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Image
Field metallography of a nickel aluminide austenitizing furnace roll. (a) a...
Available to PurchasePublished: 01 December 2004
Fig. 32 Field metallography of a nickel aluminide austenitizing furnace roll. (a) and (b) Gold-enhanced replicas representing the microstructure of a nickel aluminide austenitizing furnace roll. The dendritic microstructure consists of primary dendrite arm of nickel aluminide with small
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Image
Published: 01 January 2006
Image
Crack growth rates of nickel aluminide (Ni-23.5Al-0.5Hf-0.1B, at.%), LRO al...
Available to Purchase
in Ordered Intermetallics
> Properties and Selection: Nonferrous Alloys and Special-Purpose Materials
Published: 01 January 1990
Fig. 10 Crack growth rates of nickel aluminide (Ni-23.5Al-0.5Hf-0.1B, at.%), LRO alloys [(Fe, Ni) 3 (V,Ti)], and several high-temperature alloys tested in air at 25 °C (80 °F). Source: Ref 87
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Image
Crack growth rates of nickel aluminide (Ni-23.5Al-0.5Hf-0.1B, at.%), LRO al...
Available to PurchasePublished: 01 December 1998
Fig. 9 Crack growth rates of nickel aluminide (Ni-23.5Al-0.5Hf-0.1B, at.%), LRO alloys [(Fe,Ni) 3 (V,Ti)], and several high-temperature alloys tested in air at 25 °C (80 °F)
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Corrosion-mode diagram for nickel aluminide (Ni 3 Al) in aqueous solutions,...
Available to PurchasePublished: 01 January 2005
Fig. 26 Corrosion-mode diagram for nickel aluminide (Ni 3 Al) in aqueous solutions, as estimated from electrochemical experiments
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in Ordered Intermetallics
> Properties and Selection: Nonferrous Alloys and Special-Purpose Materials
Published: 01 January 1990
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Published: 01 December 1998
Book Chapter
Structural Intermetallics
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003164
EISBN: 978-1-62708-199-3
... melting points, and good high-temperature strength that make them an attractive material for high-temperature structural application. This article discusses the properties, chemical composition, corrosion resistance, processing, fabrication, alloying effects and crystallographic data of nickel aluminides...
Abstract
Alloys based on ordered intermetallic compounds constitute a unique class of metallic material that form long-range ordered crystal structures below a critical temperature. Aluminides, a unique class of ordered intermetallic materials, possesses many attributes like low densities, high melting points, and good high-temperature strength that make them an attractive material for high-temperature structural application. This article discusses the properties, chemical composition, corrosion resistance, processing, fabrication, alloying effects and crystallographic data of nickel aluminides (Ni3Al and NiAl), iron aluminides (Fe3Al and FeAl) and titanium aluminides (alpha-2 alloys, orthorhombic alloys, and gamma alloys).
Image
Comparison of the current density produced by dissolution of nickel and nic...
Available to PurchasePublished: 01 January 2005
Fig. 23 Comparison of the current density produced by dissolution of nickel and nickel aluminide in deaerated sulfuric acid. SCE, saturated calomel electrode
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Potential transients during and following the generation of fresh bare surf...
Available to PurchasePublished: 01 January 2005
Fig. 24 Potential transients during and following the generation of fresh bare surface by scratching of nickel, aluminum, and nickel aluminide in 0.5 mol/L NaCl, with the hydrogen evolution potential for this environment indicated SCE, saturated calomel electrode
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Image
Effects of fuel carbon residue (10% bottoms) on type II hot corrosion of ni...
Available to PurchasePublished: 01 January 2003
Fig. 21 Effects of fuel carbon residue (10% bottoms) on type II hot corrosion of nickel aluminide high-temperature coatings. Source: Ref 135
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Variation of yield strength with test temperature for selected nickel alumi...
Available to PurchasePublished: 01 December 1998
Fig. 5 Variation of yield strength with test temperature for selected nickel aluminide alloys. Strain rate, 0.5 mm/mm per min. See Table 3 for alloy compositions.
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Archetypical microstructures of aluminide coatings on a nickel superalloy. ...
Available to PurchasePublished: 01 January 1994
Fig. 3 Archetypical microstructures of aluminide coatings on a nickel superalloy. (a) Inward diffusion based on Ni 2 Al 3 (and aluminum-rich NiAl). (b) Same as (a) but heat treated at 1080 °C (1975 °F). (c) Outward diffusion of nickel in nickel-rich NiAl. (d) Inward diffusion of aluminum
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Book Chapter
Corrosion of Intermetallics
Available to PurchaseBook: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003837
EISBN: 978-1-62708-183-2
... nickel-rich and aluminum-rich sides of Ni 3 Al. This is quite different from B2-NiAl, where antisite defects are stable in the nickel-rich side and vacancies are formed in the aluminum-rich side. Oxidation In the oxidation of nickel aluminides, Al 2 O 3 grows in different modifications, depending...
