This article focuses on the mechanisms of microbially induced or influenced corrosion (MIC) of metallic materials as an introduction to the recognition, management, and prevention of microbiological corrosion failures in piping, tanks, heat exchangers, and cooling towers. It discusses the degradation of various protective systems, such as corrosion inhibitors and lubricants. The article describes the failure analysis of steel, iron, copper, aluminum, and their alloys. It also discusses the probes available to monitor conditions relevant to MIC in industrial systems and the sampling and analysis of conditions usually achieved by the installation of removable coupons in the target system. The article also explains the prevention and control strategies of MIC in industrial systems.

This article focuses on microbiologically influenced corrosion (MIC) of military assets. It discusses the mechanisms of MIC in hydrocarbon fuels and atmospheric, immersion, and buried environments with specific examples. The article describes the behavior of metals and alloys, namely, copper alloy, nickel alloy, titanium and titanium alloys, aluminum alloys, stainless steels, and carbon steel in immersion environments.

This article focuses on the mechanisms of microbiologically influenced corrosion as a basis for discussion on the diagnosis, management, and prevention of biological corrosion failures in piping, tanks, heat exchangers, and cooling towers. It begins with an overview of the scope of microbial activity and the corrosion process. Then, various mechanisms that influence corrosion in microorganisms are discussed. The focus is on the incremental activities needed to assess the role played by microorganisms, if any, in the overall scenario. The article presents a case study that illustrates opportunities to improve operating processes and procedures related to the management of system integrity. Industry experience with corrosion-resistant alloys of steel, copper, and aluminum is reviewed. The article ends with a discussion on monitoring and preventing microbiologically influenced corrosion failures.

This article focuses on the effects of microscopic organisms and the by-products they produce on the electrochemical corrosion of metals. The general characteristics of the microorganisms that facilitate their influence on the electrochemistry of corrosion are discussed. The industries most often reported as being affected by microbiological corrosion are listed, along with the organisms usually implicated in the attack. The article explains that the influence of organisms can be addressed successfully for a corrosion control program by using four types of evidence: metallurgical, microbiological, chemical, and electrochemical. It provides information on the microbiologically influenced corrosion (MIC) of irons and steels, passive alloys (austenitic stainless steels), aluminum alloys, copper alloys, and composites. The article reviews the formation of microbial biofilms and macrofouling films. It also describes the general approaches taken to prevent MIC.

This article explains how an engineer might go about assessing the risk of microbiologically influenced corrosion (MIC) in an industrial situation. It describes the systems that are susceptible to the effects of MIC by sulfate-reducing bacteria (SRB). The article discusses the effects of microorganisms other than SRB on metals. SRB-related problems, which are the most common MIC issue, are also explored. The article describes the test procedures used to enumerate microbiological populations. It concludes with a discussion on risk assessment based on operating conditions.

Corrosion resulting from the presence and activities of microbes on metals and metal alloys is generally referred to as microbiologically influenced corrosion (MIC). This article describes the biofilm formation and structure and microbial processes influencing corrosion. It also discusses the electrochemical techniques used to study and monitor MIC and presents examples of their applications to MIC.

This article discusses the general properties of ocean water and their effects on corrosion. It describes the major and minor features of the ocean water on corrosion, including the effects of variability, pollutants, and fouling organisms. Effects of water flow velocity on marine corrosion are also reviewed.

This article discusses the elements necessary for a galvanic cell operation. Detailed information on the possible corrosion reaction as a function of aqueous electrolyte concentration and pH, in the presence of certain ions, are provided using Pourbaix diagrams. A variety of atmospheric factors, climatic conditions, and air-chemical pollutants that determine the corrosiveness of the atmosphere and contribute to the metal corrosion process are discussed. The article reviews the phenomenon of precipitation runoff on the corroded metal surface and the corrosive microbial effect on metals. It describes the thermodynamics of atmospheric corrosion and models for predicting the corrosion damage of metals. The article concludes with information on the various trends in atmospheric corrosion research and methods for the corrosion processes.

This article provides a discussion on the operation of various methods and sensors that have been used or have the potential to be used for on-line, real-time monitoring of localized corrosion. These include the electrochemical noise (ECN) method, nonelectrochemical methods, the galvanically coupled differential flow cell, galvanically coupled crevice cell, coupled multielectrode sensor, and electrochemical biofilm activity sensor.

This article describes the test methods for evaluating the durability of a metal in soil. It provides useful information on soil characteristics such as soil electrical resistivity, pH value, and soil texture. Specimen design, preparation, burial, and retrieval techniques are discussed. The type of information sought during soil-induced corrosion evaluation controls the design configuration and the nature of the corrosion measurements. Consideration of these factors during the planning stage helps the corrosion engineer to obtain the maximum amount of information with the minimum number of problems.

