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Image
Effect of oxidative degradation of quench oil containing zinc dialkyl dithi...
Available to PurchasePublished: 01 February 2024
Fig. 39 Effect of oxidative degradation of quench oil containing zinc dialkyl dithiophosphate on cooling curve performance
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Book Chapter
Petroleum Oil Quenchants
Available to PurchaseSeries: ASM Handbook
Volume: 4F
Publisher: ASM International
Published: 01 February 2024
DOI: 10.31399/asm.hb.v4F.a0007002
EISBN: 978-1-62708-450-5
... Abstract In this article, an in-depth overview of petroleum quenching oils is provided, including oil composition, use, mechanism of the oil quenching processes, oil degradation, toxicology and safety, and quenching bath maintenance. oil composition oil degradation oil quenchants oil...
Abstract
In this article, an in-depth overview of petroleum quenching oils is provided, including oil composition, use, mechanism of the oil quenching processes, oil degradation, toxicology and safety, and quenching bath maintenance.
Image
Illustration of the use of infrared spectroscopy to quantitatively assess o...
Available to PurchasePublished: 01 August 2013
Fig. 95 Illustration of the use of infrared spectroscopy to quantitatively assess oxidative degradation of a quench oil. (a) New vs. moderately degraded quench oil. (b) New vs. severely degraded quench oil
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Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006381
EISBN: 978-1-62708-192-4
... Abstract This article describes the main advantages of using grease as a lubricant rather than oil. It discusses the formulation, lubricating mechanism, degradation, and characterization of grease. The article describes the parameters that determine lifetime of grease, including low-temperature...
Abstract
This article describes the main advantages of using grease as a lubricant rather than oil. It discusses the formulation, lubricating mechanism, degradation, and characterization of grease. The article describes the parameters that determine lifetime of grease, including low-temperature limit, low-temperature performance limit, high-temperature performance limit, and high-temperature limit. The article concludes with information on the practical use of grease as a lubricant reservoir.
Image
Schematic summary of general free-radical degradation mechanisms of thermal...
Available to PurchasePublished: 01 August 2013
Fig. 78 Schematic summary of general free-radical degradation mechanisms of thermal-oxidative degradation of petroleum oil quenchants. Source: Ref 197
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Image
Schematic summary of general free-radical degradation mechanisms of thermal...
Available to PurchasePublished: 01 February 2024
Fig. 9 Schematic summary of general free-radical degradation mechanisms of thermal-oxidative degradation of petroleum oil quenchants. Source: Ref 21
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Book Chapter
Quenchants Used for Heat Treatment of Ferrous Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 4B
Publisher: ASM International
Published: 30 September 2014
DOI: 10.31399/asm.hb.v04b.a0005932
EISBN: 978-1-62708-166-5
... Abstract This article describes various quenchants, namely, water and inorganic salt solutions, polymers (polyvinyl alcohol, polyalkylene glycol, polyethyl oxazoline, polyvinyl pyrrolidone and sodium polyacrylates), quench oils, and molten salts, which are used for heat treatment of ferrous...
Abstract
This article describes various quenchants, namely, water and inorganic salt solutions, polymers (polyvinyl alcohol, polyalkylene glycol, polyethyl oxazoline, polyvinyl pyrrolidone and sodium polyacrylates), quench oils, and molten salts, which are used for heat treatment of ferrous alloys. It also provides information on the steps for controlling quenching performance for polymer quenchants and oils with an emphasis on measuring quenchant performance, safety measures, and oxidation.
Book Chapter
Engine Lubricants Overview and Development Trends
Available to PurchaseSeries: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006413
EISBN: 978-1-62708-192-4
... metal damage caused by oil degradation and corrosion) Sealant (minimize leakage of combustion gases. To perform all these functions, the base lubricant, or base stock, is typically blended with about 5 to 25% additives, each of which performs one or more functions ( Ref 6 ). Performance...
Abstract
This article addresses the impact of emerging technologies on future lubricant and tribology requirements. The connection between lubricant and tribological requirements is shown by briefly describing basic lubrication and friction processes in major engine components incorporating emerging technologies. The article introduces automotive lubricant development activities and the foundation of future automotive engine-lubricant trends. It discusses how emerging powertrain technology impacts future automotive lubricant and technology requirements, focusing on the effects of engine oils and additives on engine performance to meet powertrain performance requirements. A detailed overview of automotive engine oil performance evaluation methods and specifications, and their impact on the types of advanced lubricants being developed as well as future automotive engine testing requirements, is provided.
