Most modern instrumental techniques produce an output or signal that is not absolute. To obtain quantitative information, the raw output from an instrument must be converted into a physical quantity. This is done by standardizing or calibrating the raw response from an instrument and subsequently analyzing the uncertainty from both the calibration process and the measurement process. This article briefly summarizes the most common calibration and uncertainty analysis methods, namely external standard methods, abbreviated external standard methods, internal normalization, internal standard, standard addition, and serial dilution methods. In addition, it includes information on the traceability of true value of a measured quantity.

There are many different types of polymeric materials, ranging from glassy to semicrystalline polymers and even blends. Their mechanical properties range from pure elastic with very high strains to fracture (elastomers) to almost pure linear elastic (Hookian behavior) with low strains to fracture (glassy polymers). This article provides an overview of historical development of fracture behavior in polymers. It discusses the processes involved in three fracture test methods for polymers, namely linear elastic fracture mechanics, elastic-plastic fracture mechanics, and post-yield fracture mechanics.

Case depth is the normal distance from the surface of the steel to the start of the core. Measurement of case depth is highly sensitive to the type of case hardening, original steel composition, quenching condition, and even to the testing method. This article describes the various methods of measuring case depth in steels, including chemical methods such as the combustion analysis and spectrographic analysis, microhardness test method, macroscopic and microscopic visual methods, and nondestructive methods. It contains a table that provides approximate equivalent hardness numbers for steel.

This article describes the applications of induction heat treatment of metals, including normalizing, annealing, hardening, and tempering and stress relieving. It discusses the simulation techniques of the electromagnetic and thermal processes that occur during induction heat treating. The article explains the finite-difference method, finite-element method, mutual impedance method, and boundary-element method for the numerical computation of the induction heat treating processes. It also discusses the direct and indirect coupling approaches for coupling the electromagnetic and heat-transfer problems. Modern computer simulation techniques are capable of effectively simulating electromagnetic and thermal phenomena for many processes that involve electromagnetic induction. The article considers the challenges faced by developers of modern simulation software.

Statistical analysis of mechanical property data is the most reliable method for determination of minimum design allowables. This article describes the general procedures used to determine design allowables. It provides information on the determination of a distribution form. The article presents statistical methods which help in determining design allowables. These methods include direct computation for normal distribution, direct computation for an unknown distribution, computation of derived properties, and regression analysis. The article concludes with information on low- and elevated-temperature design properties.

Gray irons are a group of cast irons that form flake graphite during solidification, in contrast to the spheroidal graphite morphology of ductile irons. The heat treatment of gray irons can considerably alter the matrix microstructure with little or no effect on the size and shape of the graphite achieved during casting. This article provides a detailed account of classes of gray iron, and heat treating methods of gray irons with examples. These methods include stress relieving, annealing, normalizing, transformation hardening, austenitizing, quenching, austempering, martempering, flame hardening, induction hardening, and nitriding.

This article reviews the main theoretical and practical aspects of sequence normally followed in digital image-acquisition, processing, analysis, and output for material characterization. It discusses the main methods of digital imaging, image processing, and analysis, as applied to microscopy of materials. The article describes the basic concepts of sampling and resolution and quantization of light microscopy, scanning electron microscopy, and transmission electron microscopy. It discusses the acquisition of a digital image that accurately represents the sample under observation and output of the image to a printer. The methods used to enhance the digital image and to extract quantitative information are also described. Different types of image segmentation, namely, adaptive segmentation and contour-based segmentation, are reviewed. The article also presents case studies on the application of image processing and analysis to materials characterization.

This article begins with an overview of steel wire configurations and sizes followed by a discussion on various wiremaking practices. The wiredrawing operation is discussed, including cleaning, die design, use of lubricants and welds, finishes, coating, and thermal treatments. Metallic coatings can be applied to wire by various methods, including hot dip processes, electrolytic process, and metal cladding by rolling metallic strip over the wire. These wires are normally grouped into broad usage categories. These categories, as well as some items in each category, are described in the article under their quality descriptions or commodity names. These include low-carbon steel wire for general usage, wire for structural applications, wire for packaging and container applications, wire for prestressed concrete, wire for electrical or conductor applications, rope wire, mechanical spring wire for general use, wire for fasteners, mechanical spring wire for special applications, upholstery spring construction wire, and alloy wire.

