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Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001110
EISBN: 978-1-62708-162-7
... Abstract Niobium-titanium alloys (NbTi) became the superconductors of choice in the early 1960s, providing a viable alternative to the A-15 compounds and less ductile alloys of niobium-zirconium. This can be attributed to the relative ease of fabrication, better electrical properties...
Abstract
Niobium-titanium alloys (NbTi) became the superconductors of choice in the early 1960s, providing a viable alternative to the A-15 compounds and less ductile alloys of niobium-zirconium. This can be attributed to the relative ease of fabrication, better electrical properties, and greater compatibility with copper stabilizing materials. This article discusses the ramifications of design requirements, selection criteria and processing methods of superconducting fibers and matrix materials. It provides information on the various steps involved in the fabrication of superconducting composites, including assembly, welding, isostatic compaction, extrusion, wire drawing, twisting, and final sizing. The article also provides a detailed account of the properties and applications of NbTi superconducting composites.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003155
EISBN: 978-1-62708-199-3
... the bulk of the superconductor. Superconducting materials that have received the most attention are niobium-titanium superconductors (the most widely used superconductor), A15 compounds (in which class the important ordered intermetallic Nb3Sn lies), ternary molybdenum chalcogenides (Chevrel phases...
Abstract
Superconductors are materials that exhibit a complete disappearance of electrical resistivity on lowering the temperature below the critical temperature. A superconducting material must exhibit perfect diamagnetism, that is, the complete exclusion of an applied magnetic field from the bulk of the superconductor. Superconducting materials that have received the most attention are niobium-titanium superconductors (the most widely used superconductor), A15 compounds (in which class the important ordered intermetallic Nb3Sn lies), ternary molybdenum chalcogenides (Chevrel phases), and high-temperature ceramic superconductors. This article provides an overview of basic principles of superconductors and the different classes of superconducting materials and their general characteristics.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001108
EISBN: 978-1-62708-162-7
... “Principles of Superconductivity,” the manufacture, properties, and applications of various superconducting materials are addressed in the following articles: “Niobium-Titanium Superconductors” (the most widely used superconductor) “A15 Superconductors” (in which class the important material Nb...
Abstract
This article reviews the history of superconductivity from its discovery in the early 1900s to the renewed interest in the mid-1980s spurred by the development of high-temperature superconducting devices. It identifies some of the materials in which superconductivity has been observed, including metals and alloys, compounds, and oxides, and discusses their properties as well as potential applications. The article also explains how various superconducting materials are produced and provides a foundation for understanding the basic operating principles.
Book Chapter
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0004008
EISBN: 978-1-62708-185-6
..., each individually surrounded by a normal metal matrix. The superconductor itself is usually a ductile alloy of niobium and titanium ( Fig. 14 ) or a brittle intermetallic of niobium and tin (Nb 3 Sn) ( Fig. 15 and 16 ). Fig. 14 Cross section of 500 niobium-titanium filaments separated...
Abstract
The drawing process, one of the oldest metal forming operations, allows excellent surface finishes and closely controlled dimensions to be obtained in long products that have constant cross sections. This article discusses the basic mechanics and preparation steps of drawing. It presents an overview of the processes, equipment, dies and die materials, and lubrication associated with drawing of rod, wire, bar, and tube. The article also provides a discussion on the design considerations and manufacturing of commercial superconducting multifilamentary conductors.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001111
EISBN: 978-1-62708-162-7
... Rod Process The various rod processes for A15 conductors resemble very strongly those described for NbTi conductors (see the article “Niobium-Titanium Superconductors” in this Volume). The bronze process consists of stacking vanadium or niobium alloy rods in bronze tubes or drilled bronze...
Abstract
This article reviews the phase diagrams, alloy with third element additions, layer growth, critical current density, and matrix materials of A15 superconductors. It describes the production methods of tape conductors (chloride deposition, and surface diffusion) and multifilamentary wires (rod process, modified jelly roll process, niobium tube process, in-situ process, powder metallurgy process, and jelly roll method). The article focuses on reaction heat treatment, which is required at the end of wire processing to convert the ductile components to the desired, but brittle, superconductor. Finally, it discusses the applications of A15 superconductors in commercial magnets, power generation, power transmission, high-energy physics, and fusion.
