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Series: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005410
EISBN: 978-1-62708-196-2
... Abstract This article describes the results obtained by Volmer, Weber, Farkas, Becker, and Doring, which constitute the classical nucleation theory. These results are the predictions of the precipitate size distribution, steady-state nucleation rate, and incubation time. The article reviews...
Abstract
This article describes the results obtained by Volmer, Weber, Farkas, Becker, and Doring, which constitute the classical nucleation theory. These results are the predictions of the precipitate size distribution, steady-state nucleation rate, and incubation time. The article reviews a nucleating system as a homogeneous phase using the classical nucleation theory, along with heterophase fluctuations that led to the formation of precipitates. It discusses the gas cluster dynamics using the kinetic approach to describe nucleation. The article presents key parameters, such as cluster condensation and evaporation rates, to describe the time evolution of the system. The predictions and extensions of the classical nucleation theory are discussed. The article also provides the limitations of classical nucleation theories in cluster dynamics.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005207
EISBN: 978-1-62708-187-0
... Abstract This article discusses selected highlights of thermodynamic relationships during solidification and nucleation kinetics behavior in connection with the basis of nucleation treatments, such as grain refinement and inoculation, to provide a summary of nucleation phenomena during casting...
Abstract
This article discusses selected highlights of thermodynamic relationships during solidification and nucleation kinetics behavior in connection with the basis of nucleation treatments, such as grain refinement and inoculation, to provide a summary of nucleation phenomena during casting. The article describes nucleation phenomenon such as homogeneous nucleation and heterogeneous nucleation. It examines various grain refinement models, such as the carbide-boride model, the free growth model, and the constitutional undercooling model. The article concludes with information on the thermal analysis techniques for assessing grain-refining characteristics during master alloy processing.
Book: Fatigue and Fracture
Series: ASM Handbook
Volume: 19
Publisher: ASM International
Published: 01 January 1996
DOI: 10.31399/asm.hb.v19.a0002355
EISBN: 978-1-62708-193-1
... Abstract This article presents an overview of fatigue crack nucleation from the point of view of the material microstructure and its evolution during cycling. It describes the sites of microcrack nucleation at the free surfaces. The article discusses the relation of dislocation structures...
Abstract
This article presents an overview of fatigue crack nucleation from the point of view of the material microstructure and its evolution during cycling. It describes the sites of microcrack nucleation at the free surfaces. The article discusses the relation of dislocation structures and surface relief and reviews the mechanisms of crack nucleation. The damage of material due to crack nucleation, the extent (in terms of the number of cycles) of the nucleation stage, and the factors influencing crack nucleation are discussed.
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Comparison between heterogeneous nucleation (A) and homogeneous nucleation ...
Available to PurchasePublished: 01 December 2008
Fig. 9 Comparison between heterogeneous nucleation (A) and homogeneous nucleation (B) in terms of the relative transformation kinetics below the melting point. The reduced temperature T r = T / T f and time t ∝ l −1 . T g , glass transition temperature
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TEM p-c replica of a region centered on the crack-nucleation point visible ...
Available to PurchasePublished: 01 January 1987
Fig. 408 TEM p-c replica of a region centered on the crack-nucleation point visible near the right edge of the fracture surface shown in Fig. 405 . The surface is intergranular and free of corrosion products, which is consistent with fracture caused by hydrogen embrittlement. 8000×
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TEM p-c replica of a region containing the crack-nucleation site near point...
Available to PurchasePublished: 01 January 1987
Fig. 409 TEM p-c replica of a region containing the crack-nucleation site near point 2 in Fig. 404 . The features that are visible in this region are the same as those in the region shown in Fig. 408 , which further indicates that hydrogen embrittlement caused the cracks. 6000×
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TEM p-c replica of a region containing a point of nucleation in a crack ver...
Available to PurchasePublished: 01 January 1987
Fig. 412 TEM p-c replica of a region containing a point of nucleation in a crack very similar to those shown in Fig. 404 and 411 , in a companion actuator shaft. This surface shows all of the intergranular characteristics of fracture by hydrogen embrittlement seen in Fig. 408 and 409
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Comparison of free-energy changes associated with homogeneous nucleation, h...
