This article describes the nitriding methods of titanium alloys such as plasma nitriding and gas nitriding. It focuses on the interaction of titanium alloys, interaction of titanium with nitrogen, and the interaction of titanium with oxygen, carbon, and hydrogen. The article provides information on the wear and fatigue properties and corrosion resistance of nitrided titanium alloys, as well as the effect of nitriding on the biocompatibility of titanium. It also compares plasma-nitrided titanium alloys with alloy steels. It concludes with a short discussion on the effect of nitriding on the surface properties of titanium and two-phase a + ß alloys.

Aluminum and its alloys are characterized by their low hardness and less satisfactory tribological performance. These limits can be overcome by means of load-specific surface engineering. This article provides information on the structure and properties of nitrided layers, and the technologies and mechanisms used for nitriding aluminum and its alloys. It also describes the nitriding behavior of aluminum alloys. The article concludes by describing how a combination of technologies can be utilized to achieve aluminum nitride with the highest tribological properties.

This article discusses the important characteristics of fluidized beds. The total space occupied by a fluidized bed can be divided into three zones: grid zone, main zone, and above-bed zone. The article discusses the various types of atmospheres of fluidized beds, such as oxidizing and decarburizing atmosphere; nitrocarburizing and nitriding atmosphere; carburizing and carbonitriding atmosphere; and chemical vapor deposition atmosphere. External resistance heating, external combustion heating, internal resistance heating, direct resistance heating, submerged combustion heating, and internal combustion heating can be used to achieve the heat input for a fluidized bed. The article also describes the operations, design considerations, and applications of fluidized-bed furnaces in heat treating. Thermochemical surface treatments, such as carburizing, carbonitriding, nitriding, and nitrocarburizing, are also discussed. Finally, the article reviews the principles and applications of fluidized-bed heat treatment.

The process of case hardening of steel includes three consecutive steps of heat treatment: heating; the thermochemical process with the enrichment of the surface area during the carburizing or carbonitriding stage with carbon and nitrogen; and the subsequent quenching process for hardening. This article provides a model-based description of the development of residual stresses during case hardening. It also describes the influence and effects of residual stresses and distortion in hardening, carburizing, and nitriding processes of the steel.

Vacuum heat treating consists of thermally treating metals and alloys in cylindrical steel chambers that have been pumped down to less than normal atmospheric pressure. This article provides a detailed account of the operations and designs of vacuum furnaces, discussing their pressure levels, resistance heating elements, quenching systems, work load support, pumping systems, and temperature control systems. It describes the classification of instruments used for measuring and recording pressure inside a vacuum processing chamber. Common devices include hydrostatic measuring devices and devices for measuring thermal and electrical conductivity. The article also describes the applications of the vacuum heat treating process, namely, vacuum nitriding and vacuum carburizing. Finally, it reviews the heat treating process of tool steels, stainless steels, Inconel 718, and titanium and its alloys.

This article provides crystallographic and engineering data for single oxide ceramics, zirconia, silicates, mullite, spinels, perovskites, borides, carbides, silicon carbide, boron carbide, tungsten carbide, silicon-nitride ceramics, diamond, and graphite. It includes data on crystal structure, density, mechanical properties, physical properties, electrical properties, thermal properties, and magnetic properties.

This article focuses on precision and ultraprecision finish machining techniques that make use of defined cutting edges, such as polycrystalline diamond and cubic boron nitride compacts. The techniques are finish turning, finish broaching, finish milling, and finish drilling.

Zirconium and hafnium surfaces require cleaning and finishing prior to many processes including joining, heat treating, plating, forming, and final surface finishing. This article provides information on surface treatment processes, surface soil removal, blast cleaning, chemical descaling, pickling or etching, anodizing, autoclaving, polishing, buffing, vapor phase nitriding, and electroplating. It also provides several application examples.

The classes of tool materials for machining operations are high-speed tool steels, carbides, cermets, ceramics, polycrystalline cubic boron nitrides, and polycrystalline diamonds. This article discusses the expanding role of surface engineering in increasing the manufacturing productivity of carbide, cermet, and ceramic cutting tool materials used in machining operations. The useful life of cutting tools may be limited by a variety of wear processes, such as crater wear, flank wear or abrasive wear, builtup edge, depth-of-cut notching, and thermal cracks. The article provides information on the applicable methods for surface engineering of cutting tools, namely, chemical vapor deposited (CVD) coatings, physical vapor deposited coatings, plasma-assisted CVD coatings, diamond coatings, and ion implantation.

Passivation; pickling, that is, acid descaling; electropolishing; and mechanical cleaning are important surface treatments for the successful performance of stainless steel used for piping, pressure vessels, tanks, and machined parts in a wide variety of applications. This article provides an overview of the various types of stainless steels and describes the commonly used cleaning methods, namely, alkaline cleaning, emulsion cleaning, solvent cleaning, vapor degreasing, ultrasonic cleaning, and acid cleaning. Finishing operations of stainless steels, such as grinding, polishing, and buffing, are reviewed. The article also explains the procedures of electrocleaning, electropolishing, electroplating, painting, surface blackening, coloring, terne coatings, and thermal spraying. It includes useful information on the surface modification of stainless steels, namely, ion implantation and laser surface processing. Surface hardening techniques, namely, nitriding, carburizing, boriding, and flame hardening, performed to improve the resistance of stainless steel alloys are also reviewed.