This article is a pictorial guide to forms of corrosion that draws attention to common pitfalls or situations that have caused premature corrosion, sometimes with expensive consequences. The examples used are not exhaustive; they highlight the necessity to fully examine materials, conditions, and specific circumstances that together can reduce the anticipated service life of a component or plant. The color images in this article are categorized according to the type of corrosion following the general order that is adopted in Volume 13A of ASM Handbook. The first table of the article provides a categorization of the forms of corrosion. It also provides a reference to articles or sections of articles in Volume 13A that detail the particular corrosion form or mechanism. The second table is a guide listing the figures in this article by material and by the corrosion form or mechanism illustrated.

This article addresses the long-term corrosion behavior of high-level waste (HLW) container materials, more specifically of the outer shell of the containers. It discusses time, environmental, and materials considerations for the emplacement of HLW in geological repositories. Environmental corrosion resistance of materials planned for reducing repositories is also discussed. The article reviews the design and characterization of nuclear waste repository with an oxidizing environment surrounding the waste package.

This article discusses the failure analysis of several steel transmission pipeline failures, describes the causes and characteristics of specific pipeline failure modes, and introduces pipeline failure prevention and integrity management practices and methodologies. In addition, it covers the use of transmission pipeline in North America, discusses the procedures in pipeline failure analysis investigation, and provides a brief background on the most commonly observed pipeline flaws and degradation mechanisms. A case study related to hydrogen cracking and a hard spot is also presented.

Paints and protective coatings are the most common means of protecting materials from deterioration. This article focuses on coating degradation that results from the environmental interaction with the coatings. The major environmental influences of the degradation include energy (solar radiation, heat and temperature variation, and nuclear radiation), permeation (moisture, solvent retention, chemical, and oxygen), stress (drying and curing, vibration, and impact and abrasion), and biological influences (microbiological and macrobiological).

This article describes the commonly observed forms of airplane corrosion, namely: general corrosion, exfoliation corrosion, pitting corrosion, microbiologically induced corrosion, galvanic corrosion, filiform corrosion, crevice corrosion, stress-corrosion cracking, and fretting. It discusses the factors influencing airplane corrosion from the manufacturing perspective: design, manufacturing, and service-related factors. The article explains the collection of corrosion data and provides an overview of the implementation and evolution of airline corrosion prevention and control programs and directions being considered in the design for corrosion prevention of airplanes.

This article addresses the major heat-transfer components of the water-steam loop of a power plant. It describes the various types of condensers, including water-cooled condensers and air-cooled condensers. The article explains the corrosion mechanisms encountered in the condensers, including erosion-corrosion, galvanic corrosion, and pitting corrosion. It discusses the types of deaerators and deals with their corrosion problems. The article provides a discussion on two types of feedwater heaters: channel feedwater heaters and header feedwater heaters. It summarizes the corrosion problems associated with common feedwater heater tube materials.

This article discusses the identifying characteristics of the forms or mechanisms of corrosion that commonly attack copper metals, as well as the most effective means of combating each. It tabulates the corrosion ratings of wrought copper alloys in various corrosive media. The article describes the corrosion behavior of copper alloys in specific environments. It reviews the corrosion characteristics of copper and copper alloys in various acids, alkalis, salts, organic compounds, and gases. The article provides information on the behavior of copper alloys that is susceptible to stress-corrosion cracking in various industrial and chemical environments. It concludes with information on various corrosion testing methods, including aqueous corrosion testing, dynamic corrosion tests, and stress-corrosion testing.

This article begins with the discussion on the background of metal-matrix composites (MMC) and moves into a broad description of the general parameters affecting the corrosion of MMC. It discusses the primary sources of MMC corrosion that include galvanic corrosion between MMC constituents, chemical degradation of interphases and reinforcements, microstructure-influenced corrosion, and processing-induced corrosion. The article elaborates on the corrosion behavior of specific aluminum, magnesium, titanium, copper, stainless steel, lead, depleted uranium, and zinc MMCs systems. It concludes with a description on the corrosion control of MMCs using protective coatings and inhibitors.

This article discusses the effects of parameters on corrosivity and explains why it is critical to examine the parameter interactions prior to capturing the synergistic effects of the parameters on corrosion. It examines the methods of internal corrosion prediction for multiphase pipelines. The article reviews methodologies to perform internal corrosion direct assessment for pipelines. Real-time monitoring techniques for assessing actual corrosion at critical locations are discussed. The article also presents the case studies for multi-technique electrochemical corrosion monitoring.