Available to PurchasePublished: 31 October 2011
Fig. 8 Comparison of free-energy changes associated with homogeneous nucleation, heterogeneous nucleation, and fusion welding
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Effect of particle radius on energy barrier to ferrite nucleation at inclus...
Available to PurchasePublished: 31 October 2011
Fig. 22 Effect of particle radius on energy barrier to ferrite nucleation at inclusions, ast; (heterogeneous), normalized relative to the homogeneous nucleation barrier, Δ G * h (homogeneous). Corresponding energy barrier to nucleation of ferrite at austenite grain boundaries is indicated
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Cooling curves during solidification. T n , nucleation temperature; T g , g...
Available to PurchasePublished: 01 December 2008
Fig. 4 Cooling curves during solidification. T n , nucleation temperature; T g , growth temperature
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Steady-state nucleation rate as a function of undercooling below the meltin...
Available to PurchasePublished: 01 December 2008
Fig. 6 Steady-state nucleation rate as a function of undercooling below the melting point. At low undercooling, the nucleation rate is primarily controlled by driving free energy; at high undercooling, as the temperature approaches the glass transition temperature, T g , nucleation
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Sequence of events during nucleation of the eutectic phases in aluminum-sil...
Available to PurchasePublished: 01 December 2008
Fig. 8 Sequence of events during nucleation of the eutectic phases in aluminum-silicon hypoeutectic alloys. Source: Ref 27
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Optical micrographs showing nucleation of silicon phase (a) on graphite par...
Available to PurchasePublished: 01 December 2008
Fig. 2 Optical micrographs showing nucleation of silicon phase (a) on graphite particle and (b) on nickel-coated graphite particles in hypereutectic aluminum-silicon alloys
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Temperature versus rates of nucleation and growth of pearlite colonies in a...
Available to PurchasePublished: 01 August 2013
Fig. 31 Temperature versus rates of nucleation and growth of pearlite colonies in a steel with eutectoid composition
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Nucleation and coalescence of eutectic grains in cast iron. (a) Early solid...
Available to PurchasePublished: 01 December 2004
Fig. 10 Nucleation and coalescence of eutectic grains in cast iron. (a) Early solidification. (b) Late solidification. (c) After solidification at room temperature. Source: Ref 5
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Regions of spinodal decomposition and classical nucleation and growth of pr...
Available to PurchasePublished: 01 December 2004
Fig. 2 Regions of spinodal decomposition and classical nucleation and growth of precipitates. (a) Phase diagram with a miscibility gap. (b) Variation in free energy with composition for the system shown in (a) at temperature T ′. Source: Ref 2
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(a) Pearlite nucleation. (b) Colony growth. (c) Deep-etched steel sample sh...
Available to PurchasePublished: 01 December 2004
Fig. 6 (a) Pearlite nucleation. (b) Colony growth. (c) Deep-etched steel sample showing pearlite colony growth off of proeutectoid cementite plate. Source: (a) and (b) from Ref 4 , p 331, (c) from Ref 6
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Nucleation mechanism of recrystallized cube grains from deformed cube bands...
Available to PurchasePublished: 01 January 2005
Fig. 14 Nucleation mechanism of recrystallized cube grains from deformed cube bands. Source: Ref 32
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Orientation distributions of nuclei observed at various nucleation sites. (...
Available to Purchase
in Transformation and Recrystallization Textures Associated with Steel Processing
> Metalworking: Bulk Forming
Published: 01 January 2005
Fig. 18 Orientation distributions of nuclei observed at various nucleation sites. (a) Grain interiors; at grain boundaries between (b) normal-direction (ND) fiber grains, (c) ND and rolling-direction (RD) fiber grains, (d) ND fiber and random grains, (e) RD fiber and random grains; and (f
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Schematic showing three types of grain-boundary nucleation and the growth o...
Available to PurchasePublished: 01 December 2004
Fig. 17 Schematic showing three types of grain-boundary nucleation and the growth of the nucleus (N) at the expense of the polygonized subgrains. See text for detailed explanation. Source: Ref 7
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