In the flux-cored arc welding (FCAW) process, the heat for welding is produced by an electric arc between a continuous filler metal electrode and a workpiece. This article discusses the advantages and disadvantages and applications of the FCAW process. It schematically illustrates the semiautomatic FCAW equipment used in the gas-shielded FCAW process. The article discusses the manufacture of flux-cored electrodes and the classification of electrodes, such as carbon and low-alloy steel electrodes, stainless steel electrodes, and nickel-base electrodes. The functions of common core ingredients in FCAW electrodes are listed in a table.

This article describes the process features, advantages, limitations, and applications of the flux cored arc welding (FCAW) as well as the equipment used in the process. Base metals, namely, carbon and low-alloy steels, stainless steels, and nickel-base alloys, welded by the FCAW process are reviewed. The article illustrates the manufacturing process for the electrodes used in FCAW and outlines the classification of carbon and low-alloy steel, stainless steel, and nickel-base electrodes.

Cast iron can be described as an alloy of predominantly iron, carbon, and silicon. This article discusses the classification of cast irons, such as gray cast iron, white cast iron, malleable cast iron, ductile cast iron, and compacted graphite iron. It reviews the various special techniques, such as groove face grooving, studding, joint design modifications, and peening, for improving the strength of a weld or its fitness for service. The article discusses the need for postweld heat treatment that depends on the condition of the casting, possible distortion during subsequent machining, the desired finish of the machined surfaces, and prior heat treatment. It describes various welding process for welding cast irons, including oxyfuel welding, braze welding, shielded metal arc welding, gas metal arc welding, and gas-tungsten arc welding.

This article describes some examples of the different welding processes for gray, ductile, and malleable irons. These processes include fusion welding, repair welding, shielded metal arc welding, gas metal arc welding, flux cored arc welding, gas tungsten arc welding, submerged arc welding, oxyfuel welding, and braze welding. The article discusses various special techniques, such as groove-face grooving, studding, joint design modifications, and peening, for improving the strength of a weld or its fitness for service. The article describes other fusion welding methods such as electrical resistance welding and thermite welding. It reviews thermal spraying processes, such as flame spraying, arc spraying, and plasma spraying, of a cast iron.

Nickel alloys can be joined reliably by all types of welding processes or methods, with the exception of forge welding and oxyacetylene welding. This article discusses the heat treatment of nickel alloys and tabulates nominal compositions of selected weldable wrought nickel and nickel alloys. It provides information on gas-tungsten arc welding, gas-metal arc welding, plasma arc welding, shielded metal arc welding, and submerged arc welding for welding nickel alloys. The article reviews the defects encountered in the arc welding of nickel alloys, including porosity, cracking, and stress-corrosion cracking. It provides information on the factors that influence the choice of filler metal and welding process of nickel alloys.

This article discusses the metallurgical aspects of underwater welds. It describes the microstructural development, which mainly includes three types of ferrite associated with low carbon steel weld metal: grain-boundary ferrite, sideplate ferrite, and acicular ferrite. The article explains the factors that affect heat-affected zone (HAZ) cracking. These include hydrogen from the weld pool, microstructures that develop in the HAZ, and stress levels that develop in the weld joint. The article describes the welding practices that can reduce residual stresses. It explains the effect of water pressure on the formation of porosity in underwater gravity welding. The article concludes with a discussion on the practical applications of underwater welding.

Arc welding methods can be classified into shielded metal arc welding, flux-cored arc welding, submerged arc welding, gas metal arc welding, gas tungsten arc welding, plasma arc welding, plasma-metal inert gas (MIG) welding, and electroslag and electrogas welding. This article provides information on process capabilities, principles of operation, power sources, electrodes, shielding gases, flux, process variables, and advantages and disadvantages of these arc welding methods. It presents information about the arc welding procedures of hardenable carbon and alloy steels, cast irons, stainless steels, heat-resistant alloys, aluminum alloys, copper and copper alloys, magnesium alloys, nickel alloys, and titanium and titanium alloys.

Copper and copper alloys offer a unique combination of material properties that makes them advantageous for many manufacturing environments. This article begins with a discussion on common metals that are alloyed with copper to produce the various copper alloys. It then reviews the factors that affect the weldability of copper alloys, including thermal conductivity of the alloy being welded, shielding gas, type of current used during welding, joint design, welding position, and surface condition. The article provides information on arc welding processes such as gas-metal arc welding, shielded metal arc welding, submerged arc welding, plasma arc welding, and gas-tungsten arc welding. It concludes with a discussion on safe welding practices.

Voltammetry is the study of the current voltage relationships observed when electroactive species in solution are subject to oxidation or reduction at electrodes under carefully controlled conditions. This article describes the basic principle of voltammetry performed using the dropping mercury electrode (polarography). It discusses the various methods of voltammetry, namely, linear sweep voltammetry, cyclic voltammetry, and stripping voltammetry that are carried out with different electrode material. The article also explores the modern instrumentation and developments achieved in voltammetry, and provides an outline of additional data, such as values of the formation, or stability, and constants of complexes formed by shifting the half-wave potential, which can be obtained by voltammetry. Additionally, the article provides a brief account of the applications of voltammetry.

