Corrosion monitoring is important in the operation of modern industrial plants and in the use and maintenance of expensive assets such as bridges and aircrafts, because the damage caused by corrosion and the rate of the deterioration can be huge and the risks devastating. This article discusses the system considerations and installation techniques of different types of direct and indirect techniques in electrochemically based on-line corrosion monitoring process. It describes the importance of probe location and on-line corrosion monitoring techniques with examples.

This article provides a discussion on the operation of various methods and sensors that have been used or have the potential to be used for on-line, real-time monitoring of localized corrosion. These include the electrochemical noise (ECN) method, nonelectrochemical methods, the galvanically coupled differential flow cell, galvanically coupled crevice cell, coupled multielectrode sensor, and electrochemical biofilm activity sensor.

This article focuses on the methods that are being developed for detecting and monitoring corrosion: electrochemical methods, electromagnetic or sound wave methods, fiber-optic technology, fluorescence methods, and the Diffracto Sight method. It reviews the importance of data management and the Corrosion Expert System. It concludes with information on the simulation and modeling for incorporating the mechanisms of corrosion prevention into military hardware systems design and operation.

This article describes the criteria for selecting a corrosion-monitoring method used in industrial plants. It provides a detailed discussion on the design, advantages, and disadvantages of plant corrosion-testing program. The basic types of racks used to support and insulate the coupons are also discussed. The analysis of electrical-resistance probes, sentry holes, side-stream loop, electrochemical noise, hydrogen-probe, and process streams are used to monitor and estimate corrosion rates. The corrosion rates can also be estimated by ultrasonic thickness measurements, polarization-resistance measurements, corrosion potential measurements, and alternating current impedance measurements. Corrosion monitoring strategies, such as locations, data analysis, redundancy, and other issues, are discussed. The article concludes with information on the interpretation and reporting of corrosion testing.

This article discusses the effects of parameters on corrosivity and explains why it is critical to examine the parameter interactions prior to capturing the synergistic effects of the parameters on corrosion. It examines the methods of internal corrosion prediction for multiphase pipelines. The article reviews methodologies to perform internal corrosion direct assessment for pipelines. Real-time monitoring techniques for assessing actual corrosion at critical locations are discussed. The article also presents the case studies for multi-technique electrochemical corrosion monitoring.

A variety of electrochemical techniques are used to detect and monitor material deterioration in service or in the field. This article describes the static or direct current measurements in a number of applications, including buried pipelines and storage tanks. It reviews the electrochemical impedance spectroscopy and electrochemical noise measurements in a laboratory, especially for the inspection of coatings.

Uniform corrosion refers to the attack on an exposed metal surface that results in homogeneous thickness loss that is evaluated by mass loss or measurement of thickness change. This article focuses on the various processes involved in mass loss tests, namely, selection and preparation of suitable test specimens, planning of the experimental technique, posttest sample cleaning, data acquisition, and reporting. It further discusses the test variables addressed during the experimental planning and provides an overview of the other test and evaluation methods of evaluating uniform corrosion.

This article explores the use of the electrochemical and nonelectrochemical techniques for measuring the corrosion behavior of buried metals and the types of probes used. The electrical resistance technique is the main nonelectrochemical technique used for measuring corrosion rate. Electrochemical techniques discussed include linear polarization resistance, electrochemical noise, harmonic distortion analysis, electrochemical impedance spectroscopy, and hydrogen permeation. The principles of operation for the corrosion measuring techniques are described along with examples of their use in soils.

Pitting is a form of localized corrosion that is often a concern in applications involving passivating metals and alloys in aggressive environments. This article describes the test methods for pitting corrosion. These methods include ASTM G 48, ASTM F 746, ASTM G 61, ASTM G 100, and electrochemical noise measurements. The visual examination, metallographic examination, and nondestructive inspection of pits are discussed. The article reviews the procedures for the use of standard charts, metal penetration, statistical analysis, and loss in mechanical properties to quantify the severity of pitting damage.

This article focuses on the subject of proactive or predictive maintenance with particular emphasis on the control and prediction of corrosion damage for life extension and failure prevention. It discusses creep life assessment from the perspective of creep-rupture properties and creepcrack growth. Practical methods based on replication and parametric approaches are also discussed.

The major benefit of the implementation of the corrosion-control technologies at Army installations is the extension of the service life of buildings and other structures. This article reviews the exposure of military facilities and equipment to a wide variety of environmental conditions, including soils, waters, or atmospheres of varying corrosivity. It presents the case studies illustrating typical examples of the types of corrosion problems found on military installations. The article describes the various corrosion-control technologies used in military facilities. These include protective coatings and linings, cathodic protection, advanced materials selection and design, water treatment, equipment inspection and monitoring, and below-grade moisture mitigation.

This article focuses on the aspects associated with inspection related to pressure vessels and pipework. These aspects include inspection policy, inspection planning and procedures, inspection strategy, inspection methodology, preparation for inspection, invasive inspection, internal visual inspection, and non-invasive inspection. Inspection execution, risk-based inspection, competence assurance of inspection personnel, inspection coverage, inspection periodicity, inspection anomaly criteria, assessment of fitness, and reporting requirements, are also discussed. The article addresses the data acquisition, reporting and trending, and review and audit for the inspection. It reviews inspection techniques, including visual inspection, ultrasonic inspection, and radiographic inspection.

This article describes the major issues involved in designing systems with acceptable cold-climate corrosion performance. It discusses the methods used to control corrosion in external and internal environments. The article provides information on the various common causes of corrosion in cold climates. These include improper transportation and storage practices; improper operations and maintenance practices; and construction practices.