Plasma (ion) nitriding is a method of surface hardening using glow-discharge technology to introduce nascent (elemental) nitrogen to the surface of a metal part for subsequent diffusion into the material. This article describes the procedures and applications of plasma nitriding methods of steel. These methods include direct-current plasma nitriding, pulsed-current plasma nitriding, and active-screen plasma nitriding. The article reviews cold-walled and hot-walled furnaces used for plasma nitriding. It provides information on the importance of controlling three process parameters: atmosphere, pressure, and part temperature. The article includes a discussion on the influence of nitrogen concentration on case structure formation on nitrided steel, and explains the significance of microstructure, hardness, and fatigue strength on nitrided case. It also discusses processing, laboratory studies, and applications of nitrocarburizing of steel.

The nitriding process typically involves the introduction of nitrogen into the surface-adjacent zone of a component, usually at a temperature between 500 and 580 deg C. This article provides an overview of the essential aspects of the thermodynamics and kinetics of nitriding and nitrocarburizing of iron-base materials with gaseous processes. It describes nitriding potentials and the Lehrer diagram, carburizing potentials, controlled nitriding and nitrocarburizing, and the microstructural evolution of the compound layer and the diffusion zone.

This article summarizes the terminology for gas reactions, and discusses low-temperature nitriding and nitrocarburizing of stainless steels. It describes the various nitriding processes, namely, high- and low-pressure nitriding, oxynitriding, sulfonitriding, oxysulfonitriding, ferritic nitrocarburizing and austenitic nitrocarburizing. The article includes a discussion on the difficulties in specimen cleaning, importance of furnace purge, uses of pre and post oxidation, depassivation, or activation, and requirements for perfect nucleation in nitriding process. In nitriding, the successful atmosphere control depends on various potentials. The article summarizes the methods of measuring potentials in nitriding and nitrocarburizing, provides useful information on the furnaces used, and the safety precautions to be followed in the nitriding process. It also describes the sample preparation procedures and testing methods to ensure the quality of the sample.

The surface of irons and steels can be hardened by introducing nitrogen (nitriding), nitrogen and carbon (nitrocarburizing), or nitrogen and sulfur (sulfonitriding) into the surface. This article lists the principal reasons for nitriding and nitrocarburizing, and summarizes the typical characteristics of nitriding processes along with a general comparison of carburizing processes in a table. It describes the two most common nitriding methods: gas nitriding and ion (plasma) nitriding. The article discusses the wear behavior of nitrided layers and the wear resistance of selected steels. Rolling-contact fatigue (RCF) occurs in rolling contacts such as bearings, rolls, and gears. The article provides a discussion on rolling-contact fatigue of nitrided steels for aerospace bearing components.

This article provides a detailed discussion on the heating equipment used for austenitizing, quenching, and tempering tool steels. These include salt bath furnaces, controlled atmosphere furnaces, fluidized-bed furnaces, and vacuum furnaces. The article discusses the types of nitriding and nitrocarburizing processes and the equipment required for heat treating tool steels to improve hardness, wear resistance, and thermal fatigue. The various nitriding and nitrocarburizing processes covered are salt bath nitrocarburizing, gas nitriding and nitrocarburizing, and plasma nitriding and nitrocarburizing.

Nitriding is a general term for all processes based on the addition of nitrogen to the surface of steel. When carbon is added along with the nitrogen, the process is called nitrocarburizing. This article provides a detailed discussion on the functional and structural properties of nitrided layers. It describes the structural changes on the surface of carbon steels, alloy steels, and austenitic stainless steels. The article explains the effects of the various nitriding processes, namely, gaseous nitriding, plasma nitriding, gaseous nitrocarburizing, and salt bath nitrocarburizing, on the structure and properties of nitrided layers.