inspection, surface preparation, heating, powder application, curing, cooling, coating inspection, and repairing. It describes the problems and solutions for FBE external pipe coatings, girth weld FBE application, FBE custom coatings, internal FBE pipe linings, and FBE rebar coatings.

Thermomechanical analysis (TMA) is a thermal analysis technique in which the length of a specimen is precisely measured versus temperature and time as the specimen is subjected to controlled heating and cooling. This article discusses the various factors and processes involved in TMA. The discussion covers the general principles, equipment used, specimen preparation process, calibration conditions, data analysis steps, and examples of the applications and interpretation of TMA.

Precious metals are of inestimable value to modern civilization. This article discusses the resources and consumption, trade practices, and special properties of precious metals and its alloys, including ruthenium, rhodium, palladium, silver, osmium, iridium, platinum, and gold, and tabulates the industrial applications of precious metals. It provides information on the commercial forms (wire, rod, sheet, strip, ribbon, and foil) and uses of precious metals, including semifinished products, precious metal powders, industrial uses, coatings, and jewelry.

Structural applications for advanced ceramics include mineral processing equipment, machine tools, wear components, heat exchangers, automotive products, aerospace components, and medical products. This article begins with an overview of the wear-resistant applications and the parameters affecting wear of ceramics, namely, hardness, thermal conductivity, fracture toughness, and corrosion resistance. The next part of the article addresses temperature-resistant applications of advanced ceramics. Specific applications of ceramic materials addressed include cutting tools, pump and valve components, rolling elements and bearings, paper and wire manufacturing, biomedical implants, heat exchangers, adiabatic diesel engines, advanced gas turbines, and aerospace applications.

The success of a reliable non-destructive evaluation (NDE) application depends greatly on the expertise and thoroughness of the NDE engineering that is performed. This article discusses the general considerations of NDE in terms of NDE response and NDE system management and schedule. It describes the NDE engineering and NDE process control, along with some case studies related to the applications of NDE. The article reviews various models for predicting NDE reliability, such as ultrasonic inspection model, eddy current inspection model, and radiographic inspection model. It concludes with an example that illustrates the integration of an ultrasonic reliability model with a CAD system.

This article is a compilation of definitions for terms related to engineering materials, including plastics, elastomers, polymer-matrix composites, adhesives and sealants, ceramics, ceramic-matrix composites, glasses, and carbon-carbon composites.