Abstract
This article reviews the corrosion behavior of intermetallics for the modeling of the corrosion processes and for devising a strategy to create corrosion protective systems through alloy and coating design. Thermodynamic principles in the context of high-temperature corrosion and information on oxidation; sulfidation; hot corrosion of NiAl-, FeAl-, and TiAl-based intermetallics; and silicides are included. The article explores the thermodynamic consideration, ordering influencing kinetics, stress-cracking corrosion, and hydrogen embrittlement of aqueous corrosion. It also explains the practical issues dealing with the corrosion problems.
Book Chapter
Ordered Intermetallics
Available to PurchaseSeries: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001102
EISBN: 978-1-62708-162-7
... and metallurgical properties, material processing and fabrication, structural applications, mechanical behavior, environmental embrittlement, alloying effects, and crystal structure of aluminides of nickel, iron, titanium, and silicides. It describes the cleavage and intergranular fracture in trialuminides...
Abstract
Ordered intermetallic compounds based on aluminides and silicides constitute a unique class of metallic materials that have promising physical and mechanical properties for structural applications at elevated temperatures. This article provides useful information on mechanical and metallurgical properties, material processing and fabrication, structural applications, mechanical behavior, environmental embrittlement, alloying effects, and crystal structure of aluminides of nickel, iron, titanium, and silicides. It describes the cleavage and intergranular fracture in trialuminides.
Book Chapter
Corrosion of Industrial Gas Turbines
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004158
EISBN: 978-1-62708-184-9
... in the coating. If there is free sulfur in the coating, it migrates to the oxide-coating interface, weakening this interface, and increasing the amount of oxide spalling. Diffusion aluminide coatings are nickel aluminide (NiAl) and cobalt aluminide (CoAl). NiAl forms on nickel-base superalloys and CoAl forms...
Abstract
The corrosion issues in the compressor, combustor and turbine sections of industrial gas turbines used in steam production generally depend on the quality of the fuel, air, and water used in the engine than on the specific industrial application. This article focuses on the forms of corrosion and their preventive measures in the compressor, combustor and turbine sections of a steam turbine. The compressor section mainly suffers from aqueous corrosion; while in case of the combustor and turbine sections, which are made of nickel-base superalloys, high-temperature environmental attack in the form of high-temperature oxidation and hot corrosion are predominant. The effect of high-temperature oxidation and hot corrosion on the mechanical properties of superalloys is also discussed.
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0004001
EISBN: 978-1-62708-185-6
... of manufacturing methods in the context of processing-cost trade-offs for gamma titanium aluminide alloys are also discussed. Iron-, Nickel-, Niobium-, and Molybdenum-Base Intermetallic Alloys This section reviews the status of the bulk forming of some of the more common aluminide and silicide systems...
Abstract
This article reviews the bulk deformation processes for various aluminide and silicide intermetallic alloys with emphasis on the gamma titanium aluminide alloys. It summarizes the understanding of microstructure evolution and fracture behavior during thermomechanical processing of the gamma aluminides with particular reference to production scaleable techniques, including vacuum arc and cold-hearth melting, isothermal forging, conventional hot forging, and extrusion. The selection and design of manufacturing methods, in the context of processing-cost trade-offs for gamma titanium aluminide alloys, are also discussed.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001101
EISBN: 978-1-62708-162-7
...-performance carbon, metallic, or ceramic additions. Reinforced intermetallic compounds such as the aluminides of titanium, nickel, and iron are also discussed in this article (for more information on intermetallic compounds, see the article “Ordered Intermetallics” in this Volume). Reinforcements...
Abstract
Metal-matrix composites (MMCs) are a class of materials with potential for a wide variety of structural and thermal management applications. They are nonflammable, do not outgas in a vacuum, and suffer minimal attack by organic fluids, such as fuels and solvents. This article presents an overview of the status of MMCs, and provides information on physical and mechanical properties, processing methods, distinctive features, and various types of continuously and discontinuously reinforced aluminum, magnesium, titanium, copper, superalloy, and intermetallic-matrix composites. It further discusses the property prediction and processing methods for MMCs.
Image
Electrochemical equilibrium diagram for nickel and aluminum showing the inf...
Available to PurchasePublished: 01 January 2005
Fig. 22 Electrochemical equilibrium diagram for nickel and aluminum showing the influence of L1 2 ordering (Ni 3 Al) on nickel and aluminum dissolution and passivation reactions. The potential ranges for the aluminide correspond to the aluminum concentration range from 0.2 to 0.3 mol fraction
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Book Chapter
High-Temperature Corrosion-Related Failures
Available to PurchaseSeries: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003555
EISBN: 978-1-62708-180-1
... and metal dusting, sulfidation, hot corrosion, chloridation, hydrogen interactions, molten metals, molten salts, and aging reactions including sensitization, stress-corrosion cracking, and corrosion fatigue. It concludes with a discussion on various protective coatings, such as aluminide coatings, overlay...
Abstract
High temperature corrosion may occur in numerous environments and is affected by factors such as temperature, alloy or protective coating composition, time, and gas composition. This article explains a number of potential degradation processes, namely, oxidation, carburization and metal dusting, sulfidation, hot corrosion, chloridation, hydrogen interactions, molten metals, molten salts, and aging reactions including sensitization, stress-corrosion cracking, and corrosion fatigue. It concludes with a discussion on various protective coatings, such as aluminide coatings, overlay coatings, thermal barrier coatings, and ceramic coatings.
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