This article describes the most significant tests to characterize the properties of constituent materials. It discusses the chemical, physical, and mechanical tests for determining the properties of reinforcement fibers and fabrics. The article provides information on some of the basic materials used for thermoset and thermoplastic resin matrices. It reviews the identification of the individual characteristics of thermoset and thermoplastic resin along with the test methods normally used for their determination. The article contains a table that lists properties and tests for uncured and cured thermoset-matrix resins and prepregs.

Sand casting processes are typically classified according to the type of binder present in the molding sand mixture. This article discusses common sand casting processes and design considerations related to shape, gating, feeding, and pattern making methods. It describes the composition of sand and binder normally used, and provides information on the aluminum casting alloys produced. The article discusses precision sand casting and sand reclamation, and includes information on health and safety considerations.

Metals and ceramics exposed to high-temperature salt solutions are susceptible to a form of corrosion caused by fused salts accumulating on unprotected surfaces. This article examines the electrochemistry of such hot corrosion processes, focusing on sodium sulfate systems generated by the combustion of fossil fuels. It explains how salt chemistry, including acid/base and oxidizing properties, affects corrosion rates and mechanisms. The article also provides information on electrochemical testing and explains how Pourbaix methods, normally associated with aqueous corrosion, can be used to study fused-salt corrosion.

Fretting is a special wear process that occurs at the contact area between two materials under load and subject to slight relative movement by vibration or some other force. This article focuses on measures to avoid or minimize crack initiation and fretting fatigue. It lists the factors that are known to influence the severity of fretting and discusses the variables that contribute to shear stresses. These variables include normal load, relative displacement (slip amplitude), and coefficient of friction. The article describes the general geometries and loading conditions for fretting fatigue. It presents the types of fretting fatigue tests and the effect of variables on fretting fatigue from different research test programs. The article also lists the general principles and practical methods for the abatement or elimination of fretting fatigue.

Tribology is the study of friction, lubrication, and wear. It is a multidisciplinary subject covering the mechanics of contacting surfaces, their roughness characteristics, lubrication, and material behavior under normal load as well as in traction. This article focuses on well-established and widely accepted analytical methods and design and analysis charts for dealing with some of the issues in the area of engine and power train tribology. It provides a discussion on lubricant rheology and the prediction of lubricating film thickness. The article reviews the frictional power loss in piston-cylinder conjunctions, engine bearings, and transmission and differential gearing systems.

This article discusses the need for design allowables, development of design allowables, and important factors that affect the selection of the allowable. It provides a comparison between lamina and laminate allowables. The article discusses laminate results and specific techniques used in the statistical development of allowable values.

Induction hardening involves multiple processing steps of heating and quenching which presents opportunity for errors and defects. This article discusses the common problems associated with induction hardening of shafts as well as the methods to diagnose, inspect, and prevent them. In addition to the major defects such as laps and seams that remain after induction hardening, microstructural transformation, decarburization, residual stress, and grain size, as well as variations in carbon content, composition, or microstructure can also affect the hardened part.

Composites are complex engineered materials that often behave differently than common isotropic materials. Before testing a composite material, or before ordering or supervising such testing, the responsible party should review certain considerations. This article provides an overview of such considerations, namely, the differences between the testing of composites and testing of isotropic materials, role of certification agencies and importance of their involvement, building-block approach to composites testing, determining the purpose of testing, normalizing results, and statistical data reduction.

This article discusses the J-integral-based single and multiple specimen techniques of the ASTM E 1737 test method for determining plane strain fracture toughness of polymeric materials. It describes the fracture toughness testing of thin sheets and films. The article concludes with information on the alternative methods for determining the fracture toughness of polymer materials.