This article explains how to prepare precious metal test samples for metallographic examination. It discusses cutting, mounting, grinding, polishing, and etching and addresses some of the challenges of working with small, relatively soft specimens. It includes dozens of example micrographs, comparing and contrasting the microstructural features of gold, platinum, iridium, palladium, and ruthenium-base alloys. It examines pure gold, intermetallic gold compounds, gold and platinum jewelry alloys, platinum-containing shape memory alloys, and alloys consisting of platinum, aluminum, and copper.

This article contains a table that lists the electrical conductivity and resistivity of selected metals, alloys, and materials at ambient temperature. These include aluminum and aluminum alloys; copper and copper alloys; electrical heating alloys; instrument and control alloys; relay steels and alloys; thermostat metals; electrical contact materials; and magnetically soft materials.

The refractory metals include niobium, tantalum, molybdenum, tungsten, and rhenium. They are readily degraded by oxidizing environments at moderately low temperatures. Protective coating systems have been developed, mostly for niobium alloys, to permit their use in high-temperature oxidizing aerospace applications. This article discusses the properties, processing, applications, and classes of refractory metals and its alloys, namely molybdenum, tungsten, niobium, tantalum and rhenium. It also provides an outline of the coating processes used to improve their oxidation resistance.

All refractory metals, except osmium and iridium, have the highest melting temperatures and lowest vapor pressures of all metals. This article discusses the commercial applications, and production procedures of refractory metals and alloys. These procedures include fabrication, machining, forming, cleaning, joining, and coatings. The article also presents information on, and specifications for, the following metals and their alloys: niobium, tantalum, molybdenum, tungsten, rhenium, and refractory metal fiber-reinforced composites. It discusses the processes involved in their production, their mechanical properties, physical properties, thermal properties, electrical properties, chemical properties, applications, and corrosion resistance.

Precious metals include gold, silver, and six platinum-group metals, namely, platinum, palladium, ruthenium, rhodium, osmium, and iridium. This article focuses on the consumption, trade practices, properties, product forms, and applications of these metals and their alloys.

Solidification is a comprehensive process of transformation of the melt of metals and alloys into a solid piece, involving formation of dendrites, segregation which involves change in composition, zone formation in final structure of the casting, and microporosity formation during shrinkage. This article describes the imperfections in the solidification process including porosity, inclusions, oxide films, secondary phases, hot tears, and metal penetration. It talks about the purpose of the gating system and the risering system in the casting process.

Copper, copper alloys, and precious metals are probably the most easily brazed metals because of their resistance to oxidation at high temperatures. This article provides a brief discussion on the metallurgy of copper, copper alloys, and precious metals and discusses the filler metals, brazing fluxes, joint clearance and design, and different brazing processes used in brazing of copper, copper alloys, and precious metals.

This article contains tables that present engineering data for the following metals and their alloys: aluminum, copper, iron, lead, magnesium, nickel, tin, titanium, zinc, precious metals, permanent magnet materials, pure metals, rare earth metals, and actinide metals. Data presented include density, linear thermal expansion, thermal conductivity, electrical conductivity, resistivity, and approximate melting temperature. The tables also present approximate equivalent hardness numbers for austenitic steels, nonaustenitic steels, austenitic stainless steel sheet, wrought aluminum products, wrought copper, and cartridge brass. The article lists conversion factors classified according to the quantity/property of interest.

This article characterizes the corrosion resistance of precious metals, namely, ruthenium, rhodium, palladium, silver, osmium, iridium, platinum, and gold. It provides a discussion on the general fabricability; atomic, structural, physical, and mechanical properties; oxidation and corrosion resistance; and corrosion applications of these precious metals. The article also tabulates the corrosion rates of these precious metals in corrosive environment, namely, acids, salts, and halogens.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of miscellaneous metals and alloys and in identifying and interpreting the morphology of fracture surfaces. The metals and alloys covered include tungsten, iridium, magnesium-base, iron-base, molybdenum-base, and tantalum-base materials. The fractographs illustrate fatigue striations, slow-bending fracture, quasi-cleavage fracture, corrosion-fatigue fracture, fatigue crack, intergranular cleavage, microvoid coalescence, tension-overload fracture, crack propagation, impact fracture, and high-cycle fatigue failure.

This article describes various procedures used in the metallographic preparation of niobium, tantalum, molybdenum, and tungsten alloys. It provides information on sectioning, grinding, mounting, polishing, and electrolytic etching as well as alternate procedures that have been used on refractory metals. The article presents and analyzes several micrographs, provides etchant formulas for various materials, and discusses the unique characteristics of rhenium and its alloys.

This article describes the metallographic technique for nonferrous metals and special-purpose alloys. These include aluminum alloys, copper and copper alloys, lead and lead alloys, magnesium alloys, nickel and nickel alloys, magnetic alloys, tin and tin alloys, titanium and titanium alloys, refractory metals and alloys, zinc and zinc alloys, and wrought heat-resisting alloys. The preparation of specimens for metallographic technique includes operations such as sectioning, mounting, grinding, polishing, and etching of nonferrous metals and alloys. The article contains tables that list the etchants for macroscopic examination and microscopic examination of nonferrous metals and special-purpose alloys.

This article reviews specific processing characteristics and forging-related properties of commonly forged families of metals and alloys, including carbon and alloy steels, stainless steels, heat-resistant alloys (iron, cobalt, and nickel base alloys), aluminum alloys, copper and copper alloys, magnesium alloys, and titanium alloys. It provides forging process variables such as stock preparation, heating and cooling of forgings, die lubrication, trimming, and cleaning of these metals and alloys. The article explains the effect of temperature, deformation rate, and die temperature on forgeability and describes the forging methods of these metals and alloys.

This article addresses surface cleaning, finishing, and coating operations that have proven to be effective for molybdenum, tungsten, tantalum, and niobium. It describes standard procedures for abrasive blasting, molten caustic processing, acid cleaning, pickling, and solvent and electrolytic cleaning as well as mechanical grinding and finishing. The article also provides information on common plating and coating methods, including electroplating, anodizing, and oxidation-resistant coatings.

This article begins with a general review of the effects of changes in stress state on processing of materials. It describes the fundamentals of hydrostatic extrusion and reviews the various issues and benefits associated with hydrostatic extrusion. The article discusses the hydrostatic extrusion of structural alloys, composites, brittle materials, and intermetallics or intermetallic compounds, with examples. It concludes with a discussion on the attempts made to extend the hydrostatic extrusion to higher temperatures.

This article contains a table that lists the density of metals and alloys. It presents information on aluminum, copper, iron, lead, magnesium, nickel, tin, titanium, and zinc, an their respective alloys. Information on wrought alloys, permanent magnet materials, precious metals, and rare earth metals is also listed.

This article presents a table that lists the linear thermal expansion of selected metals and alloys. These include aluminum, copper, iron, lead, magnesium, nickel, tin, titanium, and zinc and their alloys. Thermal expansion is presented for specific temperature ranges.

This article contains a table that lists the thermal conductivity of selected metals and alloys near room temperature. These include aluminum and aluminum alloys; copper and copper alloys; iron and iron alloys; lead and lead alloys; magnesium and magnesium alloys; nickel and nickel alloys; tin and tin alloys; titanium and titanium alloys; zinc and zinc alloys; and pure metals.