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Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003741
EISBN: 978-1-62708-177-1
... Abstract Interdiffusion microstructures appear as a region on either side of the original interface of contact between two materials. This article outlines the principles used in analyzing various interdiffusion microstructures: binary systems, copper-base systems, nickel-base systems...
Abstract
Interdiffusion microstructures appear as a region on either side of the original interface of contact between two materials. This article outlines the principles used in analyzing various interdiffusion microstructures: binary systems, copper-base systems, nickel-base systems, and silicide-forming systems. The analysis can be helpful in classifying microstructures and in understanding how they change with alloy composition, especially when thermal history is known. The microstructures also help in identifying microstructural artifacts caused by polishing and in recognizing errors in reported heat treating schedules.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001267
EISBN: 978-1-62708-170-2
... and require little metal replacement because of the very thin deposits produced. Displacement tin-lead solder processes are the exception, producing thicker deposits requiring more frequent additions. Types of Electroless Alloy Plating Systems Most electroless alloy systems are based on nickel alloys...
Abstract
Metallic nonelectrolytic alloy coatings produced from aqueous solutions are commercially used in several industries, including electronics, aerospace, medical, oil and gas production, chemical processing, and automotive. Nonelectrolytic coating systems use two types of reactions to deposit metal onto a part: electroless and displacement. This article explains the various types of electroless and dispersion alloy coating systems. It provides information on the processing of parts, process control, deposit analysis, and equipment used for coating nonelectrolytic displacement alloys. The article concludes with a discussion on the safety and environmental concerns associated with nonelectrolytic deposition processes.
Book Chapter
Electroplated Coatings for Friction, Lubrication, and Wear Technology
Available to PurchaseSeries: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006395
EISBN: 978-1-62708-192-4
.... The Plating System For most applications, electrodepositing a single metal layer onto the base material is insufficient to meet product-performance requirements. For example, a nickel coating on a zinc alloy can improve resistance to wear and corrosion; however, adhesion between nickel and zinc is very...
Abstract
This article discusses the fundamentals of electroplating processes, including pre-electroplating and surface-preparation processes. It illustrates the four layers of a plating system, namely, top or finish coat, undercoat, strike or flash, and base material layers. The article describes various plating methods, such as pulse electroplating, electroless plating, brush plating, and jet plating. It reviews the types of electrodeposited coatings, including hard coatings and soft coatings. The article also details the materials available for electroplating, including electroplated chromium, electroplated nickel, electroless (autocatalytic) nickel, electroless nickel composite coatings, electroplated gold, and platinum group coatings. These are specifically tailored toward plated coatings for friction, lubrication, and wear technology. The article concludes with a discussion on the common issues encountered with electroplating.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005336
EISBN: 978-1-62708-187-0
..., and usually the most contaminated, metal to enter the system. Similarly, the runners and ingates are curved wherever a change in direction occurs. This streamlining reduces turbulence in the metal and minimizes mold erosion. In pouring nickel-base alloys, as well as other high-alloy steels, a high gating...
Abstract
Nickel-base alloy castings are widely used in corrosive-media and high-temperature applications. This article begins with a discussion on the compositions of corrosion-resistant nickel-base casting alloys and heat-resistant nickel-base casting alloys. It describes the effects of aluminum and titanium on the structure and properties of nickel-base alloys. The article provides information on the melting, foundry, and pouring practices for nickel-base alloys. It explains the welding and heat treatment of the nickel-base casting alloys. The article concludes with an overview of the numerous applications of cast heat-resistant nickel-base alloys.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003609
EISBN: 978-1-62708-182-5
... is accelerated because protective surface films are not formed. In fact, the fluoride salts act as excellent fluxes and dissolve the various corrosion products. Typically, nickel-base alloys show better corrosion resistance than iron-base alloys. Studies have also shown that most nickel- and iron-base alloys...
Abstract
This article discusses two general mechanisms of corrosion in molten salts. One is the metal dissolution caused by the solubility of the metal in the melt. The second and most common mechanism is the oxidation of the metal to ions. Specific examples of the types of corrosion expected for the different metal-fused salt systems are also provided. The metal-fused salt systems include molten fluorides, chloride salts, molten nitrates, molten sulfates, hydroxide melts, and carbonate melts. The article concludes with information on prevention of molten salt corrosion.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003831
EISBN: 978-1-62708-183-2
... alloys. Most results published on the corrosion behavior of manganese-nickel filler metals indicate that this system exhibits poor corrosion resistance in high-temperature environments. Precious-Metal-Base Filler Alloys Gold filler alloys are used in vacuum and high-temperature heat-resisting...
