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Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005215
EISBN: 978-1-62708-187-0
... parameters that control microsegregation are discussed in relation to the manifestations of microsegregation in simple and then increasingly complex alloy systems. The measurement and kinetics of microsegregation are discussed for the binary isomorphous systems: titanium-molybdenum; binary eutectic systems...
Abstract
This article discusses the two extremes of solute redistribution, equilibrium solidification and nonequilibrium Gulliver-Scheil solidification, for which solid redistribution of solute within the primary solid phase is the distinguishing parameter. The process and material parameters that control microsegregation are discussed in relation to the manifestations of microsegregation in simple and then increasingly complex alloy systems. The measurement and kinetics of microsegregation are discussed for the binary isomorphous systems: titanium-molybdenum; binary eutectic systems: aluminum-copper and aluminum-silicon; binary peritectic systems: copper-zinc; multicomponent eutectic systems: Al-Si-Cu-Mg; and for systems with both eutectic and peritectic reactions: Fe-C-Cr and nickel-base superalloy.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005237
EISBN: 978-1-62708-187-0
...Abstract Abstract In order to model macrosegregation, one must consider convection and the partitioning of segregating elements at the dendritic length scale. This article describes microsegregation with diffusion in the solid. It presents a continuum model of macrosegregation and illustrates...
Abstract
In order to model macrosegregation, one must consider convection and the partitioning of segregating elements at the dendritic length scale. This article describes microsegregation with diffusion in the solid. It presents a continuum model of macrosegregation and illustrates the simulation of macrosegregation and microsegregation.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005229
EISBN: 978-1-62708-187-0
... distribution during subsequent aging. The article provides a schematic illustration of an energy-dispersive X-ray spectroscope (EDS) scattered data of solute distributions across a dendrite due to microsegregation of chromium and molybdenum. It concludes with information on the computational modeling...
Abstract
Homogenization, in a broad sense, refers to the processes designed to achieve uniform distribution of solutes or phases in a given matrix. This article addresses the root cause for inhomogeneities in cast components. It is nearly a standard industrial practice to homogenize alloys before thermomechanical processing. The article lists the objectives of homogenization and benefits of homogenization treatments. The benefits include increased resistance to pitting corrosion, increased resistance to stress-corrosion cracking, improved ductility, and uniform precipitate distribution during subsequent aging. The article provides a schematic illustration of an energy-dispersive X-ray spectroscope (EDS) scattered data of solute distributions across a dendrite due to microsegregation of chromium and molybdenum. It concludes with information on the computational modeling for simulation of microsegregation of chromium and molybdenum.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005226
EISBN: 978-1-62708-187-0
...Abstract Abstract Rapid solidification is a tool for modifying the microstructure of alloys that are obtained by ordinary casting. This article describes the fundamentals of the four microstructural changes, namely, microsegregation, identity of the primary phase, identity of the secondary...
Abstract
Rapid solidification is a tool for modifying the microstructure of alloys that are obtained by ordinary casting. This article describes the fundamentals of the four microstructural changes, namely, microsegregation, identity of the primary phase, identity of the secondary phase, and the formation of noncrystalline phases. It considers three factors to understand the fundamentals of these changes: heat flow, thermodynamic constraints/conditions at the liquid-solid interfaces, and diffusional kinetics/microsegregation. These factors are described in detail.
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006496
EISBN: 978-1-62708-207-5
... the castability of the alloy. The article describes the two types of segregation, namely, microsegregation and macrosegregation. It discusses the effect of freezing range on castability of an alloy. The article lists the freezing range of a number of important alloys. It concludes with a discussion on castability...
Abstract
Castability is a complex characteristic that depends on both the intrinsic fluid properties of the molten metal and the manner in which the particular alloy solidifies. This article discusses the practical aspects of solidification important to aluminum foundrymen. The primary focus is on the chemical segregation that occurs during freezing, because it determines the castability of the alloy. The article describes the two types of segregation, namely, microsegregation and macrosegregation. It discusses the effect of freezing range on castability of an alloy. The article lists the freezing range of a number of important alloys. It concludes with a discussion on castability of 2xx, 3xx, 4xx, 5xx, and 7xx alloys.
Series: ASM Handbook
Volume: 4B
Publisher: ASM International
Published: 30 September 2014
DOI: 10.31399/asm.hb.v04b.a0005967
EISBN: 978-1-62708-166-5
.... The article illustrates the use of carbon restoration on decarburized spring steels. Different geometric models for carbide formation are shown schematically. The article also describes the different microstructural features such as grain size, microcracks, microsegregation, and banding. carbides...
Abstract
Of the various thermal processing methods for steel, heat treating has the greatest overall impact on control of residual stress and on dimensional control. This article provides an overview of the effects of material- and process-related parameters on the various types of failures observed during and after heat treating of quenched and tempered steels. It describes phase transformations of steels during heating, cooling of steel with and without metallurgical transformation, and the formation of high-temperature transformation products on the surface of a carburized part. The article illustrates the use of carbon restoration on decarburized spring steels. Different geometric models for carbide formation are shown schematically. The article also describes the different microstructural features such as grain size, microcracks, microsegregation, and banding.