Image
in Principles of Superconductivity
> Properties and Selection: Nonferrous Alloys and Special-Purpose Materials
Published: 01 January 1990
Fig. 7 The critical surface for a niobium-titanium alloy. As long as the state of the superconductor remains within the critical surface, it will be superconducting. The strong interdependence of the three critical parameters ( T c , H c2 , and J c ) is clearly seen.
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Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001109
EISBN: 978-1-62708-162-7
... in all parameters. Operating conditions for superconducting magnets are often at temperatures of T ≦ 0.5 T c . Fig. 7 The critical surface for a niobium-titanium alloy. As long as the state of the superconductor remains within the critical surface, it will be superconducting. The strong...
Abstract
Superconductivity has been found in a wide range of materials, including pure metals, alloys, compounds, oxides, and organic materials. Providing information on the basic principles, this article discusses the theoretical background, types of superconductors, and critical parameters of superconductivity. It discusses the magnetic properties of selected superconductors and types of stabilization, including cryogenic stability, adiabatic stability, and dynamic stability. The article also focuses on alternating current losses in superconductors, including hysteresis loss, penetration loss, eddy current loss, and radio frequency loss. Furthermore, the article describes the flux pinning phenomenon and Josephson effects.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001079
EISBN: 978-1-62708-162-7
... wire, in which very fine filaments of the alloy (with thicknesses of <1 μm, or 40 μin.) are embedded in a copper matrix (see the article “Niobium-Titanium Superconductors” in this Volume and the section “The Manufacture of Commercial Superconductors” in the article “Wire, Rod, and Tube Drawing...
Abstract
All refractory metals, except osmium and iridium, have the highest melting temperatures and lowest vapor pressures of all metals. This article discusses the commercial applications, and production procedures of refractory metals and alloys. These procedures include fabrication, machining, forming, cleaning, joining, and coatings. The article also presents information on, and specifications for, the following metals and their alloys: niobium, tantalum, molybdenum, tungsten, rhenium, and refractory metal fiber-reinforced composites. It discusses the processes involved in their production, their mechanical properties, physical properties, thermal properties, electrical properties, chemical properties, applications, and corrosion resistance.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003824
EISBN: 978-1-62708-183-2
... processing liquid metals NIOBIUM AND NIOBIUM ALLOYS have been used in a number of industrial and aerospace applications for over 40 years. Niobium use primarily includes rocket and jet engine applications, alloying of steels and superalloys, sodium vapor highway lighting, superconductors, anodic...
Abstract
For chemical processing, niobium resists a wide variety of corrosive environments, including mineral acids, many organic acids, liquid metals, and most salt solutions. This article focuses on the mechanisms of corrosion resistance of niobium alloys in these environments. The niobium alloys include Nb-1Zr, Nb-55Ti, Nb-50Ta, and Nb-40Ta. The article describes the use of these corrosion resistant niobium alloys, and provides information on applications of niobium in various industries.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001080
EISBN: 978-1-62708-162-7
... Abstract Titanium has been recognized as an element with good mechanical and physical properties, alloying characteristics, and corrosion resistance. Providing an outline of general characteristics and types of titanium alloys, this article discusses the contemporary technology of titanium...
Abstract
Titanium has been recognized as an element with good mechanical and physical properties, alloying characteristics, and corrosion resistance. Providing an outline of general characteristics and types of titanium alloys, this article discusses the contemporary technology of titanium along with its market developments. It also discusses the application of titanium and titanium alloys in corrosive environments and in aerospace and automotive industries. The article describes the developments in titanium processing and materials technologies, which include the development of sponge production and melting processes, oxide dispersion-strengthened alloys by powder metallurgy techniques, titanium-base intermetallic compounds, and titanium-matrix composites.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003056
EISBN: 978-1-62708-200-6
... the components together at a high temperature. Success depends on the formation of an adequate interfacial contact. The most extensively studied systems are alumina with niobium, aluminum, nickel, platinum, and titanium. The metals react with Al 2 O 3 to produce various interfacial compounds, such as NiAl 2...