Abstract
Corrosion is often thought of as rusting, the process of deterioration undergone by a metal when it is exposed to air or water. This article provides the fundamentals of joints corrosion and primarily addresses the various forms of corrosion observed in brazed and soldered joints and their causes. It describes the role of proper brazing procedures in controlling corrosion. The article concludes with information on the corrosion resistance of various brazing alloy systems.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001355
EISBN: 978-1-62708-173-3
... the semiautomatic FCAW equipment used in the gas-shielded FCAW process. The article discusses the manufacture of flux-cored electrodes and the classification of electrodes, such as carbon and low-alloy steel electrodes, stainless steel electrodes, and nickel-base electrodes. The functions of common core ingredients...
Abstract
In the flux-cored arc welding (FCAW) process, the heat for welding is produced by an electric arc between a continuous filler metal electrode and a workpiece. This article discusses the advantages and disadvantages and applications of the FCAW process. It schematically illustrates the semiautomatic FCAW equipment used in the gas-shielded FCAW process. The article discusses the manufacture of flux-cored electrodes and the classification of electrodes, such as carbon and low-alloy steel electrodes, stainless steel electrodes, and nickel-base electrodes. The functions of common core ingredients in FCAW electrodes are listed in a table.
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005601
EISBN: 978-1-62708-174-0
... Abstract This article describes the process features, advantages, limitations, and applications of the flux cored arc welding (FCAW) as well as the equipment used in the process. Base metals, namely, carbon and low-alloy steels, stainless steels, and nickel-base alloys, welded by the FCAW...
Abstract
This article describes the process features, advantages, limitations, and applications of the flux cored arc welding (FCAW) as well as the equipment used in the process. Base metals, namely, carbon and low-alloy steels, stainless steels, and nickel-base alloys, welded by the FCAW process are reviewed. The article illustrates the manufacturing process for the electrodes used in FCAW and outlines the classification of carbon and low-alloy steel, stainless steel, and nickel-base electrodes.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003834
EISBN: 978-1-62708-183-2
... that cannot be obtained in a single material. The early use of clad metals in the jewelry industry combined the aesthetics of precious metals with the low-cost strength of base metals. These materials systems are currently being used for electrical and electronics applications, such as contacts and connectors...
Abstract
This article describes the principal cladding processes and methods for calculating properties of clad metals. It reviews the designing processes of clad metals to achieve specific requirements. The article discusses six categories of clad metal systems designed for corrosion control: noble metal clad systems, corrosion barrier systems, sacrificial metal systems, transition metal systems, complex multilayer systems, and clad diffusion alloys.
Book Chapter
Commercial Alloy Phase Diagrams and Their Industrial Applications
Available to PurchaseSeries: ASM Handbook
Volume: 22B
Publisher: ASM International
Published: 01 November 2010
DOI: 10.31399/asm.hb.v22b.a0005511
EISBN: 978-1-62708-197-9
... a small amount of yttrium into the Cu-Zr-Ti system, and as-cast amorphous rods as big as 10 mm in diameter were obtained ( Ref 14 ). Fig. 3 Critical diameters of the cast glassy rods as a function of the titanium concentration in atomic percent Example 2: Design and Development of Nickel-Base...
Abstract
This article focuses on the industrial applications of phase diagrams. It presents examples to illustrate how a multicomponent phase diagram calculation can be readily useful for industrial applications. The article demonstrates how the integration of a phase diagram calculation with kinetic and microstructural evolution models greatly enhances the power of the CALPHAD approach in materials design and processing development. It also discusses the limitations of the CALPHAD approach.
Book Chapter
Shape Memory Alloys
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003160
EISBN: 978-1-62708-199-3
... and properties (mechanical and physical) of commercial SMA alloys, namely nickel-titanium alloys and copper-base alloys. applications of shape memory alloys copper base alloys general characteristics mechanical properties nickel-titanium alloys physical properties processing of shape memory alloys...