Book Chapter
Martempering and Austempering
Available to PurchaseSeries: ASM Handbook
Volume: 4F
Publisher: ASM International
Published: 01 February 2024
DOI: 10.31399/asm.hb.v4F.a0007009
EISBN: 978-1-62708-450-5
... degradation rates of martempering oil relative to conventional oil quenchants, the oil degradation rate will double for every 10 °C (18 °F) increase in temperature in accordance with the Arrhenius’ rate rule ( Ref 9 ). This causes formation of acid and sludge, which may affect the hardness, oil color...
Abstract
Martempering and austempering processes may eliminate the need for conventional oil quenching and tempering. This article presents the suitability of steels for martempering and austempering. It discusses the compositions of oils suitable for marquenching and modified marquenching and also presents safety precautions recommended for the use of martempering oils. Finally, the article explains the effect of agitation and water in a molten salt bath.
Image
Illustration of the use of infrared spectroscopy to quantitatively assess o...
Available to PurchasePublished: 01 February 2024
Fig. 36 Illustration of the use of infrared spectroscopy to quantitatively assess oxidative degradation of a quench oil. Adapted from Ref 65
More
Book Chapter
Polymer Quenchants
Available to PurchaseSeries: ASM Handbook
Volume: 4F
Publisher: ASM International
Published: 01 February 2024
DOI: 10.31399/asm.hb.v4F.a0007003
EISBN: 978-1-62708-450-5
... on cooling curve analysis of polymer quenchants. cooling curve analysis induction hardening intensive quenching polymer quenchants Historical Perspective Vegetable and animal oils have been used as quenchants for metals for thousands of years. Historically, very little is known, other than...
Abstract
This article presents the fundamentals and nomenclature of polymer quenchants and provides a detailed discussion on the polymers used for quenching formulation. The article describes the effect of polymer structure on the quenching mechanism. It also presents the factors affecting polymer quenchant performance. The article details the use of polymer quenchants for intensive quenching and then focuses on the wire patenting processes and polymer quenchant analysis. The article presents the application of polymer quenchants for induction hardening. Finally, it provides details on cooling curve analysis of polymer quenchants.
Book Chapter
Vegetable and Animal Oil Quenchants
Available to PurchaseSeries: ASM Handbook
Volume: 4F
Publisher: ASM International
Published: 01 February 2024
DOI: 10.31399/asm.hb.v4F.a0007004
EISBN: 978-1-62708-450-5
... in the selection of base fluids and for fully formulated industrial oils. In general terms, biodegradability means that a substance is susceptible to biochemical decomposition, promoted by the action of microorganisms. The first stage of decomposition is named primary degradation; that is, it is the stage in which...
Abstract
This article focuses on the quenching properties of vegetable and animal oils, including toxicity and biodegradability of vegetable/animal oils. The article provides a detailed discussion on the oxidation of vegetable/animal oils. The addition of antioxidants to stabilize soybean and palm oils is discussed, and the article concludes that substantially better performance is required if vegetable oils are to be effective functional equivalents to petroleum oil formulations. This may be done by selecting different vegetable oil compositions with less unsaturation, by applying genetic modification of soybean seed oils, or by chemically modifying and stabilizing the vegetable oil structure.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003844
EISBN: 978-1-62708-183-2
... Abstract Paints and protective coatings are the most common means of protecting materials from deterioration. This article focuses on coating degradation that results from the environmental interaction with the coatings. The major environmental influences of the degradation include energy...
Abstract
Paints and protective coatings are the most common means of protecting materials from deterioration. This article focuses on coating degradation that results from the environmental interaction with the coatings. The major environmental influences of the degradation include energy (solar radiation, heat and temperature variation, and nuclear radiation), permeation (moisture, solvent retention, chemical, and oxygen), stress (drying and curing, vibration, and impact and abrasion), and biological influences (microbiological and macrobiological).
Book Chapter
Selection and Use of Lubricants in Forming of Sheet Metal
Available to PurchaseSeries: ASM Handbook
Volume: 14B
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v14b.a0005159
EISBN: 978-1-62708-186-3
..., and aromatic molecules and are classified by the species that predominates. For example, a petroleum oil consisting of 70% naphthenic molecules is called naphthenic. The different classes of oils have different properties. Linear paraffins, for example, have high resistance to oxidative degradation...
Abstract
This article provides an overview of the interfacial interactions with a lubricant film between a die and a metal, lubricant mechanisms, chemistry, qualification testing, application methods, and property test methods. It focuses on sheet metal-forming operations, although the discussions are relevant to metal-forming operations in general. The article also deals with lubricant selection as influenced by the metal to be formed and particular sheet-metal forming operations. The article also discusses some aspects of microbiology and toxicity in lubricants.
Book Chapter
Protective Overlays and Coatings Used in Oil Sands
Available to PurchaseBook: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005712
EISBN: 978-1-62708-171-9
... A. , Materials Selection in the Oil Sands Industry Based on Materials Degradation Mechanisms , Explor. Prod. , Vol 7 ( No. 1 ), 2009 , p 42 – 45 11. Llewellyn R. , Materials for Controlling Wear in Surface Mining , CIM Bull. , Vol 89 , 1996 , p 76 – 82 12. Llewellyn R...