Abstract
Many applications of ceramics and glasses require them to be joined to each other or to other materials such as metals. This article focuses on ceramic joining technologies, including glass-metal sealing, glass-ceramic/metal joining, ceramic-metal joining, ceramic-ceramic joining, and the more advanced joining of nonoxide ceramics. It also discusses metallizing, brazing, diffusion bonding, and chemical bonding.
Series: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002462
EISBN: 978-1-62708-194-8
... with processing parameters to meet the requirements of new technology. This process is ongoing today with the base alloys available for centuries (iron, copper, tin) as well as with the newer base alloys currently recruited to meet modern needs with unique property requirements (titanium, tungsten, niobium). When...
Abstract
This article focuses on the monolithic form of nonferrous alloys, including aluminum, copper, nickel, cobalt, titanium, zinc, magnesium, and beryllium alloys. Each metal and alloy offers unique combinations of useful physical, chemical, and structural properties that are made available by its particular composition and the proper choice of processing method. The article describes the composition, designation system, properties, and processing method of these metals and alloys. It discusses the effect of alloying elements in these alloys. The article explains microstructure/property relationships that are used to make specific properties available to the designers of structural applications. It provides examples of phase diagrams that illustrate eutectic and peritectic reactions.
Series: ASM Handbook
Volume: 4C
Publisher: ASM International
Published: 09 June 2014
DOI: 10.31399/asm.hb.v04c.a0005887
EISBN: 978-1-62708-167-2
... Abstract This article focuses on the temperature requirements of typical nonferrous metals and their alloys of commercial importance. These include aluminum, copper, magnesium, and titanium. The article describes the thermoelectricity, photoelectricity, and capacity of aluminum alloys...
Abstract
This article focuses on the temperature requirements of typical nonferrous metals and their alloys of commercial importance. These include aluminum, copper, magnesium, and titanium. The article describes the thermoelectricity, photoelectricity, and capacity of aluminum alloys. In addition, it provides information on the electrical properties of copper and its alloys. The article also lists typical physical and mechanical properties of aluminum alloys at ambient temperature.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001102
EISBN: 978-1-62708-162-7
.... Information on other intermetallics, such as samarium-cobalt materials for permanent magnets and niobium-base superconductive materials, is available in the articles “ Rare Earth Metals ,” “ Permanent Magnet Materials ,” and “A15 Superconductors” in this Volume. Nickel Aluminides The nickel-aluminum...
Abstract
Ordered intermetallic compounds based on aluminides and silicides constitute a unique class of metallic materials that have promising physical and mechanical properties for structural applications at elevated temperatures. This article provides useful information on mechanical and metallurgical properties, material processing and fabrication, structural applications, mechanical behavior, environmental embrittlement, alloying effects, and crystal structure of aluminides of nickel, iron, titanium, and silicides. It describes the cleavage and intergranular fracture in trialuminides.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003062
EISBN: 978-1-62708-200-6
... applications, but TiO 2 is also being developed as an oxygen sensitive resistive sensor. Other categories of ceramic materials include ferrites and ceramic superconductors. Recent developments in ferrites have been related primarily to their use as recording heads, but research in the area of microwave...
Abstract
Ceramic materials serve important insulative, capacitive, conductive, resistive, sensor, electrooptic, and magnetic functions in a wide variety of electrical and electronic circuitry. This article focuses on various applications of advanced ceramics in both electric power and electronics industry, namely, dielectric, piezoelectric, ferroelectric, sensing, magnetic and superconducting devices.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001095
EISBN: 978-1-62708-162-7
... group discovered a second class of metallic liquids that form glasses at rapid solidification rates. These are referred to as the metal-metal systems. These alloys contain an early transition metal or rare earth element (for example, zirconium, titanium, niobium, tantalum, and so on) alloyed with a late...
