Vacuum induction melting (VIM) is often done as a primary melting operation followed by secondary melting (remelting) operations. This article presents the process description of VIM and illustrates potential processing routes for products, which are cast from VIM ingots or electrodes. It describes the VIM refinement process, which includes the removal of trace elements, nitrogen and hydrogen degassing, and deoxidation. The article concludes with information on the production of nonferrous materials by VIM.

Gas porosity is a major factor in the quality and reliability of castings. The major cause of gas porosity in castings is the evolution of dissolved gases from melting and dross or slag containing gas porosity. Degassing is the process of removing these gases. This article describes the methods of degassing aluminum, magnesium, and copper alloys. It provides information on the sources of hydrogen in aluminum and gases in copper.

This article discusses the most common methods of melting steels, namely, electric arc and induction melting. It describes the classification of refractories by an index of the “basicity” of the slag formed on the steel surface. The article provides a discussion on the converter metallurgy, which includes melt refinement in argon oxygen decarburization (AOD) vessels and vacuum oxygen decarburization (VODC) in a converter vessel. It also discusses ladle metallurgy, which includes vacuum induction degassing, vacuum oxygen decarburization, and vacuum ladle degassing.

Inert gas fusion is a method of determining the quantitative content of gases in ferrous and nonferrous materials where gases, such as hydrogen, nitrogen, and oxygen, are physically and chemically adsorbed by the materials and later removed and swept by from the fusion area by an inert carrier gas. This article describes the operating principles and sample selection of inert gas fusion. It explains the mechanisms involved in the introduction of fusion gas, separation and detection of fusion gas by thermal-conductive and infrared detection methods. Additionally, the article explains the methods used for analyzing trace amounts of nitrogen, oxygen, and hydrogen in the carrier mediums, providing examples that aid in solving several problems.

This article reviews the solubilities of the common gases present in ferrous metals, such as cast irons, and nonferrous metals, such as aluminum, copper, magnesium, and their alloys. The kinetics of the relevant reactions, reactions during solidification, and possible methods of control or removal of the dissolved gases are discussed. The most common method for removing hydrogen from aluminum, copper, and magnesium is inert gas flushing. The article provides information on techniques to overcome gas porosity in ferrous and nonferrous metals.

There are a wide variety of furnace types and designs for melting aluminum. This article discusses the various types of furnaces, including gas reverberatory furnaces, crucible furnaces, and induction melting furnaces. It describes the classification of solid fluxes: cover fluxes, drossing fluxes, cleaning fluxes, and furnace wall cleaner fluxes. The article reviews the basic considerations in proper flux selection and fluxing practices. It explains the basic principles of degassing and discusses the degassing of wrought aluminum alloys. The article describes filtration in wrought aluminum production and in shape casting. It also reviews grain refinement in aluminum-silicon casting alloys, aluminum-silicon-copper casting alloys, aluminum-copper casting alloys, aluminum-zinc-magnesium casting alloys, and aluminum-magnesium casting alloys. The article concludes with a discussion on aluminum-silicon modification.

This article presents a detailed account on the process flow, composition, alternative sources, and the advancement of ironmaking, steelmaking and secondary steelmaking practices. Some steels, such as bearing steels, heat-resistant steels, ultrahigh strength missile and aircraft steels, and rotor steels have higher quality requirements and tighter composition control than plain carbon or ordinary low-alloy steels. The production of special-quality steels requires vacuum-based induction or electric remelting and refining capabilities. The article explores the types and characteristics of various steel manufacturing processes, such as ingot casting, continuous casting, and hot rolling. It provides an outline of specialized processing routes of producing ultralow plain carbon steels, interstitial-free steels, high strength low-alloy steels, ultrahigh strength steels, stainless steels, and cold-rolled products, and briefly explains the analytical techniques for liquid steels.

The electronic microcircuit industry has placed severe demands on metal suppliers to provide metals of the highest reproducible purity attainable as a result of the constant quest for the true values of physical and chemical properties of metals. This article describes the commonly used methods for ultrapurification of metals produced by electrolytic processes, including fractional crystallization, zone refining, vacuum melting, distillation, chemical vapor deposition, and solid state refining techniques. In addition, it describes the trace element analysis and resistance-ratio test methods used to characterize purity. Tables list the values for resistance ratios of zone-refined metals and their corresponding chemical compositions, and provide an example of the detection of impurities to concentrations in the parts per billion range, utilizing a combination of the glow discharge mass spectroscopy method and Leco combustion methods.

Several qualitative, semiquantitative, and quantitative tests are available to estimate and control metal cleanliness, particularly inclusion concentration of aluminum alloys. This article provides a description of a few of the metal cleanliness assessment techniques, such as chemical analysis, pressure filter tests, electric resistivity tests, reduced-pressure test, and ultrasonic technique. Detection methods based on the certain principles and the types of impurities in chemical analysis are discussed.