Abstract
This article focuses on coatings and overlays adopted for use as wear- and corrosion-resistant materials in oil sand processing. It describes the most common application processes for oil sand coatings and overlays, including welding, high-velocity oxyfuel thermal spray, laser cladding, and vacuum brazing. The article provides information on the selection of overlays and materials such as chromium-carbide-base overlays and tungsten carbide metal-matrix composites.
Series: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005824
EISBN: 978-1-62708-165-8
..., classification, selection, and maintenance are reviewed in detail. The article addresses the various reasons for quench oil variability and complications due to aging and contamination. brine cooling flow velocity heat-transfer coefficient oil quenchants polyacrylates polyalkylene glycol polymer...
Abstract
This article provides an overview of common quenching media, the factors involved in the mechanism of quenching, and process variables, namely, surface condition, mass and section size of the workpiece, and flow rate of the quenching liquid. It describes the methods of quenchant characterization using hardening-power and cooling-power tests. The article discusses the fundamentals involved in heat-transfer coefficient and heat flux of quenching processes. This discussion is followed by various actual examples of applications of these methods using simplified equations. Quenchant evaluation, classification, selection, and maintenance are reviewed in detail. The article addresses the various reasons for quench oil variability and complications due to aging and contamination.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006073
EISBN: 978-1-62708-172-6
...-internal stress, and vibration-external stress; and (4) biological influences such as microbiological, mildew, and marine fouling. biological influence coating degradation energy paints permeation pigments stress PAINTS AND COATINGS of all types are widely used to provide color...
Abstract
This article discusses the environmental influences on protective coating films that can result in deterioration. These environmental factors can be classified into four groups: (1) energy: solar, heat; (2) permeation: moisture, solvent, chemical, and gas; (3) stress: drying and curing-internal stress, and vibration-external stress; and (4) biological influences such as microbiological, mildew, and marine fouling.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006405
EISBN: 978-1-62708-192-4
... (soot), sludge, and varnish Protection, because it prevents metal damage that is due to oxidation and corrosion Untreated, or nonformulated, lubricants (mineral-based oils and/or synthetic-based oils) do not possess the necessary properties to be effective fluids in the demanding lubrication...
Abstract
This article focuses on lubricants classified as either internal combustion engine or nonengine lubricants, and the lubricant additives. The functional groups of chemically active and inert additives, as well as friction modifiers and other additives, are described in detail. The chemically active additives include dispersants, detergents, antiwear, and extreme-pressure agents, oxidation inhibitors, and rust and corrosion inhibitors. The chemically inert additives include emulsifiers, demulsifiers, pour-point depressants, foam inhibitors, and viscosity improvers. The article also discusses the multifunctional nature of additives and concludes with information on lubricant formulation.
Book Chapter
Corrosion of Metal Artifacts and Works of Art in Museum and Collection Environments
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004140
EISBN: 978-1-62708-184-9
... role or may degrade other materials that in turn produce corrosive agents. Additionally, some metals (notably copper, zinc, nickel, and alloys containing these metals) are particularly sensitive to aerosol particulates, such as ammonium sulfate and SO 2 , in combination with oxidants, such as NO 2...
Abstract
This article presents a general survey of corrosive agents and processes that exist within what are usually considered the protective environments of museums and historic collections. It reviews the corrosion influencing factors, such as humidity, temperature, and light. The article provides a list of pollutants and their sources in museums and collections. It discusses the sources of corrosion, including plastic and wood, sulfur, and carbonyl compounds. The article describes the preservation steps for materials in museum to eliminate the corrosive sources acting on the objects and to avoid other potentially damaging materials.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006411
EISBN: 978-1-62708-192-4
... scientists and engineers understand the principles behind lubricant selection. Components of Lubricating Oils Liquid lubricants are primarily composed of a base oil (90–95%) and additives (5–10%). Base oil primarily consists of hydrocarbons, which provide the physical properties of lubricants, while...
Abstract
The function of lubricants is to control friction and wear in a lubricating system containing machine elements such as gears and bearings. This article discusses the basic properties of lubricants to help scientists and engineers understand the principles behind lubricant selection. It reviews the functions of additives, such as friction modifiers, antiwear additives, viscosity modifiers, corrosion inhibitors, oxidation inhibitors, dispersants, and detergents. The article discusses the physical properties of liquid lubricants and the performance characteristics of lubricants. It describes the most common lubricant categories and provides information on the health and safety aspects of using liquid lubricants. The article concludes with a discussion on the lubricant-application method that plays a vital role in how the lubricant functions.
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