This article discusses various molten-metal treatments, namely fluxing, degassing, and molten-metal filtration. It focuses on various molten-metal handling systems for transporting, holding, or delivering molten metal to the mold/die system. These include launders, tundishes, holding furnaces or transport crucibles, molten-metal transfer pumps, teeming ladles, and dosing and pouring furnaces.

This article reviews the production stages of iron foundry casting, with particular emphasis on the melting practices, molten metal treatment, and feeding of molten metal into sand molds. It discusses the molten metal treatments for high-silicon gray, high-nickel ductile, and malleable irons. Foundry practices are also described for compacted graphite, high-silicon ductile, and high-alloy white irons.

Foundry practices critical to the production of cast irons include melting, alloying, molten metal treatment, pouring, and the design of feeding systems (gating and risering) to allow proper filling of the casting mold. This article reviews these production stages of iron foundry casting, with particular emphasis on the melting practices, molten metal treatment, and feeding of molten metal into sand molds. It discusses the castability factors, such as fluidity, shrinkage, and resistance, of gray iron. Typical cupola charge compositions and the final analyses for class 30 and class 40 gray iron castings are presented in a table. The article describes the induction melting and arc furnace melting used in gray iron foundries. It also reviews the inoculation methods such as stream inoculation and mold inoculation, of gray iron.

The melting process often includes refining and treating the metal. The choice of which type of melting to use depends on a number of factors: type of alloy being melted, the local cost of electric power, and local environmental regulations. This article discusses the principles, furnace types, charging practices of metal melting methods, namely induction melting, cupola melting, arc melting, crucible melting, reaction melting, and vacuum melting, and the refractories and charging practice of reverberatory furnaces. Molten metal treatment of steels and aluminum also is discussed in the article.

There are a wide variety of furnace types and designs for melting aluminum. This article discusses the various types of furnaces, including gas reverberatory furnaces, crucible furnaces, and induction melting furnaces. It describes the classification of solid fluxes: cover fluxes, drossing fluxes, cleaning fluxes, and furnace wall cleaner fluxes. The article reviews the basic considerations in proper flux selection and fluxing practices. It explains the basic principles of degassing and discusses the degassing of wrought aluminum alloys. The article describes filtration in wrought aluminum production and in shape casting. It also reviews grain refinement in aluminum-silicon casting alloys, aluminum-silicon-copper casting alloys, aluminum-copper casting alloys, aluminum-zinc-magnesium casting alloys, and aluminum-magnesium casting alloys. The article concludes with a discussion on aluminum-silicon modification.

Aluminum fluxing is a step in obtaining clean molten metal by preventing excessive oxide formation, removing nonmetallic inclusions from the melt, and preventing and/or removing oxide buildup on furnace walls. This article discusses the solid fluxes and gas fluxes used in foundries. It reviews the classification of solid fluxes depending on their use and function at the foundry operation. These include cover fluxes, drossing fluxes, cleaning fluxes, and furnace wall cleaner fluxes. The article also examines the operational practices and applications of the flux injection in the foundries. It describes the applications of the aluminum fluxing such as crucible furnaces, transfer ladles, reverberatory furnaces, and holding/casting furnaces.

Interplays of metallurgical factors, such as dissolved oxygen, carbon, and silicon content, that control the molten metal from melting to pouring, have a decisive influence on the quality of the castings. This article focuses on the magnesium treatment and desulfurization carried out during inoculation and nucleation of molten cast iron, assisting in the formation of cast iron. The different types of cast irons are gray cast iron, nodular cast iron, compacted graphite iron, malleable cast iron, and alloyed cast iron. The article provides an overview of the melt treatment processes carried out in cast steel, wrought and cast aluminum, and copper materials.

Molten salt baths are anhydrous, fused chemical baths used at elevated temperatures for a variety of industrial cleaning applications. This article discusses their applications in paint stripping, polymer removal, casting cleaning, glass removal, and plasma/flame spray removal. It provides an overview of the basic design and safety considerations of the salt bath equipment and describes the environmental impact of molten salt bath cleaning.

Dross, which is the oxide-rich surface that forms on melts due to exposure to air, is a term that is usually applied to nonferrous melts, specifically the lighter alloys such as aluminum or magnesium. This article describes dross formation and ways to reduce it, the economic implications of dross, and in-plant enhancement or recovery of dross. It discusses the influence of the melter type on dross generation and the influence of charge materials and operating practices on melt loss. Fluxing is a word applied in a broad sense to a number of melt-treating methods. The article also discusses the in-furnace treatment with chemical fluxes.

The use of gases or molten salts as the quenchant for steel parts is commonly limited to the quenching of high-alloy steel or the carbonizing quenching of low-alloy steel. This article reviews the quenching process of steels with molten metals (quenchant) such as molten lead, molten bismuth, and molten sodium. It also contains tables that list the physical properties of lead, bismuth, sodium, and molten sodium.