Series: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005420
EISBN: 978-1-62708-196-2
...Abstract Abstract This article focuses on the concepts involved in heat-transfer modeling, thermomechanical modeling, and microsegregation modeling of hot tearing. It discusses the modeling of solidification defects, namely, inclusion entrapment, segregation, shrinkage cavities, gas porosity...
Abstract
This article focuses on the concepts involved in heat-transfer modeling, thermomechanical modeling, and microsegregation modeling of hot tearing. It discusses the modeling of solidification defects, namely, inclusion entrapment, segregation, shrinkage cavities, gas porosity, mold-wall erosion, and hot-tear cracks.
Series: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005437
EISBN: 978-1-62708-196-2
... example problems that illustrate how the hierarchy of time and length scales associated with transport leads to the important features of cast microstructures. It includes equations for estimating microsegregation in cast alloys. solidification microstructure microsegregation cast alloys...
Abstract
This article presents the governing equations for moving a solidification front, based on the balance of mass, momentum, energy, and solute. It reviews how material properties and geometry can be analyzed in the context of the governing equations. The article provides several example problems that illustrate how the hierarchy of time and length scales associated with transport leads to the important features of cast microstructures. It includes equations for estimating microsegregation in cast alloys.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003727
EISBN: 978-1-62708-177-1
...Abstract Abstract The most common aluminum alloy systems are aluminum-silicon, aluminum-copper, and aluminum-magnesium. This article focuses on the grain structure, eutectic microstructure, and dendritic microstructure of these systems. It provides information on microsegregation and its...
Abstract
The most common aluminum alloy systems are aluminum-silicon, aluminum-copper, and aluminum-magnesium. This article focuses on the grain structure, eutectic microstructure, and dendritic microstructure of these systems. It provides information on microsegregation and its problems in casting of alloys. The article also illustrates the casting defects such as macroporosity, microshrinkage, and surface defects, associated with the alloys.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005210
EISBN: 978-1-62708-187-0
... to control the columnar and equiaxed microstructures. The formation of cellular and dendritic structures in one- and two-phase structures is presented with emphasis on the effect of processing conditions and composition on the selection of microstructure and microstructure scales. microsegregation...
Abstract
Nonplanar microstructures form most frequently during the solidification of alloys, and play a crucial role in governing the properties of the solidified material. This article emphasizes the basic ideas, characteristic lengths, and the processing conditions required to control the columnar and equiaxed microstructures. The formation of cellular and dendritic structures in one- and two-phase structures is presented with emphasis on the effect of processing conditions and composition on the selection of microstructure and microstructure scales.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005208
EISBN: 978-1-62708-187-0
... of the application of transport phenomena in solidification, focusing on microstructure formation. casting energy mass microsegregation microstructure momentum solidification atomic dimensions macroscopic casting size casting solidification Fundamentals Some of the most important tools...
Abstract
This article begins with balance equations for mass, momentum, energy, and solute and the necessary boundary conditions for solving problems of interest in casting and solidification. The transport phenomena cover a vast range of length and time scales, from atomic dimensions up to macroscopic casting size and from nanoseconds for interface attachment kinetics to hours for casting solidification. The article describes how to determine which phenomena are most important at the particular length and time scale for the problem. It concludes with several examples of the application of transport phenomena in solidification, focusing on microstructure formation.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005225
EISBN: 978-1-62708-187-0
... casting process as a function of axial distance from the point of droplet atomization. The article concludes with information on the occurrence of macrosegregation and coarsening in spray cast preforms. coarsening gas atomization macrosegregation microsegregation spray casting probability...
Abstract
Spray casting, also known as spray forming, is a niche casting process for the manufacture of preforms. This article lists commercial examples of alloys manufactured by spray casting and provides sequential steps of the spray casting process. Gas atomization is a chaotic, stochastic process that always produces a wide range of droplet diameters. The article schematically illustrates a typical log-normal droplet diameter probability density distribution on a mass or volume basis obtained by gas atomization. It also explains the changes in solid fraction during the spray casting process as a function of axial distance from the point of droplet atomization. The article concludes with information on the occurrence of macrosegregation and coarsening in spray cast preforms.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005236
EISBN: 978-1-62708-187-0
... cellular automaton method grain growth grain structure microsegregation microstructure nucleation phase field method direct modeling structure formation intermediate length scales MODELING OF STRUCTURE FORMATION in casting of alloys involves several length scales, ranging from the atomic...
Abstract
Modeling of structure formation in casting of alloys involves several length scales, ranging from the atomic level to macroscopic scale. Intermediate length scales are used to define the microstructure of the growing phases and the grain structure. This article discusses the principles and applications of the phase field method and the cellular automaton method for modeling the direct evolution of structure at the intermediate length scales, where transport phenomena govern the spatial and temporal evolution of the structure that involves nucleation and growth.
