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morphological stability
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Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005209
EISBN: 978-1-62708-187-0
... build-up at the solid-liquid interface forming transients and steady state, the morphological stability/instability and perturbation theory, and rapid solidification effects, including solute trapping and oscillatory instabilities. The article presents a microstructural selection map that presents...
Abstract
One impressive example of plane front solidification (PFS) is the industrial production of large silicon single crystals, used mainly as substrates for integrated circuits. This article explores the PFS of a single phase, without taking convection into account. It discusses the solute build-up at the solid-liquid interface forming transients and steady state, the morphological stability/instability and perturbation theory, and rapid solidification effects, including solute trapping and oscillatory instabilities. The article presents a microstructural selection map that presents an overview of interface stability as a function of composition for a given alloy.
Image
Published: 01 December 2008
Fig. 8 Stability diagrams for an Al-1at.%Fe alloy as a function of growth rate, V , ( G = 5 × 10 6 K/m). Source: Ref 28 . (a) Composition dependence of morphological and oscillatory instabilities showing complete morphological stability below 5 × 10 −3 at.%. Source: Ref 23 . (b
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Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005226
EISBN: 978-1-62708-187-0
... before the liquid cools to the glass transition temperature. Glass formation is more likely in (b). Diffusional Kinetics/Microsegregation Morphological Stability The avoidance of constitutional supercooling for dilute alloys by solidification at slow velocity and high thermal gradients...
Abstract
Rapid solidification is a tool for modifying the microstructure of alloys that are obtained by ordinary casting. This article describes the fundamentals of the four microstructural changes, namely, microsegregation, identity of the primary phase, identity of the secondary phase, and the formation of noncrystalline phases. It considers three factors to understand the fundamentals of these changes: heat flow, thermodynamic constraints/conditions at the liquid-solid interfaces, and diffusional kinetics/microsegregation. These factors are described in detail.
Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006270
EISBN: 978-1-62708-169-6
... alloys: Two-phase alloys that can be strengthened to some extent by heat treatment, depending on the amount of alloying elements that stabilize the beta phase. Alpha-beta titanium alloys are the most versatile of the three types of titanium alloys, with phase compositions, sizes, and distributions...
Abstract
The response of titanium and titanium alloys to heat treatment depends on the composition of the metal, the effects of the alloying elements on the alpha-beta crystal transformation, and the thermomechanical processing utilized during processing of the alloy. This article provides a detailed discussion on the effects of heat treatment on the mechanical properties for three general classes of titanium alloys, namely, alpha and near-alpha titanium alloys, alpha-beta alloys, and beta alloys.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001286
EISBN: 978-1-62708-170-2
... generates pinholes in the deposited film. Surface morphology —affects the angle-of-incidence of the depositing atoms and thus the film growth. Geometrical shadowing of the surface from the depositing adatom flux reduces surface coverage. Surface morphology can affect the film properties and stability...
Abstract
This article describes eight stages of the atomistic film growth: vaporization of the material, transport of the material to the substrate, condensation and nucleation of the atoms, nuclei growth, interface formation, film growth, changes in structure during the deposition, and postdeposition changes. It also discusses the effects and causes of growth-related properties of films deposited by physical vapor deposition processes, including residual film stress, density, and adhesion.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005230
EISBN: 978-1-62708-187-0
.... In this article, the discussion is limited to heat treatment of cast alloys. The choice of heat treatment depends on various factors, such as application, dimensional and microstructural stability, mechanical properties, sensitivity to environmental degradation, and so on. A typical heat treatment regimen...
Abstract
This article provides an overview of heat treatment processes, namely, solution heat treatment, quenching, natural aging, and artificial aging. It contains a table that lists the various heat treatment tempers commonly practiced for nonferrous castings. The article describes microstructural changes that occur due to the heat treatment of cast alloys.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003728
EISBN: 978-1-62708-177-1
... of using heat treatment. Titanium is a transition metal with an incomplete d shell in its electronic structure, which enables it to form solid solutions with most substitutional elements having a size factor within ±20%. Alloying of titanium is dominated by the ability of elements to stabilize either...
Abstract
This article describes the development of heat-resistant titanium-base alloys and their classification into several microstructure categories based on their strengthening mechanisms. It explains the phase transformation in titanium-aluminum-base alloys and two peritectic reactions that take place in the titanium-aluminum system. The article also describes two approaches for controlling the orientation of the high-temperature alpha phase to achieve the required lamellar orientation by directional solidification in order to improve the strength and ductility of titanium-aluminum alloys. One approach is by seeding the alpha phase in the alloys, and the other is without seeding, by controlling the solidification path of alloys through appropriate alloying. The article discusses the grain refinement technique used to improve the ductility of cast titanium-aluminum alloys to a level of above 1" at room temperature and reasonable room temperature ductility in the as-cast condition. Finally, it provides information on the microstructures produced through various near-net shape manufacturing processes.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003358
EISBN: 978-1-62708-195-5
... Abstract This article focuses on the production of particulate reinforcements that are used in discontinuously reinforced metal-matrix composite (DRMMC) materials systems, their physical and materials properties, and the particle shape and overall morphology. The most common DRMMC materials...