Batch furnaces and continuous furnaces are commonly used in heat treating. This article provides a detailed account of various heat treating equipment and its furnace types, including salt bath equipment (externally heated, immersed-electrode and submerged-electrode furnaces), and fluidized-bed equipment (external-resistance-heated fluidized beds). It describes various auxiliary equipment used in cold-wall furnaces, namely, heating elements and pumping systems. Five types of heat-resistant alloys are used for furnace parts, trays, and fixtures: Fe-Cr alloys, Fe-Cr-Ni alloys, Fe-Ni-Cr alloys, nickel-base alloys and cobalt-base alloys. The article lists the recommended applications for alloys for parts and fixtures for various types of heat treating furnaces.

Metals and alloy powders are used in welding, hardfacing, brazing, and soldering applications, which include hardface coatings, the manufacturing of welding stick electrodes and flux-cored wires, and additives in brazing pastes or creams. This article reviews these applications and the specific powder properties and characteristics they require.

Weldability refers to the ease of welding a material under the imposed fabrication conditions to perform satisfactorily during service. This article is a comprehensive collection of tables that summarize the general weldability of cast irons, steels, nonferrous metals, and their alloys by common fusion welding processes.

Shielded metal arc welding (SMAW), commonly called stick or covered electrode welding, is a manual welding process whereby an arc is generated between a flux-covered consumable electrode and a workpiece. This article discusses the advantages and limitations and applications of the SMAW process and describes the equipment used. It provides information on various coated electrodes used in the SMAW process, including mild and low-alloy steel-covered electrodes, stainless steel covered electrodes, and nickel and copper alloys covered electrodes. It reviews weld schedules and procedures, as well as the variations of the SMAW process. The article concludes with information on the special applications of the SMAW process and safety considerations.

Hardfacing is a form of surfacing that is applied for the purpose of reducing wear, abrasion, impact, erosion, galling, or cavitation. This article describes the deposition of hardfacing alloys by oxyfuel welding, various arc welding methods, laser welding, and thermal spray processes. It discusses the categories of hardfacing alloy, such as build-up alloys, metal-to-metal wear alloys, metal-to-earth abrasion alloys, tungsten carbides, and nonferrous alloys. A summary of the selection guide for hardfacing alloys is presented in a table. The article describes the procedures for stainless steel weld cladding and the factors influencing joint integrity in dissimilar metal joining. It concludes with a discussion on joining carbon and low-alloy steels to various dissimilar materials (both ferrous and nonferrous) by arc welding.

Submerged arc welding (SAW) is suited for applications involving long, continuous welds. This article describes the operating principle, application, advantages, limitations, power source, equipment, and fluxes in SAW. It reviews three different types of electrodes manufactured for SAW: solid, cored, and strip. The article highlights the factors to be considered for controlling the welding process, including fit-up of work, travel speed, and flux depth. It also evaluates the defects that occur in SAW: lack of fusion, slag entrapment, solidification cracking, and hydrogen cracking. Finally, the article provides information on the safety measures to be followed in this process.

This article describes the classification of fuel cells depending on the operating temperature and type of electrolytes used. This classification includes alkaline fuel cells, phosphoric acid fuel cells, polymer electrolyte membrane fuel cells (PEMFCs), molten carbonate fuel cells (MCFCs), and solid oxide fuel cells (SOFCs). The article explains the corrosion processes in fuel cells due to solid-gas interactions, solid-liquid interactions, and solid-solid interactions. It discusses the long-term performance stability and long-term degradation processes of PEMFCs, MCFCs, and SOFCs. The article reviews the development of chemically and structurally compatible component materials in PEMFCs, MCFCs, and SOFCs.

This article discusses factors involved in selecting welding processes and consumables and establishing procedures and practices for the arc welding of low-alloy steels. It provides information on welding consumables in terms of filler metals and fluxes and shielding gases. The article describes the various categories of low-alloy steels, such as high-strength low-alloy (HSLA) structural steels, high-strength low-alloy quenched and tempered(HSLA Q&T) structural steels, low-alloy steels for pressure vessels and piping, medium-carbon heat-treatable (quenched and tempered) low-alloy (HTLA) steels, ultrahigh-strength low-alloy steels, and low-alloy tool and die steels. It concludes with a discussion on repair practices for tools and dies.

Overpotential is the current-producing potential difference between a nonequilibrium electrode potential and its corresponding equilibrium value for an electrode reaction. This article provides information on the overpotential of an electrode reaction. It contains a table that lists the values based on the electrode reaction. Because overpotential is a kinetic parameter and depends on current density, overpotential values presented are for a specific current density.