Abstract
The term shape memory alloys (SMAs) refers to the group of metallic materials that demonstrate the ability to return to some previously defined shape or size when subjected to the appropriate thermal procedure. Materials that exhibit shape memory only upon heating are referred to as having a one-way shape memory. Some materials also undergo a change in shape upon recooling. These materials have a two-way shape memory. This article discusses the general characteristics of SMAs by using typical transformation versus temperature curve. It describes the processing, applications and properties (mechanical and physical) of commercial SMA alloys, namely nickel-titanium alloys and copper-base alloys.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001266
EISBN: 978-1-62708-170-2
... a cyanide-base system with potassium borohydride as the reducing agent. Deposit thickness, 1.5 μm. 5000× Process Description As mentioned earlier, the deposition of gold without an external source of current can occur by a simple displacement reaction between two metals: (Eq 1...
Abstract
This article focuses on the electroless gold plating technique, describing the advantages and limitations, applications, and properties of plated deposits. It also reviews process variables of the technique, including gold concentration, reducing agent, agitation, and contaminants.
Book Chapter
Introduction to the Selection of Stainless Steels
Available to PurchaseSeries: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001407
EISBN: 978-1-62708-173-3
... Fundamentally, stainless steels are based on the iron-chromium, iron-chromium-carbon, and iron-chromium-nickel systems, but may contain a number of other alloying additions that alter their microstructures and/or properties. The “stainless” nature of these steels arises primarily from the addition of chromium...
Abstract
Stainless steels are an important class of engineering alloys used in both wrought and cast form for a wide range of applications and in many environments. This article aids in the selection of stainless steels based on weldability and service integrity. Stainless steels are classified by microstructure and are described as ferritic, martensitic, austenitic, or duplex. The article illustrates compositional ranges of the ferritic, martensitic, austenitic, and duplex alloys in the Schaeffler diagram. It describes the metallurgical aspects of welded stainless steels to be considered for particular engineering applications and service conditions. The article discusses the microstructural evolution of the weld metal and the heat-affected zone, susceptibility to defect formation during welding, mechanical and corrosion properties, and weld process tolerance.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003593
EISBN: 978-1-62708-182-5
... used aluminum beverage cans, the Hall-Heroult aluminum electrowinning cell with a fluoride (cryolite)-base electrolyte, nitrate/nitrite heat-exchange salts, and fused salt descaling or heat treatment baths. In other important engineering systems, the accelerated corrosion of materials results from...
Abstract
Metals and ceramics exposed to high-temperature salt solutions are susceptible to a form of corrosion caused by fused salts accumulating on unprotected surfaces. This article examines the electrochemistry of such hot corrosion processes, focusing on sodium sulfate systems generated by the combustion of fossil fuels. It explains how salt chemistry, including acid/base and oxidizing properties, affects corrosion rates and mechanisms. The article also provides information on electrochemical testing and explains how Pourbaix methods, normally associated with aqueous corrosion, can be used to study fused-salt corrosion.
Book Chapter
Introduction to the Selection of Nonferrous Corrosion-Resistant Materials
Available to PurchaseSeries: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001427
EISBN: 978-1-62708-173-3
... laboratory corrosion testing. For many applications, nickel-base alloys are called upon to resist certain severe corrosion environments. Pure nickel has good resistance to reducing environment corrosion and is an excellent base upon which to build corrosion-resistant alloys. The atomic size, outer-shell...
Abstract
Improvement in the corrosion performance of a component or structure can be achieved through proper design, surface protection, proper material selection, or combinations of all three parameters. This is an introductory article on the selection of nonferrous corrosion-resistant materials.
Book Chapter
Corrosion Resistance of Stainless Steels and Nickel Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003676
EISBN: 978-1-62708-182-5
... By far, the largest family of nickel alloys is that based on the nickel-chromium system, with alloy 600 (N06600) being the prototype ( Fig. 2 ). Chromium imparts resistance to oxidizing environments and high-temperature strength. Increasing chromium to 30%, as in alloy 690 (N06690), also increases...
Abstract
Stainless steels and nickel-base alloys are recognized for their resistance to general corrosion and other categories of corrosion. This article examines the effects of specific alloying elements, metallurgical structure, and mechanical conditioning on corrosion resistance of these materials. It provides information on the compositions of selected stainless steels, copper-nickel, and nickel-base alloys in a tabular form. The article also illustrates the compositional and property linkages for stainless steels and nickel-base alloys.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003120
EISBN: 978-1-62708-199-3
...-boundary and intragranular δ phase in (d). γ″ not obvious but present in (d) (right). Superalloy Systems The three types of superalloys—iron-nickel-, nickel-, and cobalt-base—may be further subdivided into cast and wrought. A large number of alloys have been invented and studied; many have been...