Although stainless steel is naturally passivated by exposure to air and other oxidizers, additional surface treatments are needed to prevent corrosion. Passivation, pickling, electropolishing, and mechanical cleaning are important surface treatments for the successful performance of stainless steel. This article describes the surface treatment of stainless steels including abrasive blast cleaning, acid pickling, salt bath descaling, passivation treatments, electropolishing, and the necessary coating processes involved. It also describes the surface treatment of heat-resistant alloys including metallic contaminant removal, tarnish removal, oxide and scale removal, finishing, and coating processes.

Cast iron, which usually refers to an in situ composite of stable eutectic graphite in a steel matrix, includes the major classifications of gray iron, ductile iron, compacted graphite iron, malleable iron, and white iron. This article discusses melting, pouring, desulfurization, inoculation, alloying, and melt treatment of these major ferrous alloys as well as carbon and alloy steels. It explains the principles of solidification by describing the iron-carbon phase diagram, and provides a pictorial presentation of the basic microstructures and processing steps for cast irons.

Ingot casting is the vital conduit between molten metal provided by primary production and recycling and the manufacture of aluminum and aluminum alloy products. A number of ingot casting processes have been developed to ensure the soundness, integrity, and homogeneity required by downstream manufacturing processes. This article starts with a review of the different forms of ingot and the molten-metal processing techniques involved in ingot casting. It then describes the open-mold casting and direct chill (DC) ingot casting processes. The process variations and solidification in the DC process are summarized. The article explains continuous processes, namely, twin-roll strip casting, slab casting, and wheel-belt processes. It concludes with information on postsolidification processes, including stress relief and scalping, and a discussion of safety practices for ingot casting.

Aluminum casting alloys are the most versatile of all common foundry alloys and generally have the highest castability ratings. This article provides an overview of the common methods of aluminum shape casting. These include gravity casting, die casting, sand casting, lost foam casting, shell mold casting, plaster casting, investment casting, permanent mold casting, squeeze casting, semisolid forming, centrifugal casting, and pressure die casting. The article presents several different factors on which the selection of a casting process depends. It discusses gating and risering principles in casting. The article concludes with information on premium engineered castings that provide higher levels of quality and reliability than in conventionally produced castings.

Ingot casting is the vital conduit between molten metal provided by primary production and recycling, and the manufacture of aluminum and aluminum alloy products. This article discusses various ingot forms, such as remelt ingot, billets, ingots for rolling, fabricating ingot, and particle ingot and powder. It describes the molten metal processing and ingot casting process in terms of open-mold casting and direct chill process. The article examines the continuous processes that provide commercial alternatives to conventional ingot casting. It reviews the postsolidification processes in terms of stress relief, homogenization, and scalping. The article concludes with a discussion on safety limited to ingot casting.

This article discusses the types of squeeze-casting machines and the advantages of squeeze casting. It examines the considerations required for the casting and tooling design process of squeeze-casting. The article describes the various factors that affect the squeeze-cast products and outlines a few of the key process characteristics. It provides information on the applications of squeeze-cast and contains a table that compares the tensile, hardness, and impact properties of select squeeze-cast aluminum alloys with those obtained from conventional casting processes.

Unlike gray iron, which contains graphite flakes, ductile iron has an as-cast structure containing graphite particles in the form of small, rounded, spheroidal nodules in a ductile metallic matrix. This article discusses the raw materials that are used for ductile iron production and outlines the most common and important requirements for controlling the composition of ductile iron. Treatment to produce ductile iron involves the addition of magnesium to change the form of the graphite, followed by or combined with inoculation of a silicon-containing material to ensure a graphitic structure with freedom from carbides. The article describes the methods of magnesium treatment, control of magnesium content, and inoculation. It concludes with a discussion on the metallurgical controls of ductile iron production.

This article provides an overview of exogenous and indigenous inclusions. It discusses the general concepts of phase diagrams, thermochemical relationships, and reaction rates, along with their practical significance. The article describes the most common techniques for controlling the occurrence of inclusions in any cast metal. It presents a discussion on the inclusions in ferrous and nonferrous alloys, including steels, cast irons, aluminum alloys, copper alloys, and magnesium alloys.

Heat treatment of depleted uranium (DU) alloys with 4.0 wt% or more molybdenum or equivalent is similar to that of dilute alloys. This article discusses the metallurgical characteristics and processing considerations of DU and its alloys, and describes the control of grain size and orientation using beta treatment. It lists the typical mechanical properties of DU as functions of the amount of cold work and hardness data of uranium rod, and describes the annealing of cold-worked DU. The article also describes the heat treatment of dilute alloys of DU, focusing on the three basic furnace designs used for heating or heat treating of unalloyed uranium: molten salt baths, inert-atmosphere furnaces, and vacuum furnaces. Finally, it presents procedures that are examples of heat treatment used to meet certain specifications of ultimate tensile strength, yield strength, and elongation.