Series: ASM Handbook
Volume: 22B
Publisher: ASM International
Published: 01 November 2010
DOI: 10.31399/asm.hb.v22b.a0005511
EISBN: 978-1-62708-197-9
... to predict the microstructural evolution in a Ni-Al-Cr γ+β/γ diffusion couple. Finally, in example 8, thermodynamic modeling is integrated with a microscopic and cellular automaton model to simulate the microstructure and microsegregation of aluminum alloys during solidification. Example 5: Prediction...
Abstract
This article focuses on the industrial applications of phase diagrams. It presents examples to illustrate how a multicomponent phase diagram calculation can be readily useful for industrial applications. The article demonstrates how the integration of a phase diagram calculation with kinetic and microstructural evolution models greatly enhances the power of the CALPHAD approach in materials design and processing development. It also discusses the limitations of the CALPHAD approach.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003724
EISBN: 978-1-62708-177-1
... and solid grains), and solid. Mechanical properties are affected by the solidification structure at the mesoscale level, which is described by features such as grain size and type (columnar or equiaxed), the type and concentration of chemical microsegregation, and the amount of microshrinkage, porosity...
Abstract
This article provides information on four different length scales at which surface morphology can be viewed: macro, meso, micro and nanoscale. Elementary thermodynamics demonstrates that a liquid cannot solidify unless some undercooling below the equilibrium (melting) temperature occurs. The article details five types of solidification undercooling, namely, kinetic, thermal, constitutional (solutal), curvature, and pressure undercooling. It explains the types of nucleation which occur in the melt during solidification. The effects of local instabilities at the solid/liquid interface during growth are illustrated. The article also describes the solidification structures of pure metals, solid solutions, eutectics, peritectics, and monotectics.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005227
EISBN: 978-1-62708-187-0
... to form the bulk of the matrix. The solidification microstructure of the matrix is refined and modified due to the presence of fibers and/or particles, providing a possible means of controlling solute microsegregation within the microstructure, macrosegregation of reinforcements in the casting...
Abstract
This article discusses the solidification of a matrix alloy in cast metal matrix composites (MMCs). It begins with a discussion on the mixing techniques in reinforcement incorporation and wettability of reinforcement. It describes the solidification processes, such as stir mixing and melt infiltration, used in the synthesis of MMCs. The article also considers the fundamentals of the process and presents a computational modeling of particle/solidification front interactions in metal-ceramic systems. The article concludes with information on nanocomposites.
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005589
EISBN: 978-1-62708-174-0
... resistance to corrosion in a wide variety of aqueous media. However, the corrosion resistance of the weld can often be inferior to that of the base metal due to microsegregation of molybdenum ( Ref 13 ). The microsegregation leaves the dendrite cores depleted in molybdenum, rendering them susceptible...
Abstract
Dissimilar metal welding applications require careful control over the welding parameters and corresponding dilution level in order to produce welds with proper microstructure and properties for the intended service. This article reviews the relation between the dilution and bulk fusion-zone compositions and describes the effect of fusion welding parameters on dilution. It also provides typical examples of the microstructure and property control in dissimilar weld applications.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006319
EISBN: 978-1-62708-179-5
... in this case. These areas are composed of austenite partly transformed into martensite. Such austenite is usually referred to as unreacted austenite. It is caused by the microsegregation of alloying elements. As in the case of steels, alloying elements are added to cast irons to control the final...
Abstract
The transformation of austenite of cast irons represents a more complex and less studied subject. This article discusses the general features of the decomposition of austenite into bainite. It describes the heat treatment cycles of austempered cast iron microstructure. The article reviews several factors, such as presence of graphite and austenite grain size, which affect the transformation rate of austenite during austempering of free-graphite cast irons.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005234
EISBN: 978-1-62708-187-0
... concentration nodal fields. In the general case, where macrosegregation is important (see the article in this volume “Modeling of Microsegregation and Macrosegregation” ), this calculation could involve intricate calculations to couple thermal and species trations through the phase diagram ( Ref 7 ). Two...
Abstract
This article examines the critical features of four key areas of modeling transport phenomena associated with casting processes. These include heat and species transport in a metal alloy, flow of the liquid metal, tracking of the free metal-gas surface, and inducement of metal flow via electromagnetic fields. Conservation equations that represent important physical phenomena during casting processes are presented. The article provides a discussion on how the physical phenomena can be solved. It provides information on a well-established array of general and specific computational tools that can be readily applied to modeling casting processes. The article also summarizes the key features of the conservation equations in these tools.
Series: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005406
EISBN: 978-1-62708-196-2
... the possibility of simulating directly the development of the solid/liquid interface, including its kinetics, pattern formation, and microsegregation with a limited number of approximations. While this article focuses on a presentation of the CA and PF methods that represent the state of the art for modeling...
Abstract
This article focuses on the intermediate length scales, where transport phenomena govern the spatial and temporal evolution of a structure. It presents the cellular automaton (CA) and phase field (PF) methods that represent the state of the art for modeling macrostructure and microstructure. The article describes the principles of the PF method and provides information on the applications of the PF method. The CA model is introduced as a computationally efficient method to predict grain structures in castings using the mesoscopic scale of individual grains. The article discusses the coupling of the CA to macroscopic calculation of heat, flow, and mass transfers in castings and applications to realistic casting conditions.