Abstract
Superalloys are nickel, iron-nickel, and cobalt-base alloys generally used for high-temperature applications. Superalloys are used in aircraft, industrial, marine gas turbines, nuclear reactors, spacecraft structures, petrochemical production, orthopedic and dental prostheses, and environmental protection applications. This article discusses the material characteristics, phases, structures, and systems of superalloys. It describes the processing of superalloys, including primary and secondary melting, deformation processing (conversion), powder processing, investment casting, and joining methods. The article also describes the properties, microstructure, and thermal exposure of superalloys. It further discusses the effects of environmental factors on superalloys, including oxidation and hot corrosion. Protective coatings are also discussed. The article provides information on the mechanical properties and chemical composition of nickel, iron, and cobalt-base superalloys in both the cast and wrought forms.
Book Chapter
Nickel and Nickel Alloys
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003147
EISBN: 978-1-62708-199-3
... the austenite (fcc) phase of some of the highly alloyed stainless steels, the boundary between these and nickel-base alloys is rather diffuse. For example, the Unified Numbering System (UNS) for metals and alloys classifies the following austenitic stainless steels as nickel alloys: Material UNS...
Abstract
Nickel and nickel-base alloys are vitally important to modern industry because of their ability to withstand a wide variety of severe operating conditions involving corrosive environments, high temperatures, high stresses, and combinations of these factors. This article discusses the mining and extraction of nickel and describes the uses of nickel. It discusses the categories of nickel-base alloys, including wrought corrosion-resistant alloys, cast corrosion-resistant alloys, heat-resistant alloys (superalloys), and special-purpose alloys. The article covers the corrosion resistance of nickel with the inclusion of varying alloying elements. It provides useful information on the behavior of nickel and nickel alloys in specific environments describes its corrosion resistance in certain acids, alkalis, and salts.
Book Chapter
Introduction to Corrosion Resistance of Bulk Materials
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003673
EISBN: 978-1-62708-182-5
... are iron-base and contain a small amount (usually in the 0.5 to 3.0 wt% range) of nickel, molybdenum, chromium, or copper. They also generally have small amounts of phosphorus, nitrogen, and sulfur. At the higher end of the alloying scale are the more costly and significantly more corrosion-resistant...
Abstract
This article discusses factors that influence the effect of alloying, metallurgical treatments, and mechanical treatments on the corrosion resistance of metallic materials, with schematic illustrations.
Book Chapter
Heat Treating of Precipitation-Hardenable Stainless Steels and Iron-Base Superalloys
Available to PurchaseSeries: ASM Handbook
Volume: 4D
Publisher: ASM International
Published: 01 October 2014
DOI: 10.31399/asm.hb.v04d.a0005961
EISBN: 978-1-62708-168-9
... Abstract Precipitation hardening is a hardening mechanism found in various steels and alloy systems, such as nickel-, cobalt-, titanium-, copper-, and iron-base alloys. This article provides a brief description of precipitation hardening process, furnace equipment, surface-related problems...
Abstract
Precipitation hardening is a hardening mechanism found in various steels and alloy systems, such as nickel-, cobalt-, titanium-, copper-, and iron-base alloys. This article provides a brief description of precipitation hardening process, furnace equipment, surface-related problems, and protective atmospheres used in heat treatment of iron-base precipitation-hardenable (PH) superalloys. It focuses on various factors to be considered in heat treating of PH stainless steels: cleaning prior to heat treatment, furnace atmospheres, time-temperature cycles, variations in cycles, and scale removal after heat treatment. The article describes the mechanical properties, solution treatment, and aging treatment for many martensitic PH alloys, including: Alloy 17-4 PH, Alloy 13-8 Mo, Alloy 15-5 PH, Custom 450, and Custom 455; as well as semiaustenitic PH stainless steels such as Alloy 17-7 PH, Alloy PH 15-7 Mo, AM-350, Pyromet 350, AM-355, and Pyromet 355; austenitic PH stainless steel, A-286; cast PH stainless steels; and iron-nickel PH superalloys.
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