This article reviews the graphite morphology, chemical composition requirements, castability, mechanical properties, and corrosion resistance of compacted graphite (CG) irons. It describes the factors affecting the mechanical properties of CG irons. The article also presents the advantages of the CG irons.

This article discusses the graphite morphology, chemical composition, mechanical and physical properties, and applications of compacted graphite (CG) irons. It compares the selected properties of gray, ductile and CG irons, and lists their property requirements as per ASTM A 842. A listing of tensile properties of various CG irons produced by different melt treatment methods is also provided.

Malleable iron is a cast ferrous metal that is initially produced as white cast iron and is then heat treated to convert the carbon-containing phase from iron carbide to a nodular form of graphite called temper carbon. This article provides a discussion on the melting practices, heat treatment, microstructure, production technologies, mechanical properties, and applications of ferritic, pearlitic, and martensitic malleable iron.

Cast iron exhibits a considerable amount of eutectic in the solid state. This article discusses the structure of liquid iron-carbon alloys to understand the mechanism of the solidification of cast iron. It illustrates nucleation of the austenite-flake graphite eutectic, austenite-spheroidal graphite eutectic, and austenite-iron carbide eutectic. The article provides a discussion on primary austenite and primary graphite. Depending on the carbon equivalent, the primary phase in cast iron can be either austenite for hypoeutectic cast iron or graphite for hypereutectic cast iron. The article also describes the growth of eutectic in cast iron in terms of isothermal solidification, directional solidification, and multidirectional solidification.

This article discusses the melting and poring practices, heat treatment, and applications of different types of high-alloy graphitic iron, namely, high-silicon gray irons, high-silicon ductile irons, nickel-alloyed austenitic irons, austenitic gray irons, austenitic ductile irons, and aluminum-alloyed irons.

Cast iron, which usually refers to an in situ composite of stable eutectic graphite in a steel matrix, includes the major classifications of gray iron, ductile iron, compacted graphite iron, malleable iron, and white iron. This article discusses melting, pouring, desulfurization, inoculation, alloying, and melt treatment of these major ferrous alloys as well as carbon and alloy steels. It explains the principles of solidification by describing the iron-carbon phase diagram, and provides a pictorial presentation of the basic microstructures and processing steps for cast irons.

The term cast iron designates a group of materials that contain more than one constituent in their microstructure due to excess carbon that result in unique characteristics such as the fracture appearance and graphite morphology. This article discusses the classification of cast iron and the various metallurgical aspects, such as composition, alloying element, solidification, and graphite morphologies, of different types of cast iron. It describes the physical properties for various cast irons and the influence of microstructure and chemical composition on each property. The article provides a detailed account on thermal properties, conductive properties, magnetic properties, and acoustic properties of cast iron. It also discusses heat treatment, namely, stress relieving, annealing, normalizing, through hardening, and surface hardening. The article presents a discussion on the welding, machining and grinding, and coating of the types of cast iron.

Malleable iron is a type of cast iron that has most of its carbon in the form of irregularly shaped graphite nodules. This article tabulates the typical composition of malleable iron and specifications, and applications of malleable iron castings. It discusses the metallurgical control of malleable irons with emphasis on its composition and heat treatment. The article provides information on the specifications and mechanical properties of different types of malleable irons, such as ferritic, pearlitic, and martensitic malleable irons.

This article reviews the production stages of iron foundry casting, with particular emphasis on the melting practices, molten metal treatment, and feeding of molten metal into sand molds. It discusses the molten metal treatments for high-silicon gray, high-nickel ductile, and malleable irons. Foundry practices are also described for compacted graphite, high-silicon ductile, and high-alloy white irons.

This article provides information on the general characteristics, composition, uses, applications and specifications for standard grades of ductile iron. It describes the manufacturing and metallurgical process control procedures, including testing and inspection, and heat treatment. The article also talks about the effects of composition, graphite shape, and section size on the mechanical properties of ductile iron. Tables and graphs provide helpful information on the tensile properties, compressive properties, torsional properties, damping capacity, impact properties, fracture toughness, fatigue strength, and elevated-temperature properties of ductile iron.

Cast irons primarily are iron alloys that contain more than 2% carbon and from 1 to 3% silicon. This article provides a description of iron-iron carbide-silicon system; and discusses the classification, composition, and characteristics of cast irons, such as gray, ductile, malleable, compacted graphite, and white cast iron. A table shows the correspondence between commercial and microstructural classification, as well as final processing stage in obtaining common cast irons.