Abstract
This article focuses on the production of particulate reinforcements that are used in discontinuously reinforced metal-matrix composite (DRMMC) materials systems, their physical and materials properties, and the particle shape and overall morphology. The most common DRMMC materials systems used for aerospace structural applications are silicon carbide and boron carbide particulate reinforcement in an aluminum alloy matrix. The article concludes with information on reinforcement chemistry for designing DRMMC materials systems.
Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006274
EISBN: 978-1-62708-169-6
... “Principles of Heat Treating of Nonferrous Alloys” in this Volume). In addition, not all precipitation or transformation processes are necessarily associated with an appreciable strengthening. Heat treatment can induce solid-state phase changes for other reasons, such as stabilization of part dimensions...
Abstract
This article describes the different types of precipitation and transformation processes and their effects that can occur during heat treatment of various nonferrous alloys. The nonferrous alloys are aluminum alloys, copper alloys, magnesium alloys, nickel alloys, titanium alloys, cobalt alloys, zinc alloys, and heat treatable silver alloys, gold alloys, lead alloys, and tin alloys. It also provides a detailed discussion on the effects due to precipitation and transformation processes in these non-ferrous alloys.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005210
EISBN: 978-1-62708-187-0
... and solute are rejected into the liquid so that negative temperature and concentration gradients are present in the liquid at the solid/liquid interface. As discussed by Kurz in the previous article, “Plane Front Solidification,” in this Volume, the stability of the interface at low velocity is controlled...
Abstract
Nonplanar microstructures form most frequently during the solidification of alloys, and play a crucial role in governing the properties of the solidified material. This article emphasizes the basic ideas, characteristic lengths, and the processing conditions required to control the columnar and equiaxed microstructures. The formation of cellular and dendritic structures in one- and two-phase structures is presented with emphasis on the effect of processing conditions and composition on the selection of microstructure and microstructure scales.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003012
EISBN: 978-1-62708-200-6
... Abstract Additives for plastics and elastomers are used to increase the ease of processing and to improve the properties of the final product. Additives improve processing characteristics by increasing lubricity and by stabilizing the polymer. Additives that improve properties include those...
Abstract
Additives for plastics and elastomers are used to increase the ease of processing and to improve the properties of the final product. Additives improve processing characteristics by increasing lubricity and by stabilizing the polymer. Additives that improve properties include those that decrease static charge development and microbial activity and those that improve flame retardation characteristics, color, light stability, impact resistance, density and mechanical properties. This article focuses on the additives for polymers and elastomers that are used for improving processing--blowing agents, mold-release agents, lubricants, plasticizers, and heat stabilizers--and for improving properties antimicrobials, antioxidants, antistatic agents, colorants, fillers and fiber reinforcements, flame retardants, impact modifiers, light stabilizers, plasticizers, and heat stabilizers. Furthermore, it discusses the method for addition of these additives and the problems faced during compounding.
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006884
EISBN: 978-1-62708-392-8
... occurs by the formation of hydroxyapatite. Dicalcium phosphate consists of crystal water along with anhydrous and dihydrate salts. This article summarizes research achievements regarding dicalcium phosphate dihydrate (DCPD) production with controlled morphology and reactivity, including effects...
Abstract
Calcium phosphates react to form more stable salts in aqueous solutions. This phenomenon has been applied to the solidification process for the dental and medical cement calcium phosphate cement, which consists of multiple phases of calcium phosphates and calcium salts; solidification occurs by the formation of hydroxyapatite. Dicalcium phosphate consists of crystal water along with anhydrous and dihydrate salts. This article summarizes research achievements regarding dicalcium phosphate dihydrate (DCPD) production with controlled morphology and reactivity, including effects of an additive and of production conditions on precipitation. It also summarizes achievements made in the hybridization of nano-apatite onto DCPD particles.
Book Chapter
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006673
EISBN: 978-1-62708-213-6
... of temperature or time in a controlled atmosphere. The weight of the evaluated material can decrease due to volatilization or decomposition or increase because of gas absorption or chemical reaction. Thermogravimetric analysis can provide valuable information regarding the composition and thermal stability...
Abstract
Thermogravimetric analysis (TGA) is a thermal analysis technique that measures the amount and rate of change in the weight of a material as a function of temperature or time in a controlled atmosphere. This article provides a detailed account of the concepts of TGA, covering the various criteria to be considered for specimen preparation and calibration of TGAs. The use of thermogravimetric analysis data in the assessment of failure analysis of plastics and the combined usage of TGA with other techniques to understand the changes in the sample are also covered. The article provides examples of applications and provides information on the interpretation of TGA.
Book Chapter
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003736
EISBN: 978-1-62708-177-1
... Abstract Martensite is a metastable structure that forms during athermal (nonisothermal) conditions. This article reviews the crystallographic theory, morphologies, orientation relationships, habit plane, and transformation temperature of ferrous martensite microstructures. It examines...
Abstract
Martensite is a metastable structure that forms during athermal (nonisothermal) conditions. This article reviews the crystallographic theory, morphologies, orientation relationships, habit plane, and transformation temperature of ferrous martensite microstructures. It examines the stages of the tempering process involved in