Abstract
Metallic glasses can be prepared by solidification of liquid alloys at cooling rates sufficient to suppress the nucleation and growth of competing crystalline phases. This article presents a historical survey of the study of metallic glasses and other amorphous metals and alloys. This includes a discussion of synthesis and processing methods, structure and morphology, and a description of the electronic, magnetic, thermodynamic, chemical, and mechanical properties of metallic glasses. In addition, the article describes the development of metallic glasses as materials for technical applications.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001105
EISBN: 978-1-62708-162-7
... for a cermet can also be chosen from the group of more reactive metals, such as titanium or zirconium, or it can be selected from series of refractory metals that includes chromium, niobium, molybdenum, and tungsten. Lower-melting metals and alloys, primarily those based on copper and aluminum, round out...
Abstract
Ceramic-metal composites, or cermets, combine the heat and wear resistance of ceramics with the formability of metals, filling an application niche that includes cutting tools, brake pads, heat shields, and turbine components. This article examines a wide range of cermets, including oxide cermets, carbide and carbonitride cermets, boride cermets, and other refractory types. It describes the powder metallurgy process by which cermets are produced, examining each step from powder preparation to post treatment. It discusses forming and compacting, injection molding, extrusion, rolling, pressing, slip casting, and sintering. It also discusses fundamental concepts such as chemical bonding, chemical composition, microstructure, and the development of physical and mechanical properties.
Book Chapter
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001316
EISBN: 978-1-62708-170-2
...-titanium yellow rutile 71077-18-4 (Ti,Ni,Sb)O 2 11-15-4 Nickel-niobium-titanium yellow rutile 68611-43-8 (Ti,Ni,Nb)O 2 11-16-4 Chrome-antimony-titanium buff rutile 68186-90-3 (Ti,Cr,Sb)O 2 11-17-6 Chrome-niobium-titanium buff rutile 68611-42-7 (Ti,Cr,Nb)O 2 11-18-6 Chrome...
Abstract
This article focuses on the ceramic coatings for ceramic and glass substrates. It describes the role of oxides in glazes and discusses the optical and appearance properties of various types of glazes, such as leadless glazes, lead-containing glazes, opaque glazes, and satin and matte glazes. The article provides information on the classification of pigments and the applications of ceramic coatings for decorations on ceramic and glass surfaces.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001457
EISBN: 978-1-62708-173-3
... conductors, piezoelectric devices, and high-critical-temperature superconductors, this category of materials and the related joining technology is outside the scope of this article. A primary impetus behind the emphasis on structural ceramics is the desire for improved efficiency and increased component...
Abstract
This article is intended to assist the development of procedures for the brazing of ceramic-to-ceramic or ceramic-to-metal joints for service under elevated temperatures, mechanical or thermal stresses, or corrosive atmospheres. It describes the factors considered in preparing a procedure for the brazing of graphitic materials.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003005
EISBN: 978-1-62708-200-6
... low carbon contents (0.05 to ∼0.25%) in order to produce adequate formability and weldability, and they have manganese contents up to 2.0%. Typically, HSLA steels are strengthened by small additions of elements such as niobium (also known as columbium), copper, vanadium, or titanium and sometimes...
Abstract
The selection of engineered materials is an integrated process that requires an understanding of the interaction between materials properties, manufacturing characteristics, design considerations, and the total life cycle of the product. This article classifies various engineered materials, including ferrous alloys, nonferrous alloys, ceramics, cermets and cemented carbides, engineering plastics, polymer-matrix composites, metal-matrix composites, ceramic-matrix and carbon-carbon composites, and reviews their general property characteristics and applications. It describes the synergy between the elements of the materials selection process and presents a general comparison of material properties. Finally, the article provides a short note on computer aided materials selection systems, which help in proper archiving of materials selection decisions for future reference.
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