This article presents a table of the crystal structure of allotropic forms of metallic elements in terms of the Pearson symbol, space group, and prototype of the structure. The temperatures of the phase transformations are listed in degree Celsius and the pressures are in GPa. The lattice parameters of the unit cells are given in nanometers. The compilation of the table is restricted to changes in crystal structure that occur as a result of a change in temperature or pressure.

Crystal structure is the arrangement of atoms or molecules in the solid state that involves consideration of defects, or abnormalities, in idealized atomic/molecular arrangements. The three-dimensional aggregation of unit cells in the crystal forms a space lattice or Bravais lattice. This article provides a brief review of the terms and basic concepts associated with crystal structures. It also discusses some of the significant defects obstructing plastic flow in real crystals, namely point defects, line defects, stacking faults, twins, and cold work. Several tables in the article provide information on the crystal structures and lattice parameters of allotropes of metallic elements.

This article contains a table that lists the vapor pressures of selected metallic elements.

Diffusion brazing (DFB) is a process that coalesces, or joins, metals by heating them to a suitable brazing temperature at which either a preplaced filler metal will melt and flow by capillary attraction or a liquid phase will form in situ between one faying surface and another. This article discusses the two critical aspects of DFB, namely, a liquid filler metal must be formed and become active in the joint area and extensive diffusion of filler metal elements into the base metal must occur. It schematically illustrates a diffusion process that results in the loss of identity of original brazed joint. The article also discusses the advantages of DFB.

This article presents ternary alloy phase diagrams to be used primarily by engineers to solve industrial problems. The diagrams presented are for stable equilibrium conditions, with the exception of metastable conditions for some diagrams involving carbon and iron. In some ternary diagrams involving carbon and iron, the symbol M is used to represent both iron and the other metallic element when the two metals substitute for each other in a carbide phase.

This article defines crystallographic terms and concepts, including crystal structure, unit cell, structure symbols, lattice, space-group notation, and atom position. It schematically illustrates the atom positions, prototypes, structure symbols, space-group notations, and lattice parameters for some of the simple metallic crystals. A table that lists the crystal structures of various metal elements is presented. The crystal structures are described by the Pearson symbols for crystal system, space lattice, total number of atoms per unit cell, and prototype structure. The article tabulates the assorted structure types of metallurgical interest arranged according to Pearson symbol. It also provides information on crystal defects, explaining some significant ones, such as point defects, line defects, stacking faults, and twins.

Aluminum, the second most plentiful metallic element, is an economic competitor in various applications owing to its appearance, light weight, fabricability, physical properties, mechanical properties, and corrosion resistance. This article discusses the primary and secondary production of aluminum and classification system for cast and wrought aluminum alloys. It talks about various manufactured forms of aluminum and its alloys, which are classified into standardized products such as sheet, plate, foil, rod, bar, wire, tube, pipe, and structural forms, and engineered products such as extruded shapes, forgings, impacts, castings, stampings, powder metallurgy parts, machined parts, and metal-matrix composites. The article also reviews important fabrication characteristics in the machining, forming, forging, and joining of aluminum alloys. It concludes with a description of the major industrial applications of aluminum, including building and construction, transportation, consumer durables, electrical, machinery and equipment, containers and packaging, and other applications.

The electronic microcircuit industry has placed severe demands on metal suppliers to provide metals of the highest reproducible purity attainable as a result of the constant quest for the true values of physical and chemical properties of metals. This article describes the commonly used methods for ultrapurification of metals produced by electrolytic processes, including fractional crystallization, zone refining, vacuum melting, distillation, chemical vapor deposition, and solid state refining techniques. In addition, it describes the trace element analysis and resistance-ratio test methods used to characterize purity. Tables list the values for resistance ratios of zone-refined metals and their corresponding chemical compositions, and provide an example of the detection of impurities to concentrations in the parts per billion range, utilizing a combination of the glow discharge mass spectroscopy method and Leco combustion methods.

This article provides basic information on chemical elements and their arrangement into a periodic table based on recurring similarities in the fundamental nature of the elements.

This article provides basic information on the chemical elements and their arrangement into a periodic table based on recurring similarities in the fundamental nature of the elements. These elements follow a periodic pattern related to the electron configuration that allows them to be arranged into the convenient periodic table.

Fluxes are added to the welding environment to improve arc stability, provide a slag, add alloying elements, and refine the weld pool. This article discusses the effect of oxygen, which is an important chemical reagent to control the weld metal composition, microstructure, and properties. It provides information on the inclusions that form as a result of reactions between metallic alloy elements and nonmetallic tramp elements, or by mechanical entrapment of nonmetallic slag or refractory particles. The article reviews the considerations of flux formulation during shielded metal arc welding and flux cored arc welding (FCAW). It describes the types of fluxes used for submerged arc welding and FCAW as well as five essential groups of flux ingredients and their interactions.

Fluxes are added to the welding environment to improve arc stability, to provide a slag, to add alloying elements, and to refine the weld pool. This article describes the effect of oxygen that directly reacts with alloying elements to alter their effective role by reducing hardenability, promoting porosity, and producing inclusions. It proposes basicity index for welding as a measure of expected weld metal cleanliness and mechanical properties. The article discusses alloy modification in terms of slipping and binding agents, slag formation, and slag detachability. It reviews the types of fluxes for different arc welding processes, such as shielded metal arc welding (SMAW), flux-cored arc welding (FCAW), and submerged arc welding (SAW).

Chemical elements are the basic chemical substances; that is, they cannot be decomposed by chemical change or made by chemical union. These elements follow a periodic pattern related to the atomic mass of each that allows them to be arranged into a convenient table. This article includes a series of tables: the first gives the names and symbols of the elements in alphabetical order and the second lists the elements in order by atomic number and give the atomic weight for each. The periodic table of the elements also is included in the article.

Rare earth metals belong to Group IIIA of the periodic table that includes scandium, yttrium, and the lanthanide elements which are lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium. This article classifies the rare earth metals based on their purity level, which are designated as research grades (>99.8% pure) and commercial grades (95% - 98% pure), and describes the preparation and purification, including solid-state electrolysis. It further discusses physical, mechanical, and chemical properties; electronic configurations; crystal structures, and explains the alloy forming characteristics of rare earth elements. The article concludes by describing the various applications of commercial-grade rare earth elements and commercial alloys, which incorporates rare earth elements as additives.