Specialty steels encompass a broad range of ferrous alloys noted for their special processing characteristics (powder metallurgy alloys), corrosion resistance (stainless steels), wear resistance and toughness (tool steels), high strength (maraging steels), or magnetic properties (electrical steels). This article provides a detailed discussion on the various surface treatments, including cleaning, nitriding, carburizing, coating, and plating, performed on specialty steels.

This article reviews the corrosion behavior in various environments for seven important nickel alloy families: commercially pure nickel, Ni-Cu, Ni-Mo, Ni-Cr, Ni-Cr-Mo, Ni-Cr-Fe, and Ni-Fe-Cr. It examines the behavior of nickel alloys in corrosive media found in industrial settings. The corrosive media include: hydrochloric acid, sulfuric acid, phosphoric acid, hydrofluoric acid, hydrobromic acid, nitric acid, organic acids, salts, seawater, and alkalis. The modes of high-temperature corrosion include oxidation, carburization, metal dusting, sulfidation, nitridation, corrosion by halogens, and corrosion by molten salts. Applications where the corrosion properties of nickel alloys are important factors in materials selection include the petroleum, chemical, and electrical power industries. Most nickel alloys are much more resistant than the stainless steels to reducing acids, such as hydrochloric, and some are extremely resistant to the chloride-induced phenomena of pitting, crevice attack, and stress-corrosion cracking (to which the stainless steels are susceptible). Nickel alloys are also among the few metallic materials able to cope with hot hydrofluoric acid. The conditions where nickel alloys suffer environmentally assisted cracking are highly specific and therefore avoidable by proper design of the industrial components.

This article examines the high-temperature oxidation of silica-forming ceramics under constant temperature and cyclic conditions. The effects of water vapor, impurities, and molten salts are discussed. The article describes the oxidation and corrosion of silica-forming composites, oxide ceramics, non-silica forming nitrides, carbides, and borides. The performance of environmental barrier coatings by material type is also discussed. The article also explains the effects of oxidation and corrosion on the mechanical properties of ceramic-matrix composites. It concludes with information on high-temperature applications, wear properties, and the microscopic analyses of advanced ceramics.

Selecting the proper cutting tool material for a specific machining application can provide substantial advantages, including increased productivity, improved quality, and reduced costs. This article begins with a description of the factors affecting the selection of a cutting tool material. This is followed by a schematic representation of their relative application ranges in terms of machining speeds and feed rates. The article provides a detailed account of chemical compositions of various tool materials, including high-speed tool steels, cobalt-base alloys, cemented carbides, cermets, ceramics, cubic boron nitride, and polycrystalline diamond. It compares the toughness, and wear resistance for these cutting tool materials. Finally, the article explains the steps for selecting tool material grades for specific application.

This article is a pictorial representation of commonly observed microstructures in iron-base alloys (carbon and alloy steels, cast irons, tool steels, and stainless steels) that occur as a result of variations in chemical analysis and processing. It reviews a wide range of common and complex mixtures of constituents (single or combination of two phases) that are encountered in iron-base alloys and the complex structure that is observed in these microstructures. The single-phase constituents discussed in the article include austenite, ferrite, delta ferrite, cementite, various alloy carbides, graphite, martensite, and a variety of intermetallic phases, nitrides, and nonmetallic inclusions. The article further describes the two-phase constituents including, tempered martensite, pearlite, and bainite and nonmetallic inclusions in steel that consist of two or more phases.

Case hardening is defined as a process by which a ferrous material is hardened in such a manner that the surface layer, known as the case, becomes substantially harder than the remaining material, known as the core. This article discusses the equipment required, process variables, carbon and hardness gradients, and process procedures of different types of case hardening methods: carburizing (gas, pack, liquid, vacuum, and plasma), nitriding (gas, liquid, plasma), carbonitriding, cyaniding and ferritic nitrocarburizing. An accurate and repeatable method of measuring case depth is essential for quality control of the case hardening process and for evaluation of workpieces for conformance with specifications. The article also discusses various case depth measurement methods, including chemical, mechanical, visual, and nondestructive methods.

This article presents the principles of chemical vapor deposition (CVD) with illustrations. It discusses the types of CVD processes, namely, thermal CVD, plasma CVD, laser CVD, closed-reactor CVD, chemical vapor infiltration, and metal-organic CVD. The article reviews the CVD reactions of materials related to hard, tribological, and high-temperature coatings and to free-standing structures. It concludes by reviewing the advantages, disadvantages, and applications of CVD.

This article discusses the application of amorphous and crystalline films through plasma-enhanced chemical vapor deposition (PECVD) from the view point of microelectronic device fabrication. It describes the various types of PECVD reactors and deposition techniques. Plasma enhancement of the CVD process is discussed briefly. The article also describes the properties of amorphous and crystalline films deposited by the PECVD process for integrated circuit fabrication.

Physical vapor deposition (PVD) coatings are harder than any metal and are used in applications that cannot tolerate even microscopic wear losses. This article describes the three most common PVD processes: thermal evaporation, sputtering, and ion plating. It also discusses ion implantation in the context of research and development applications.