The high-alloyed white irons are primarily used for abrasion-resistant applications and are readily cast into the parts needed in machinery for crushing, grinding, and handling of abrasive materials. This article discusses three major groups of the high-alloy white cast irons: nickel-chromium white irons, chromium-molybdenum irons, and high-chromium white irons. Mechanical properties for three white irons representing each of these three general groups are presented as bar graphs. The article also describes the various heat treatments of a martensitic microstructure, including austenitization, quenching, tempering, annealing, and stress relieving.

High-alloyed white cast irons are an important group of materials whose production must be considered separately from that of ordinary types of cast irons. The metallic matrix supporting the carbide phase in the high-alloy white cast irons can be adjusted by alloy content and heat treatment to develop proper balance between resistance to abrasion and toughness needed to withstand repeated impact. This article provides a brief discussion on the heat treatment, mechanical properties, and chemical compositions of high-alloy white cast irons such as nickel-chromium white irons and high-chromium white irons.

This article presents a discussion on the melting, pouring, and shakeout practices; composition control; molds, patterns, and casting design; heat treatment; and applications of different classes of nickel-chromium white irons and high-chromium white irons.

Alloy cast irons are considered to be those casting alloys based on the iron-carbon-silicon system that contain one or more alloying elements intentionally added to enhance one or more useful properties. Alloy cast irons can be classified as white cast irons, corrosion-resistant cast irons, and heat-resistant cast irons. This article discusses abrasion-resistant chilled and white irons, high-alloy corrosion-resistant irons, and medium-alloy and high-alloy heat-resistant gray and ductile irons. The article outlines in a list the approximate ranges of alloy content for various types of alloy cast irons. The article explains the effects of alloying elements and the effects of inoculants. In most cast irons, it is the interaction among alloying elements that has the greatest effect on properties. Inoculants other than appropriate graphitizing or nodularizing agents are used rarely, if ever, in high-alloy corrosion-resistant or heat-resistant irons.

Cast irons have been widely used by engineers in applications that require low cost, excellent castability, good damping capacity, ease of machining, and wear resistance. This article discusses the classification of wear for cast irons: adhesive wear, abrasive wear, and erosive wear. Typical wear applications for a variety of cast iron grades are listed in a table. The article reviews the general wear characteristics of gray irons, compacted graphite (CG) irons, and ductile irons. It discusses the typical compositions and properties of white and chilled iron castings. Gray cast iron is the dominant material for both brake drums and disk brake rotors. The article reviews brake lining chemistry effects, graphite morphology effects, and external abrasive effects on brake drums. It concludes with information on cast iron grinding balls.

This article presents typical wear applications for a variety of cast iron grades in a table. In general, wear is classified according to three major types: adhesive (frictional) wear (sliding and rolling) caused by contact of one metallic surface with another; abrasive wear caused by contact with metallic (shots, swarf) or nonmetallic abrasive materials; and erosive wear. The article discusses general wear characteristics of gray iron, compacted gray iron, and ductile iron. It provides information on the brake lining chemistry effects, graphite morphology effects, normal cast iron wear, local cast iron wear, and external abrasive effects on brake drums and disk brake rotors made of gray cast iron. The article concludes with a discussion on the application of cast iron for grinding balls.

Castability of alloys is a measure of their ability to be cast to a given shape with a given process without the formation of cracks/tears, pores/shrinkage, and/or other significant casting defects. This article discusses the factors which affect the fluidity of an iron melt: alloy composition and initial melt condition. Besides the basic alloy properties, the effective castability of high-alloy irons can be significantly improved through casting and casting system design. The article describes the product design and processing factors of high-alloy graphitic irons and high-alloy white irons. It explains the heat treatment of high-silicon irons for high-temperature service and concludes with a discussion on machining and finishing of high-alloy iron castings.

The high-alloy irons can be categorized into two main groups: the high-alloy graphitic irons (covering both gray and ductile grades) and the high-alloy white irons. High-alloy irons are used in applications with demanding requirements, such as high resistance to wear, heat, and corrosion, or for combined properties. This article discusses the specification and selection of high-alloy irons. The common alloying elements and their effect on the stable and metastable eutectic temperatures are listed in a table. The article provides information on the compositions, properties and applications of high-alloy graphitic irons and high-alloy white irons.

Alloy cast irons are casting alloys based on the Fe-C-Si system that contain one or more alloying elements added to enhance one or more useful properties. This article discusses the composition of different types of alloy cast iron, including white cast irons, corrosion-resistant cast irons, heat-resistant cast irons, and abrasion-resistant cast irons. It provides information on the effect of the alloying element on their high-temperature properties. The article also discusses the microstructure and mechanical properties of alloy cast irons.