Aluminum fluxing is a step in obtaining clean molten metal by preventing excessive oxide formation, removing nonmetallic inclusions from the melt, and preventing and/or removing oxide buildup on furnace walls. This article discusses the solid fluxes and gas fluxes used in foundries. It reviews the classification of solid fluxes depending on their use and function at the foundry operation. These include cover fluxes, drossing fluxes, cleaning fluxes, and furnace wall cleaner fluxes. The article also examines the operational practices and applications of the flux injection in the foundries. It describes the applications of the aluminum fluxing such as crucible furnaces, transfer ladles, reverberatory furnaces, and holding/casting furnaces.

This article describes the casting characteristics and practices of copper and copper alloys. It discusses the melting and melt control of copper alloys, including various melt treatments to improve melt quality. These treatments include fluxing and metal refining, degassing, deoxidation, grain refining, and filtration. The article provides a discussion on these melt treatments for group I to III alloys. It describes the three categories of furnaces for melting copper casting alloys: crucible furnaces, open-flame furnaces, and induction furnaces. The article explains the important factors that influence the selection of a casting method. It discusses the production of copper alloy castings. The article concludes with information on the gating and feeding systems used in production of copper alloy castings.

The melting process often includes refining and treating the metal. The choice of which type of melting to use depends on a number of factors: type of alloy being melted, the local cost of electric power, and local environmental regulations. This article discusses the principles, furnace types, charging practices of metal melting methods, namely induction melting, cupola melting, arc melting, crucible melting, reaction melting, and vacuum melting, and the refractories and charging practice of reverberatory furnaces. Molten metal treatment of steels and aluminum also is discussed in the article.

This article discusses the principle, coil design, types and operation of a vacuum induction furnace. It describes the operation parameters that should be considered during the functioning of the induction furnace.

This article discusses the applications of high-strength aluminum powder metallurgy (P/M) alloys, detailing the advantages, properties, and the various steps involved in P/M technology, including powder production, powder processing, and degassing and consolidation. Three areas of design efforts to push the inherent advantages of aluminum alloys to new limits are also covered: high ambient-temperature strength with improved corrosion and stress corrosion cracking resistance; improved elevated-temperature properties so aluminum alloys can more effectively compete with titanium alloys; and increased stiffness and/or reduced density for aluminum alloys to compete with organic composites. An appendix provides a detailed account of the properties, processing, and applications of conventionally pressed and sintered aluminum P/M alloys.

This article discusses two major sintering methods: pressureless and pressure-assisted sintering. Pressureless sintering techniques include vacuum and partial-pressure, hydrogen, and microwave sintering. Pressure-assisted consolidation techniques include overpressure sintering, sintering followed by postsinter hot isostatic pressing, hot pressing, and several rapid hot consolidation techniques. The article describes nitrogen sintering and the sintering of cermets. It reviews the furnaces used for sintering and presents the lubrication removal techniques. The article also outlines the need to control carbon and oxygen to obtain optimal properties and explains microstructure development and grain size control.

Refractory metals are extracted from ore concentrates or scrap, processed into intermediate chemicals, and then reduced to metal, usually in powder form. This article discusses the raw materials needed and the processing steps for producing pure and alloyed refractory metal powders. The effects of processing conditions on the physical and chemical properties of tungsten, molybdenum, tantalum, niobium, and rhenium powders are reviewed.

Vacuum heat treating consists of thermally treating metals and alloys in cylindrical steel chambers that have been pumped down to less than normal atmospheric pressure. This article provides a detailed account of the operations and designs of vacuum furnaces, discussing their pressure levels, resistance heating elements, quenching systems, work load support, pumping systems, and temperature control systems. It describes the classification of instruments used for measuring and recording pressure inside a vacuum processing chamber. Common devices include hydrostatic measuring devices and devices for measuring thermal and electrical conductivity. The article also describes the applications of the vacuum heat treating process, namely, vacuum nitriding and vacuum carburizing. Finally, it reviews the heat treating process of tool steels, stainless steels, Inconel 718, and titanium and its alloys.

Plasma melting is a material-processing technique in which the heat of thermal plasma is used to melt a material. This article discusses two typical design principles of plasma torches in the transferred mode: the tungsten tip design and the hollow copper electrode design. It describes the sources of atmospheric contamination in plasma melting furnaces and their control measures. The equipment used in plasma melting furnaces are also discussed. The article provides a detailed discussion on various plasma melting processes, such as plasma consolidation, plasma arc remelting, plasma cold hearth melting, and plasma casting.

This article provides a detailed discussion on the causes of formation of shrinkage porosity and gas porosity along with the methods involved in eliminating them. It discusses the process of porosity formation and the factors affecting porosity formation, including alloy composition, external pressure, and cooling conditions.