This article discusses the five basic matrix structures in cast irons: ferrite, pearlite, bainite, martensite, and austenite. The alloying elements, used to enhance the corrosion resistance of cast irons, including silicon, nickel, chromium, copper, molybdenum, vanadium, and titanium, are reviewed. The article provides information on classes of the cast irons based on corrosion resistance. It describes the various forms of corrosion in cast irons, including graphitic corrosion, fretting corrosion, pitting and crevice corrosion, intergranular attack, erosion-corrosion, microbiologically induced corrosion, and stress-corrosion cracking. The cast irons suitable for the common corrosive environments are also discussed. The article reviews the coatings used on cast irons to enhance corrosion resistance, such as metallic, organic, conversion, and enamel coatings. It explains the basic parameters to be considered before selecting the cast irons for corrosion services.

Cast irons may be compared with steels in their reactions to hardening. However, because cast irons (except white iron) contain graphite and substantially higher percentages of silicon, they require higher austenitizing temperatures. This article describes the effect of heat treatment processes such as annealing, normalizing, surface hardening, tempering, stress relieving, quenching, and austempering, on hardness and tensile properties of cast irons, namely gray irons, ductile irons, malleable irons, and austenitic irons.

The properties of irons and steels are linked to the chemical composition, processing path, and resulting microstructure of the material. For a particular iron and steel composition, most properties depend on microstructure. Processing is a means to develop and control microstructure, for example, hot rolling, quenching, and so forth. This article describes the role of these factors in both theoretical and practical terms, with particular focus on the role of microstructure. It lists the mechanical properties of selected steels in various heat-treated or cold-worked conditions. In steels and cast irons, the microstructural constituents have the names ferrite, pearlite, bainite, martensite, cementite, and austenite. The article presents four examples that have very different microstructures: the structural steel has a ferrite plus pearlite microstructure; the rail steel has a fully pearlitic microstructure; the machine housing has a ferrite plus pearlite matrix with graphite flakes; and the jaw crusher microstructure contains martensite and cementite.

Alloy cast irons are casting alloys based on the Fe-C-Si system that contain one or more alloying elements added to enhance one or more useful properties. This article discusses the composition of different types of alloy cast iron, including white cast irons, corrosion-resistant cast irons, heat-resistant cast irons, and abrasion-resistant cast irons. It provides information on the effect of the alloying element on their high-temperature properties. The article also discusses the microstructure and mechanical properties of alloy cast irons.

An understanding of the influence of microstructure on machinability can provide an insight into more efficient machining and the correct solution to problems. Providing numerous microstructures to depict examples, this article describes the relationship between the microstructure and machinability of cast irons, steels, and aluminum alloys. It presents data on hardness values and the effect of the matrix microstructure of cast iron on tool life. It also explains how a higher inclusion count improves the machinability of steels and why aluminum alloys can be machined at very high speeds.

In high-iron-tonnage operations, the cupola remains the most efficient source of continuous high volumes of iron needed to satisfy high production foundries or the multiple casting machines of centrifugal pipe producers. This article explores successful improvement technologies in cupola equipment, including preheated air blast, recuperative hot blast systems, and duplex electric holders. It discusses the shell, intermittent or continuous tapping, tuyere and blower systems, refractory lining, water-cooled cupolas, emission-control systems, and storage and handling of the charge materials. The article provides a discussion on control tests for cupola, including the chill test and mechanical test. It concludes with information on specialized cupolas such as cokeless cupola and plasma-fired cupola.

This article is an atlas of fractographs that covers pearlitic and ferritic ductile irons. The fractographs display the following: brittle cleavage fracture; fatigue crack propagation; fatigue and monotonic fracture surfaces; fracture modes in slow monotonic loading and impact loading; and microcrack initiation and propagation.

This article provides an overview of exogenous and indigenous inclusions. It discusses the general concepts of phase diagrams, thermochemical relationships, and reaction rates, along with their practical significance. The article describes the most common techniques for controlling the occurrence of inclusions in any cast metal. The article provides a discussion on the inclusions in ferrous and nonferrous alloys. The ferrous and nonferrous alloys include steels, cast irons, aluminum alloys, copper alloys, and magnesium alloys.

This article begins with a description of the classes and grades of ductile iron. It discusses the factors affecting the mechanical properties of ductile iron. The article reviews the hardness properties, tensile properties, shear and torsional properties, compressive properties, fatigue properties, fracture toughness, and physical properties of ductile iron and compares them with other cast irons to aid the designer in materials selection. It concludes with information on austempered ductile iron.